Clusters and Colloids


Book Description

This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.




Spin-Crossover Materials


Book Description

The phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved. Spin-Crossover Materials: Properties and Applications presents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics including Spin-crossover in mononuclear, polynuclear and polymeric complexes Structure: function relationships in molecular spin-crossover materials Charge-transfer-induced spin-transitions Reversible spin-pairing in crystalline organic radicals Spin-state switching in solution Spin-crossover compounds in multifunctional switchable materials and nanotechnology Physical and theoretical methods for studying spin-crossover materials Spin-Crossover Materials: Properties and Applications is a valuable resource for academic researchers working in the field of spin-crossover materials and topics related to crystal engineering, solid state chemistry and physics, and molecular materials. Postgraduate students will also find this book useful as a comprehensive introduction to the field.




Spin Glasses


Book Description

The phase of condensed matter known as spin glasses has become a vital and productive area of research. Historically, experiment has suggested unusual effects which have brought the theoretical study of the spin Glass Problem Onto The Same Footing As The Experimental Study. Experiments in the late 1960s on magnetic alloys presented interesting effects which were difficult to explain. It took until the mid 1970s for new developments in condensed matter theory to reveal that a sharp phase transition was at the root of the phenomenon. John Mydosh tells the story of the spin glasses in a phenomenological way. He describes these materials first from the premise of an experiment, using figures and tables rather than equations and derivations. This empirical approach then leads to recent advances in finding and measuring spin glasses which closely mimic the theoretical models. The author describes spin glasses as a state of magnetic ordering in third place after ferromagnetism and antiferromagnetism. He also pays heed to the importance of amorphous or glassy materials in contemporary physics while also describing the richness of analogues with many areas of research from astrophysics via molecular evolution to zoology.




Phase Diagram and Magnetic Excitations of BaFe2-xNixAs2: A Neutron Scattering Study


Book Description

This book studies the structural, magnetic and electronic properties of, as well as magnetic excitations in, high-temperature BaFe2-xNixAs2 superconductors using neutron diffraction and neutron spectroscopic methods. It describes the precise determination of the phase diagram of BaFe2-xNixAs2, which demonstrates strong magnetoelastic coupling and avoided quantum criticality driven by short-range incommensurate antiferromagnetic order, showing cluster spin glass behavior. It also identifies strong nematic spin correlations in the tetragonal state of uniaxial strained BaFe2-xNixAs2. The nematic correlations have similar temperature and doping dependence as resistivity anisotropy in detwinned samples, which suggests that they are intimately connected. Lastly, it investigates doping evolution of magnetic excitations in overdoped BaFe2-xNixAs2 and discusses the links with superconductivity. This book includes detailed neutron scattering results on BaFe2-xNixAs2 and an introduction to neutron scattering techniques, making it a useful guide for readers pursuing related research.




Neutron Scattering - Magnetic and Quantum Phenomena


Book Description

Neutron Scattering - Magnetic and Quantum Phenomena provides detailed coverage of the application of neutron scattering in condensed matter research. The book's primary aim is to enable researchers in a particular area to identify the aspects of their work where neutron scattering techniques might contribute, conceive the important experiments to be done, assess what is required to carry them out, write a successful proposal for one of the major user facilities, and perform the experiments under the guidance of the appropriate instrument scientist. An earlier series edited by Kurt Sköld and David L. Price, and published in the 1980s by Academic Press as three volumes in the series Methods of Experimental Physics, was very successful and remained the standard reference in the field for several years. This present work has similar goals, taking into account the advances in experimental techniques over the past quarter-century, for example, neutron reflectivity and spin-echo spectroscopy, and techniques for probing the dynamics of complex materials of technological relevance. This volume complements Price and Fernandez-Alonso (Eds.), Neutron Scattering - Fundamentals published in November 2013. - Covers the application of neutron scattering techniques in the study of quantum and magnetic phenomena, including superconductivity, multiferroics, and nanomagnetism - Presents up-to-date reviews of recent results, aimed at enabling the reader to identify new opportunities and plan neutron scattering experiments in their own field - Provides a good balance between theory and experimental techniques - Provides a complement to Price and Fernandez-Alonso (Eds.), Neutron Scattering - Fundamentals published in November 2013




Magnetic Neutron Scattering: Proceedings Of The Third Summer School On Neutron Scattering


Book Description

The proceedings provide a topical survey of the static and dynamical magnetic properties of condensed matter studied by neutron scattering which has been the key technique in this field for a long time. The static aspects deal with the determination of long-range ordered spin structures and magnetization densities. The dynamic aspects concentrate on the determination of magnetic excitations such as spin waves and crystal-field transitions. The use of polarized-neutron techniques is particularly emphasized. All these topics are thoroughly introduced, methodically discussed, and highlighted with recent experimental results obtained for a vast variety of magnetic materials (e.g., strongly correlated electron systems, multilayers, nanocrystals, molecular complexes, etc.) by acknowledged experts. Other experimental methods (x-ray scattering, muon spin rotation) in the study of magnetism are compared to neutron scattering.




Complementarity Between Neutron And Synchrotron X-ray Scattering - Proceedings Of The Sixth Summer School Of Neutron Scattering


Book Description

Understanding and manipulating the properties of materials naturally occurring in our world and artificially produced by modern technologies requires detailed information on their properties on the atomic scale. This information is the basis for any kind of research in physics, chemistry, biology, engineering, metallurgy, and ceramics. Among the various experimental methods, neutron and photon scattering have become the key techniques of choice.This book provides an overview of the complementarity between neutron and synchrotron x-ray scattering. The most important topics are covered, including structure determination, magnetic correlations, polymer dynamics, thin films and multilayers, photoemission studies, etc; they are thoroughly introduced and discussed by experts from both the experimental and the theoretical side.




Neutron Scattering


Book Description

Neutron Scattering




Neutron Scattering from Magnetic Materials


Book Description

Neutron Scattering from Magnetic Materials is a comprehensive account of the present state of the art in the use of the neutron scattering for the study of magnetic materials. The chapters have been written by well-known researchers who are at the forefront of this field and have contributed directly to the development of the techniques described. Neutron scattering probes magnetic phenomena directly. The generalized magnetic susceptibility, which can be expressed as a function of wave vector and energy, contains all the information there is to know about the statics and dynamics of a magnetic system and this quantity is directly related to the neutron scattering cross section. Polarized neutron scattering techniques raise the sophistication of measurements to even greater levels and gives additional information in many cases. The present book is largely devoted to the application of polarized neutron scattering to the study of magnetic materials. It will be of particular interest to graduate students and researchers who plan to investigate magnetic materials using neutron scattering.· Written by a group of scientist who have contributed directly in developing the techniques described.· A complete treatment of the polarized neutron scattering not available in literature.· Gives practical hits to solve magnetic structure and determine exchange interactions in magnetic solids.· Application of neutron scattering to the study of the novel electronic materials.