Ion Exchange in Analytical Chemistry


Book Description

Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.




Ion Exchange in Analt Chemistry


Book Description

The aim of this rare volume is to provide up-to-the-minute coverage of the many applications of ion exchange in analytical chemistry. This work places major emphasis on modern high-resolution chromatography, and also includes the analysis of proteins and biological macromolecules. The easy-to-read text gives a general account of ion exchangers, their properties and how they are made, as well as a brief account of the physical chemistry of classical microporous ion-exchanging polymers. Organized by methods and techniques, this one-of-a-kind book describes each technique using illustrations by representative applications. This interesting review also compares ion-exchange methods with other methods of accomplishing the same analyses. It addresses many new areas in this field, including such exciting topics as pulsed amperometric detection of carbohydrates, amino acids, and peptides; chromatography of carbohydrates by anion exchange; and methods of polymer synthesis. Everyone who has an interest in analytical chemistry, chromatography, reactive polymers, and chromatographic science will want to add this reference to their collection of up-to-date resources.




Ion Exchange in Analytical Chemistry


Book Description

Ion Exchange in Analytical Chemistry ...




Applications of Ion Exchange Materials in Chemical and Food Industries


Book Description

This book presents the applications of ion-exchange materials in the chemical and food industries. It includes topics related to the application of ion exchange chromatography in water softening, purification and separation of chemicals, separation and purification of food products and catalysis. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.




Ion Chromatography


Book Description

Bewitched is an odd word with which to begin a chemical textbook. Yet that is a fair description of how I reacted on first leaming of ion exchange and imagining what might be done with it. That initial fascination has not left me these many years later, and it has provided much ofthe motivation for writing this book. The perceived need for a text on the fundamentals of ion chromatography provided the rest. Many readers will have a general idea of what ion chromatography is and what it does. Briefly, for those who do not, it is an umbrella term for a variety of chromatographie methods for the rapid and sensitive analysis of mixtures of ionic species. It has become highly developed in the last decade, and while it is now routinely used for the determination of organic as weH as inorganic ions, its initial impact was greatest in the area of inorganic analysis. In the past the determination of inorganic ions, particularly anions, meant laborious, time-con suming, and often not very sensitive "wet chemieal" methods. In the last ten years that has changed radically as ion chromatography has supplanted these older methods.




Encyclopedia of Geochemistry


Book Description

The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.




Chemical Separations


Book Description

This laboratory manual and reference provides a working knowledge of an array of separation methods via detailed coverage of the principles, equipment and techniques involved, with an emphasis on everyday practice rather than theory.







Ion Exchange and Solvent Extraction


Book Description

Volume 17 in the Ion Exchange and Solvent Extraction series represents the vanguard of research on solvent extraction. It covers the principles of electrolyte extraction and other subjects of increasing interest to the field. This volume begins with pharmaceutical applications of supercritical fluid solvents, particularly supercritical carbon dioxide. It also contains chapters on liquid ion exchangers and relevant experiment protocols, SCF applications in drug formulation and pollution reduction, exploiting SCF as reaction media, applications of metal bis(dicarbollide) in analytical chemistry and radioactive waste treatment, and synergistic extraction of metal ions. Volume 17 discusses the ion exchange isothermal supersaturation technique, metal separation via pH-induced parametric pumping, modeling of ion exchange kinetics for ultrapure water, and the engineering of activated carbons and carbonaceous materials for removal of metal ions and organic micropollutants in water. Volume 17 cover topics that include supercritical fluid applications, applications of metal bis(dicarbollide), and synergistic extraction of metal ions.




Ion Exchange


Book Description

This book provides broad coverage of ion exchange and its applications. Different chapters focus on the importance of ion exchange applications such as strengtening dental porcelains, gradient changes in glass refraction, and resins as effective sorbents. Each chapter includes a brief historical overview of ion exchange and its applications. The authors also give a brief overview of these applications as well as review current experimental data on the subject.