Alternative Catalytic Materials


Book Description

Many important industrial chemical processes rely heavily on catalysis and so researchers are always on the lookout for alternative catalytic materials that may improve existing processes or lead to new ones. Families of alternative catalytic materials currently being investigated include the carbides, nitrides and phosphides as well as amorphous boron catalysts. The addition of carbon, nitrogen or phosphorous to transition metals and the creation of boron-transition metal alloys leads to catalytic materials that have interesting properties, with applications in a range of different reactions, including electrocatalysis. This book provides a comprehensive account of the preparation, characterisation and application of these catalytic materials. It is an important reference for researchers and industrialists working in heterogeneous catalysis and materials chemistry.




Alternative Catalytic Materials


Book Description

Many important industrial chemical processes rely heavily on catalysis and so researchers are always on the lookout for alternative catalytic materials that may improve existing processes or lead to new ones. Families of alternative catalytic materials currently being investigated include the carbides, nitrides and phosphides as well as amorphous boron catalysts. The addition of carbon, nitrogen or phosphorous to transition metals and the creation of boron-transition metal alloys leads to catalytic materials that have interesting properties, with applications in a range of different reactions, including electrocatalysis. This book provides a comprehensive account of the preparation, characterisation and application of these catalytic materials. It is an important reference for researchers and industrialists working in heterogeneous catalysis and materials chemistry.




New Materials for Catalytic Applications


Book Description

New Materials for Catalytic Applications proposes the use of both new and existing materials for catalytic applications, such as zeolites, metal oxides, microporous and mesoporous materials, and monocrystals. In addition, metal-oxides are discussed from a new perspective, i.e. nano- and photocatalytic applications. The material presents these concepts with a new focus on strategies in synthesis, synthesis based on a rational design, the correlation between basic properties/potential applications, and new catalytic solutions for acid-base, redox, hydrogenation, photocatalytic reactions, etc. - Presents organometallic concepts for the synthesis of nanocatalysts - Provides a synthesis of new materials following the fluorolytic sol-gel concept - Covers electronic and photocatalytic properties via synthesis of nano-oxide materials - Details the nature of sites in MOFs generating catalytic properties immobilization of triflates in solid matrices for organic reactions




Catalysis by Materials with Well-Defined Structures


Book Description

Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner - Outlines the importance of nanomaterials and their potential as catalysts - Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity - Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts - Offers examples on various in situ characterization instrumental techniques - Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods




Advanced Catalytic Materials


Book Description

Todays chemical industry processes worldwide largely depend on catalytic reactions and the desirable future evolution of this industry toward more selective products, more environmentally friendly products, more energy-efficient processes, a smaller use of hazardous reagents, and a better use of raw materials also largely involves the development of better catalysts and, specifically, purposely designed catalytic materials. The careful study and development of the new-generation catalysts involve relatively large groups of specialists in universities, research centers, and industries, joining forces from different scientific and technical disciplines. This book has put together recent, state-of-the-art topics on current trends in catalytic materials and consists of 16 chapters.




Advanced Functional Solid Catalysts for Biomass Valorization


Book Description

Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts' properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts' stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed.




Heterogeneous Catalytic Materials


Book Description

Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively. This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for catalysts), mixed and complex oxides and salts, halides, sulfides, carbides, and unsupported and supported metals are all considered. The book encompasses applications in industrial chemistry, refinery, petrochemistry, biomass conversion, energy production, and environmental protection technologies. - Provides a systematic and clear approach of the synthesis, solid state chemistry and surface chemistry of all solid state catalysts - Covers widely used instrumental techniques for catalyst characterization, such as x-ray photoelectron spectroscopy, scanning electron microscopy, and more - Includes characterization methods and lists all catalytic behavior of the solid state catalysts - Discusses new developments in nanocatalysts and their advantages over conventional catalysts




Chemical Looping Partial Oxidation


Book Description

This is the first comprehensive guide to the principles and techniques of chemical looping partial oxidation. With authoritative explanations from a pioneer of the chemical looping process, you will: • Gain a holistic overview of metal oxide reaction engineering, with coverage of ionic diffusion, nanostructure formation, morphological evolution, phase equilibrium, and recyclability properties of metal oxides during redox reactions • Learn about the gasification of solid fuels, the reforming of natural gas, and the catalytic conversion of methane to olefins • Understand the importance of reactor design and process integration in enabling metal oxide oxygen carriers to produce desired products • Discover other applications of catalytic metal oxides, including the production of maleic anhydride and solar energy conversions Aspen Plus® simulation software and results accompany the book online. This is an invaluable reference for researchers and industry professionals in the fields of chemical, energy and environmental engineering, and students studying process design and optimization.




Fundamentals of Energy Storage and Conversion


Book Description

The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Fundamentals of Energy Storage and Conversion¿, held during the 213th meeting of The Electrochemical Society, in Phoenix, Arizona from May 18 to 23, 2008.




SPR Catalysis V26


Book Description

Over 7000 papers are published in the field of catalysis each year. While the majority appear within a handful publications, keeping up with the literature can be difficult. Now in its 26th volume, the Specialist Periodical Report on Catalysis presents critical and comprehensive reviews of the hottest literature published over the last twelve months. Industrial and academic scientists face increasing challenges to find cost-effective and environmentally sound methods for converting natural resources into fuels, chemicals and energy. This series is edited by two leading researchers in the field and provides a balanced and in-depth review of the modern approaches to these challenges, covering major areas of heterogeneous and homogenous catalysis, as well as specific applications of catalysis, such as NOx control, kinetics and experimental techniques, such as microcalorimetry. With chapters detailing specific areas within the field, this series is a comprehensive reference for anyone working in Catalysis and an essential resource for any Library.