Biofuels


Book Description

This book offers the current state of knowledge in the field of biofuels, presented by selected research centers from around the world. Biogas from waste production process and areas of application of biomethane were characterized. Also, possibilities of applications of wastes from fruit bunch of oil palm tree and high biomass/bagasse from sorghum and Bermuda grass for second-generation bioethanol were presented. Processes and mechanisms of biodiesel production, including the review of catalytic transesterification process, and careful analysis of kinetics, including bioreactor system for algae breeding, were widely analyzed. Problem of emissivity of NOx from engines fueled by B20 fuel was characterized. The closing chapters deal with the assessment of the potential of biofuels in Turkey, the components of refinery systems for production of biodegradable plastics from biomass. Also, a chapter concerning the environmental conditions of synthesis gas production as a universal raw material for the production of alternative fuels was also added.




Hydrogen and Syngas Production and Purification Technologies


Book Description

Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems




Sustainable Alternative Syngas Fuel


Book Description

The development and use of sustainable and alternative fuels (syngas, biogas, biodiesel, bio-oil, hydrogen) derived from sources other than petroleum is needed due to the limited fossil fuel resources, the need for reduction of atmospheric greenhouse gas emissions, energy security, and to meet the future high energy demand due to population growth. New alternative fuels that can be produced locally and derived from renewable sources will be more sustainable compared to fossil fuels. Alternative and renewable fuels can be produced using different thermochemical and bio-chemical processes. Gasification is a thermochemical process used to produce syngas fuel (mainly hydrogen and carbon dioxide) from renewable (biomass) and conventional (coal) sources. The syngas fuels produced from the gasification process can be used for different applications: power generation (combustion of syngas fuel in gas turbine engines), heating, and transportation (internal combustion engines). This book intends to provide the reader with an overview of the current technologies, methods, and strategies of syngas fuel production, characterization, and application.




Advanced Nanomaterials for Catalysis and Energy


Book Description

Advanced Nanomaterials for Catalysis and Energy: Synthesis, Characterization and Applications outlines new approaches to the synthesis of nanomaterials (synthesis in flow conditions, laser electrodispersion of single metals or alloys on carbon or oxide supports, mechanochemistry, sol-gel routes, etc.) to provide systems with a narrow particle size distribution, controlled metal-support interaction and nanocomposites with uniform spatial distribution of domains of different phases, even in dense sintered materials. Methods for characterization of real structure and surface properties of nanomaterials are discussed, including synchrotron radiation diffraction and X-ray photoelectron spectroscopy studies, neutronography, transmission/scanning electron microscopy with elemental analysis, and more. The book covers the effect of nanosystems' composition, bulk and surface properties, metal-support interaction, particle size and morphology, deposition density, etc. on their functional properties (transport features, catalytic activity and reaction mechanism). Finally, it includes examples of various developed nanostructured solid electrolytes and mixed ionic-electronic conductors as materials in solid oxide fuel cells and asymmetric supported membranes for oxygen and hydrogen separation. - Outlines synthetic and characterization methods for nanocatalysts - Relates nanocatalysts' properties to their specific applications - Proposes optimization methods aiming at specific applications




Natural Gas Conversion VI


Book Description

This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 6th Natural Gas Conversion Sumposium held in Alaska in June 2001. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings.The 6th Natural Gas Conversion Symposium is conducted under the overall direction of the Organizing Committee. The Program Committee was responsible for the review, selection, editing of most of the manuscripts included in this volum. A standing International Advisory Board has ensured the effective long-term planning and the continuity and technical excellence of these meetings.




Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities


Book Description

Energy and feedstock materials for the chemical industry are in increasing demand and, with constraints related to the availability and use of oil, the energy and chemical industry is undergoing considerable changes. In recent years, major restructuring has occurred in the oil, petrochemical, and chemical industry, with increasing attention devoted to the use of natural gas, methane in particular, as a chemical feedstock rather than just as a fuel. The conversion of remote natural gas into liquid fuels or other transportable chemicals is a challenge to industrial catalysis. Few processes exist so far with the major ones involving the conversion of natural gas to synthesis gas by steam reforming, CO2 reforming, or partial oxidation, followed by the syntheses of methanol, hydrocarbons (Fischer-Tropsch synthesis), or ammonia. In this book, a comprehensive overview of the field of processing natural gas is given, through a series of chapters written by leading scientists and engineers in the field. New developments are discussed and current work relevant to the area is shown by a series of recent works by researchers working in this and related fields.




Methane Conversion


Book Description

This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered.The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.




Integrated Gasification Combined Cycle (IGCC) Technologies


Book Description

Integrated Gasification Combined Cycle (IGCC) Technologies discusses this innovative power generation technology that combines modern coal gasification technology with both gas turbine and steam turbine power generation, an important emerging technology which has the potential to significantly improve the efficiencies and emissions of coal power plants. The advantages of this technology over conventional pulverized coal power plants include fuel flexibility, greater efficiencies, and very low pollutant emissions. The book reviews the current status and future developments of key technologies involved in IGCC plants and how they can be integrated to maximize efficiency and reduce the cost of electricity generation in a carbon-constrained world. The first part of this book introduces the principles of IGCC systems and the fuel types for use in IGCC systems. The second part covers syngas production within IGCC systems. The third part looks at syngas cleaning, the separation of CO2 and hydrogen enrichment, with final sections describing the gas turbine combined cycle and presenting several case studies of existing IGCC plants. - Provides an in-depth, multi-contributor overview of integrated gasification combined cycle technologies - Reviews the current status and future developments of key technologies involved in IGCC plants - Provides several case studies of existing IGCC plants around the world




Polygeneration Systems


Book Description

The support for polygeneration lies in the possibility of integrating different technologies into a single energy system, to maximize the utilization of both fossil and renewable fuels. A system that delivers multiple forms of energy to users, maximizing the overall efficiency makes polygeneration an emerging and viable option for energy consuming industries. Polygeneration Systems: Design, Processes and Technologies provides simple and advanced calculation techniques to evaluate energy, environmental and economic performance of polygeneration systems under analysis. With specific design guidelines for each type of polygeneration system and experimental performance data, referred both to single components and overall systems, this title covers all aspects of polygeneration from design to operation, optimization and practical implementation. Giving different aspects of both fossil and non-fossil fuel based polygeneration and the wider area of polygeneration processes, this book helps readers learn general principles to specific system design and development through analysis of case studies, examples, simulation characteristics and thermodynamic and economic data. - Detailed economic data for technology to assist developing feasibility studies regarding the possible application of polygeneration technologies - Offers a comprehensive list of all current numerical and experimental results of polygeneration available - Includes simulation models, cost figures, demonstration projects and test standards for designers and researchers to validate their own models and/or to test the reliability of their results




Natural Gas Conversion V


Book Description

On January 1988, the ascertained and economically accessible reserves of Natural Gas (NG) amounted to over 144,000 billion cubic meters worldwide, corresponding to 124 billion tons of oil equivalents (comparable with the liquid oil reserves, which are estimated to be 138 billion TOE). It is hypothesized that the volume of NG reserve will continue to grow at the same rate of the last decade. Forecasts on production indicate a potential increase from about 2,000 billion cubic meters in 1990 to not more than 3,300 billion cubic meters in 2010, even in a high economic development scenario. NG consumption represents only one half of oil: 1.9 billion TOE/y as compared to 3.5 of oil. Consequently, in the future gas will exceed oil as a carbon atom source. In the future the potential for getting energetic vectors or petrochemicals from NG will continue to grow.The topics covered in Natural Gas Conversion V reflect the large global R&D effort to look for new and economic ways of NG exploitation. These range from the direct conversion of methane and light paraffins to the indirect conversion through synthesis gas to fuels and chemicals. Particularly underlined and visible are the technologies already commercially viable.These proceedings prove that mature and technologically feasible processes for natural gas conversion are already available and that new and improved catalytic approaches are currently developing, the validity and feasibility of which will soon be documented. This is an exciting area of modern catalysis, which will certainly open novel and rewarding perspectives for the chemical, energy and petrochemical industries.