Guidance Manual for the Minimisation of NDMA and other Nitrosamines in Drinking and Recycled Water


Book Description

N-nitrosodimethylamine (NDMA) is a nitrogen-containing organic compound that has known carcinogenic properties. NDMA has been a health concern for some industries for a number of years as it is used in rubber formulations, as a fire retardant, antioxidant, additive for lubricants and softener of copolymers; it is also a degradation product of dimethylhydrazine, an additive to rocket fuel. Most people are exposed to NDMA via a number of diverse routes including cigarette smoke (actively or passively) and processed foods, for example smoked meat products. However, it has only come to the attention of the international water industry since it was recognised as a disinfection by-product (DBP) of chloramination or chlorination in the presence of ammonia. The aim of this guidance manual is to answer commonly asked questions about this emerging issue, such as: How do they come to be in drinking water and recycled water and what • concentrations are “normal”? What regulatory/guidance levels have been imposed in Australia and elsewhere? How are they formed? What are the risk factors for the occurrence of nitrosamines in my system? What can we do to control them? What are the implications for the drinking and recycled water industry, and in particular for public health? This Guidance Manual has a companion document, Generic Management Plan for Nitrosamines in Drinking Water which provides provide background information on the group of organic contaminants, nitrosamines. This book is co-published with Water Research Australia.







Analysis and Formation of Disinfection Byproducts in Drinking Water


Book Description

Drinking water disinfection has markedly reduced diseases causes by waterborne pathogenic microorganisms. However, an unintended consequence of disinfection and/or oxidation processes is the generation of disinfection byproducts (DBPs) which are formed from the reactions of disinfectants/oxidants with water matrix components. This volume of the Comprehensive Analytical Chemistry Handbook presents recent advances about the formation, identification, and quantification of inorganic and organic DBPs during oxidative processes. The book begins with a first chapter reviewing the most recent non-targeted screening approaches and workflows to characterize DBPs using low-, high-, and ultra-high-resolution mass spectrometry. The second chapter discusses the analysis of inorganic chloramines in waters using on-site and/or in-lab analytical methods. The third chapter provides an overview of the current knowledge about the mechanisms of chlorine dioxide reactions and byproducts formation. The fourth chapter presents some fundamental and practical aspects about ozonation processes in water treatment and provides an overview about ozone reaction mechanisms and byproducts formation. The fifth chapter focuses on the reactivity of halide ions, particularly bromide and iodide, with common oxidants and the role they play in determining the speciation of DBPs in treated waters. The chapter also presents strategies to mitigate the formation of DBPs during oxidation processes. Finally, the last chapter tackles the topic of DBPs formation during potable water reuse. It discusses the formation of DBPs of major concern in both memebrane-based and non-membrane-based potable water reuse treatment schemes.Researchers, water treatment specialists, and regulators will find in this book a valuable and compact resource on several key topics regarding the formation, identification, quantification, and mitigation of DBPs. - Identification and quantification of known and unknown DBPs - Formation of DBPs during different disinfection/oxidation processes - DBPs of concern in new technologies and/or new applications of existing technologies in water treatment




Water Reuse


Book Description

Expanding water reuse-the use of treated wastewater for beneficial purposes including irrigation, industrial uses, and drinking water augmentation-could significantly increase the nation's total available water resources. Water Reuse presents a portfolio of treatment options available to mitigate water quality issues in reclaimed water along with new analysis suggesting that the risk of exposure to certain microbial and chemical contaminants from drinking reclaimed water does not appear to be any higher than the risk experienced in at least some current drinking water treatment systems, and may be orders of magnitude lower. This report recommends adjustments to the federal regulatory framework that could enhance public health protection for both planned and unplanned (or de facto) reuse and increase public confidence in water reuse.




Drinking Water Distribution Systems


Book Description

Protecting and maintaining water distributions systems is crucial to ensuring high quality drinking water. Distribution systems-consisting of pipes, pumps, valves, storage tanks, reservoirs, meters, fittings, and other hydraulic appurtenances-carry drinking water from a centralized treatment plant or well supplies to consumers' taps. Spanning almost 1 million miles in the United States, distribution systems represent the vast majority of physical infrastructure for water supplies, and thus constitute the primary management challenge from both an operational and public health standpoint. Recent data on waterborne disease outbreaks suggest that distribution systems remain a source of contamination that has yet to be fully addressed. This report evaluates approaches for risk characterization and recent data, and it identifies a variety of strategies that could be considered to reduce the risks posed by water-quality deteriorating events in distribution systems. Particular attention is given to backflow events via cross connections, the potential for contamination of the distribution system during construction and repair activities, maintenance of storage facilities, and the role of premise plumbing in public health risk. The report also identifies advances in detection, monitoring and modeling, analytical methods, and research and development opportunities that will enable the water supply industry to further reduce risks associated with drinking water distribution systems.




Water Quality & Treatment: A Handbook on Drinking Water


Book Description

The definitive water quality and treatment resource--fully revised and updated Comprehensive, current, and written by leading experts, Water Quality & Treatment: A Handbook on Drinking Water, Sixth Edition covers state-of-the-art technologies and methods for water treatment and quality control. Significant revisions and new material in this edition reflect the latest advances and critical topics in water supply and treatment. Presented by the American Water Works Association, this is the leading source of authoritative information on drinking water quality and treatment. NEW CHAPTERS ON: Chemical principles, source water composition, and watershed protection Natural treatment systems Water reuse for drinking water augmentation Ultraviolet light processes Formation and control of disinfection by-products DETAILED COVERAGE OF: Drinking water standards, regulations, goals, and health effects Hydraulic characteristics of water treatment reactors Gas-liquid processes and chemical oxidation Coagulation, flocculation, sedimentation, and flotation Granular media and membrane filtration Ion exchange and adsorption of inorganic contaminants Precipitation, coprecipitation, and precipitative softening Adsorption of organic compounds by activated carbon Chemical disinfection Internal corrosion and deposition control Microbiological quality control in distribution systems Water treatment plant residuals management




Safe Drinking Water


Book Description

Drinking water provides an efficient source for the spread of gastrointestinal microbial pathogens capable of causing serious human disease. The massive death toll and burden of disease worldwide caused by unsafe drinking water is a compelling reason to value the privilege of having safe drinking water delivered to individual homes. On rare occasions, that privilege has been undermined in affluent nations by waterborne disease outbreaks traced to the water supply. Using the rich and detailed perspectives offered by the evidence and reports from the Canadian public inquiries into the Walkerton (2000) and North Battleford (2001) outbreaks to develop templates for understanding their key dimensions, over 60 waterborne outbreaks from 15 affluent countries over the past 30 years are explored as individual case studies. Recurring themes and patterns are revealed and the critical human dimensions are highlighted suggesting insights for more effective and more individualized preventive strategies, personnel training, management, and regulatory control. Safe Drinking Water aims to raise understanding and awareness of those factors that have most commonly contributed to or caused drinking-water-transmitted disease outbreaks - essentially a case-history analysis within the multi-barrier framework. It contains detailed analysis of the failures underlying drinking-water-transmitted disease epidemics that have been documented in the open literature, by public inquiry, in investigation reports, in surveillance databases and other reliable information sources. The book adopts a theme of 'converting hindsight into foresight', to inform drinking-water and health professionals including operators, managers, engineers, chemists and microbiologists, regulators, as well as undergraduates and graduates at specialty level. Key Features: Contains details and perspectives of major outbreaks not widely known or understood beyond those directly involved in the investigations. Technical and scientific background associated with case studies is offered in an accessible summary form. Does not require specialist training or experience to comprehend the details of the numerous outbreaks reviewed. By providing a broad-spectrum review using a consistent approach, several key recurring themes are revealed that offer insights for developing localized, tailor-made prevention strategies.




Advanced Oxidation Processes for Water Treatment


Book Description

Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada




The Llobregat


Book Description

The Llobregat belongs to the most thoroughly studied rivers in Europe and is a paradigm of the confluence of human and natural disturbances in a single basin. Because of its location in a very densely populated region and its Mediterranean character, the Llobregat supports a mixture of irregular flow, water abstraction, excess nutrients, mining debris, and a wide array of pollutants. The aquatic organisms strive to survive in a dramatically changing river that passes through a succession of dams, weirs and channels. The long-term river monitoring as well as the research that has been carried out in the river for a long time have provided an extensive knowledge of these disturbances and their effects on the biological communities. This book highlights the available information, with emphasis on the hydrological, chemical and biological elements interspersed in the river. Experts in the field discuss the main nutrient patterns and pollutant occurrence and the responses of the biological quality elements as well as the river ecosystem to the overall natural and man-made influences.




Hazardous Pollutants in Biological Treatment Systems


Book Description

Hazardous pollutants are a growing concern in treatment engineering. In the past, biological treatment was mainly used for the removal of bulk organic matter and the nutrients nitrogen and phosphorous. However, relatively recently the issue of hazardous pollutants, which are present at very low concentrations in wastewaters and waters but are very harmful to both ecosystems and humans, is becoming increasingly important. Today, treatment of hazardous pollutants in the water environment becomes a challenge as the water quality standards become stricter. Hazardous Pollutants in Biological Treatment Systems focuses entirely on hazardous pollutants in biological treatment and gives an elaborate insight into their fate and effects during biological treatment of wastewater and water. Currently, in commercial and industrial products and processes, thousands of chemicals are used that reach water. Many of those chemicals are carcinogens, mutagens, endocrine disruptors and toxicants. Therefore, water containing hazardous pollutants should be treated before discharged to the environment or consumed by humans. This book first addresses the characteristics, occurrence and origin of hazardous organic and inorganic pollutants. Then, it concentrates on the fate and effects of these pollutants in biological wastewater and drinking water treatment units. It also provides details about analysis of hazardous pollutants, experimental methodologies, computational tools used to assist experiments, evaluation of experimental data and examination of microbial ecology by molecular microbiology and genetic tools. Hazardous Pollutants in Biological Treatment Systems is an essential resource to the researcher or the practitioner who is already involved with hazardous pollutants and biological processes or intending to do so. The text will also be useful for professionals working in the field of water and wastewater treatment.