Electrochemical Methods for the Micro- and Nanoscale


Book Description

Are electrochemical methods like asking the crystal ball? Once you read this book about electrochemistry on the micro- and nanoscale, you know it better. This textbook presents the essentials of electrochemical theory, sheds light on the instrumentation, including details on the electronics, and in the second part, discusses a wide variety of classical and advanced methods. The third part of the book covers how to apply the techniques for selected aspects of material science, microfabrication, nanotechnology, MEMS, NEMS, and energy applications. With this book, you will be able to successfully apply the methods in the fields of sensors, neurotechnology, biomedical engineering, and electrochemical energy systems. Undergraduate or Master students can read the book linearly as a comprehensive textbook. For Ph.D. students, postdoctoral researchers as well as for researchers in industry, the book will help by its clear structure to get fast answers from a specific section.




Electrochemistry at the Nanoscale


Book Description

For centuries, electrochemistry has played a key role in technologically important areas such as electroplating or corrosion. In recent decades, electrochemical methods are receiving increasing attention in important strongly growing fields of science and technology such as nanosciences (nanoelectrochemistry) and life-sciences (organic and biological electrochemistry). Characterization, modification and understanding of various electrochemical interfaces or electrochemical processes at the nanoscale, has led to a huge increase of the scientific interest in electrochemical mechanisms as well as of application of electrochemical methods in novel technologies. This book presents exciting emerging scientific and technological aspects of the introduction of the nanodimension in electrochemical approaches are presented in 12 chapters/subchapters.




Electrochemical Nanotechnologies


Book Description

In this book, the term "electrochemical nanotechnology" is defined as nanoprocessing by means of electrochemical techniques. This introductory book reviews the application of electrochemical nanotechnologies with the aim of understanding their wider applicability in evolving nanoindustries. These advances have impacted microelectronics, sensors, materials science, and corrosion science, generating new fields of research that promote interaction between biology, medicine, and microelectronics. This volume reviews nanotechnology applications in selected high technology areas with particular emphasis on advances in such areas. Chapters are classified under four different headings: Nanotechnology for energy devices - Nanotechnology for magnetic storage devices - Nanotechnology for bio-chip applications - Nanotechnology for MEMS/Packaging.




Modern Electrochemical Methods in Nano, Surface and Corrosion Science


Book Description

The basics and principles of new electrochemical methods and also their usage for fabrication and analysis of different nanostructures were discussed in this book. These methods consist of electrochemical methods in nanoscale (e.g. electrochemical atomic force microscopy and electrochemical scanning tunneling microscopy) and also electrochemical methods for fabrication of nanomaterials.




Micro-Nano Electrochemical Systems and Fabrication Techniques Handbook


Book Description

This book is a collection of researches by various experts who share their analysis of current trends and future implications of micro-nano electrochemical systems. MEMS technology is progressively influencing and improving our quality of life. Simultaneously, progress in nanotechnology and nanomaterials has accelerated the growth of NEMS. This book consists of an analysis of modern technologies and their forthcoming developments. It focuses on the recent progress in devices and production procedures in the field of these miniaturized electromechanical structures. This book presents information about design, production and packaging; as well as solutions in these aspects for targeted functions. This book aims to help experts and students who are engaged in this field.




Nanoscale Electrochemistry


Book Description

Nanoscale Electrochemistry focuses on challenges and advances in electrochemical nanoscience at solid–liquid interfaces, highlighting the most prominent developments of the last decade. Nanotechnology has had a tremendous effect on the multidisciplinary field of electrochemistry, yielding new fundamental insights that have broadened our understanding of interfacial processes and stimulating new and diverse applications. The book begins with a tutorial chapter to introduce the principles of nanoscale electrochemical systems and emphasize their unique behavior compared with their macro/microscopic counterparts. Building on this, the following three chapters present analytical applications, such as sensing and electrochemical imaging, that are familiar to the traditional electrochemist but whose extension to the nanoscale is nontrivial and reveals new chemical information. The subsequent three chapters present exciting new electrochemical methodologies that are specific to the nanoscale, including "single entity"-based methods and surface-enhanced electrochemical spectroscopy. These techniques, now sufficiently mature for exposition, have paved the way for major developments in our understanding of solid–liquid interfaces and continue to push electrochemical analysis toward atomic-length scales. The final three chapters address the rich overlap between electrochemistry and nanomaterials science, highlighting notable applications in energy conversion and storage. This is an important reference for both academic and industrial researchers who are seeking to learn more about how nanoscale electrochemistry has developed in recent years. - Outlines the major applications of nanoscale electrochemistry in energy storage, spectroscopy and biology - Summarizes the major principles of nanoscale electrochemical systems, exploring how they differ from similar system types - Discusses the major challenges of electrochemical analysis at the nanoscale




Electrochemical Methods


Book Description

Provides students with solutions to problems in the 3rd edition of the classic textbook Electrochemical Methods: Fundamentals and Applications Electrochemical Methods is a popular textbook on electrochemistry that takes the reader from the most basic chemical and physical principles, through fundamentals of thermodynamics, kinetics, and mass transfer, all the way to a thorough treatment of all important experimental methods. Holistically, it offers comprehensive coverage of all important topics in the field. To aid in reader comprehension, exercises are included at the end of each chapter which extend concepts introduced in the text or show how experimental data are reduced to fundamental results. This book provides worked solutions for many of the end-of-chapter exercises and is a key resource for any student who makes use of the original textbook.




New Tools for Studying Nanoscale Electrochemical Phenomena


Book Description

This dissertation focuses primarily on the fabrication of micro and nanoscale electrochemical structures such as electrodes, electrode arrays, and nanopores. It also discusses the use of these tools in studying nanoscale electrochemical processes such as geometric considerations in redox molecule diffusion to nanoscale electrodes, confined diffusion within electrode arrays, nanoparticle transport, and emulsion droplet transport and agglomeration. There is an introduction to electrochemistry followed by considerations to make when studying electron transfer at the nanoscale using voltammetric and amperometric measurements. Chapter 2 discusses three types of new nanoelectrodes that have been developed. These nanoelectrodes are different from previous nanoelectrodes in their materials and fabrication methods. Chapter 3 introduces the reader to electrode arrays and their properties. A new way of fabricating microelectrode arrays with high density and a nearly 100% success rate in terms of electrode activity is presented. In Chapter 4 a new electrochemical imaging technique developed in our lab is introduced. This new technique requires bipolar electrode arrays, new variants of which are fabricated using several methods which are discussed. Chapter 5 moves away from Faradaic current measurements toward ionic current measurements of nanoparticles. Emulsified oil droplets are monitored with ionic current measurements and fluorescence imaging to reveal their interactions at a nanopore. In Chapter 6 a new method for fabricating nanopores is outlined along with substantial experiments and finite element simulations to describe their properties. The ability of this new nanopore to measure nanoparticles is illustrated through resistive-pulse sensing. These new nanopores are compared with another type of nanopore using both experiment and simulation.




Handbook of Electrochemistry


Book Description

Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)