Cyclohexane from Benzene and Hydrogen - Cost Analysis - Cyclohexane E11A


Book Description

This report presents a cost analysis of Cyclohexane from benzene and hydrogen. The process examined is a liquid phase hydrogenation process. In this process, benzene is hydrogenated in a liquid-phase reactor in the presence of a nickel-based catalyst. The reactor's overhead is sent to a second reactor to convert the non-reacted benzene. This report was developed based essentially on the following reference(s): US Patent 5,668,293, issued to Institut Francais du Petrole in 1997 Keywords: Benzene Hexahydride, Cycloalkane, Liquid-Phase Reaction, Hydrogenation Reaction, IFP




Caprolactam Production from Benzene - Cost Analysis - Caprolactam E11A


Book Description

This report presents a cost analysis of Caprolactam production from benzene. The process examined involves the following steps: benzene is hydrogenated to cyclohexane; cyclohexane is oxidized to a mixture of cyclohexanol and cyclohexanone; cyclohexanol is dehydrogenated to cyclohexanone; cyclohexanone undergoes an oximation reaction with hydroxilamine; and the oxime produced is rearranged to Caprolactam. Ammonium sulfate is also generated as by-product. This report was developed based essentially on the following reference(s): (1) "Caprolactam", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) "Cyclohexane", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Cyclohexanone, Cyclohexanol, Lactam Synthesis, Lactam Purification, Ammonium Sulfate Crystallization




Adipic Acid Production from Cyclohexane - Cost Analysis - Adipic Acid E11A


Book Description

This report presents a cost analysis of Adipic Acid production from cyclohexane. The process examined is a two-stage oxidation process, similar to the Invista technology. In this process, cyclohexane is initially oxidized with air to produce KA oil (mixture of cyclohexanone and cyclohexanol). Subsequently, the KA oil is oxidized with nitric acid to produce Adipic Acid. A mixture of adipic, glutaric, and succinic acids is generated as by-product. GGKEY:YEUZ5NEBS2C This report was developed based essentially on the following reference(s): (1) US Patent 20040054235, issued to DuPont in 2004 (assigned to Invista in 2004) (2) "Adipic Acid," Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Hexanedioic Acid, DuPont, Ketone/Alcohol Oil, Air Oxidation, Nitric Acid Oxidation, Boric Acid




Cyclohexane from Benzene and Hydrogen - Cost Analysis - Cyclohexane E11A


Book Description

This report presents a cost analysis of Cyclohexane from benzene and hydrogen The process examined is a liquid phase hydrogenation process. In this process, benzene is hydrogenated in a liquid-phase reactor in the presence of a nickel-based catalyst. The reactor's overhead is sent to a second reactor to convert the non-reacted benzene. This report was developed based essentially on the following reference(s): US Patent 5,668,293, issued to Institut Francais du Petrole in 1997 Keywords: Benzene Hexahydride, Cycloalkane, Liquid-Phase Reaction, Hydrogenation Reaction, IFP




LLDPE Production via Solution Process - Cost Analysis - LLDPE E11A


Book Description

This report presents a cost analysis of Linear Low Density Polyethylene (LLDPE) production from polymer grade (PG) ethylene and 1-octene using a solution process. The process under analysis is similar to NOVA Chemicals SCLAIRTECH process. This report was developed based essentially on the following reference(s): EP Patent 0527144, issued to DuPont in 1996 Keywords: Ethene, DuPont Canada, Cyclohexane, Stirred-Reactor, Swing Technology, Multi-Reactor




Hexamethylenediamine Production from Butadiene - Cost Analysis - HMDA E11A


Book Description

This report presents a cost analysis of Hexamethylenediamine (HMDA) production from butadiene and hydrogen cyanide In the process examined, butadiene reacts with hydrogen cyanide to produce adiponitrile as an intermediate. Subsequently, the adiponitrile is hydrogenated to produce HMDA. This report was developed based essentially on the following reference(s): (1) WO Patent 2015009847, issued to Invista Technologies in 2015 (2) US Patent 4395573, issued to Monsanto in 1981 Keywords: HMDA, Rhône-Poulenc, DuPont, Hydrocyanation




Quantitative Chemical Analysis


Book Description

The gold standard in analytical chemistry, Dan Harris’ Quantitative Chemical Analysis provides a sound physical understanding of the principles of analytical chemistry and their applications in the disciplines




Fundamentals of Petroleum Refining


Book Description

Fundamentals of Petroleum Refining presents the fundamentals of thermodynamics and kinetics, and it explains the scientific background essential for understanding refinery operations. The text also provides a detailed introduction to refinery engineering topics, ranging from the basic principles and unit operations to overall refinery economics. The book covers important topics, such as clean fuels, gasification, biofuels, and environmental impact of refining, which are not commonly discussed in most refinery textbooks. Throughout the source, problem sets and examples are given to help the reader practice and apply the fundamental principles of refining. Chapters 1-10 can be used as core materials for teaching undergraduate courses. The first two chapters present an introduction to the petroleum refining industry and then focus on feedstocks and products. Thermophysical properties of crude oils and petroleum fractions, including processes of atmospheric and vacuum distillations, are discussed in Chapters 3 and 4. Conversion processes, product blending, and alkylation are covered in chapters 5-10. The remaining chapters discuss hydrogen production, clean fuel production, refining economics and safety, acid gas treatment and removal, and methods for environmental and effluent treatments. This source can serve both professionals and students (on undergraduate and graduate levels) of Chemical and Petroleum Engineering, Chemistry, and Chemical Technology. Beginners in the engineering field, specifically in the oil and gas industry, may also find this book invaluable. - Provides balanced coverage of fundamental and operational topics - Includes spreadsheets and process simulators for showing trends and simulation case studies - Relates processing to planning and management to give an integrated picture of refining




Basic Principles and Calculations in Chemical Engineering


Book Description

Best-selling introductory chemical engineering book - now updated with far more coverage of biotech, nanotech, and green engineering Thoroughly covers material balances, gases, liquids, and energy balances. Contains new biotech and bioengineering problems throughout.




New Horizons in Biotechnology


Book Description

The practice of biotechnology, though different in style, scale and substance in globalizing science for development involves all countries. Investment in biotechnology in the industrialised, the developing, and the least developed countries, is now amongst the widely accepted avenues being used for economie development. The simple utilization of kefir technology, the detoxification of injurious chemical pesticides e.g. parathion, the genetic tailoring of new crops, and the production of a first of a kind of biopharmaceuticals illustrate the global scope and content of biotechnology research endeavour and effort. In the developing and least developed nations, and in which the 9 most populous countries· are encountered, problems concerning management of the environment, food security, conservation of human health resources and capacity building are important factors that influence the path to sustainable development. Long-term use of biotechnology in the agricultural, food, energy and health sectors is expected to yield a windfall of economic, environmental and social benefits. Already the prototypes of new medicines and of prescription fruit vaccines are available. Gene based agriculture and medieine is increasingly being adopted and accepted. Emerging trends and practices are reflected in the designing of more efficient bioprocesses, and in new research in enzyme and fermentation technology, in the bioconversion of agro industrial residues into bio-utility products, in animal healthcare, and in the bioremediation and medical biotechnologies. Indeed, with each new day, new horizons in biotechnology beckon.