Author : N. M. Emanuel'
Publisher : Elsevier
Page : 425 pages
File Size : 43,46 MB
Release : 2013-11-19
Category : Science
ISBN : 1483149250
Approx.424 pages
Author : N. M. Emanuel
Publisher : Elsevier
Page : 628 pages
File Size : 15,75 MB
Release : 2013-10-22
Category : Science
ISBN : 1483145115
Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.
Author : R. A. Sheldon
Publisher : John Wiley & Sons
Page : 448 pages
File Size : 25,64 MB
Release : 2007-06-27
Category : Science
ISBN : 3527611010
This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: · Numerous catalytic reductions and oxidations methods · Solid-acid and solid-base catalysis · C-C bond formation reactions · Biocatalysis · Asymmetric catalysis · Novel reaction media like e.g. ionic liquids, supercritical CO2 · Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.
Author : A.E. Shilov
Publisher : Springer Science & Business Media
Page : 226 pages
File Size : 24,52 MB
Release : 1984-06-30
Category : Science
ISBN : 9789027716286
Author : Evgeny T. Denisov
Publisher : CRC Press
Page : 1020 pages
File Size : 45,32 MB
Release : 2005-03-29
Category : Medical
ISBN : 142003085X
Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information
Author : Shannon S. Stahl
Publisher : John Wiley & Sons
Page : 454 pages
File Size : 17,8 MB
Release : 2016-10-10
Category : Technology & Engineering
ISBN : 3527337814
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Author : Daniel Duprez
Publisher : World Scientific
Page : 1035 pages
File Size : 40,46 MB
Release : 2014-07-24
Category : Science
ISBN : 1783263342
This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.
Author : David Azbel
Publisher : Cambridge University Press
Page : 372 pages
File Size : 33,54 MB
Release : 1981-08-31
Category : Science
ISBN : 9780521237727
The behaviour of bubbles is a unifying theme of this book. From an explanation of the fundamentals of bubbles formation at a single orifice, Dr Azbel goes on to set up equations for bubble motion, bubble size, bubble-size distribution and pressure drop across a perforated plate.
Author : Philippe Arpentinier
Publisher : Editions TECHNIP
Page : 490 pages
File Size : 42,68 MB
Release : 2001
Category : Science
ISBN : 9782710807773
Volume 1 covers the most important technological aspects of the use of molecular oxygen for catalytic oxidation reactions.Volume 2 addresses the safety issues associated with the use of oxygen in catalytic oxidation reactions.Contents Vol. 1: 1. Introduction. 2. Chemical-physical properties of molecular oxygen. 3. Oxygen production technologies. 4. Chemical fundamentals of oxidation reactions. 5. Reactor technologies for multiphase systems. 6. Liquid phase oxidations. 7. Gas phase selective oxidations. 8. Selective oxidation of paraffins. References. Index. Vol. 2: 9. Introduction to safety problems in the chemical industry. 10. Chemical aspects of combustion in the gaseous phase. 11. Homogeneous chemical explosions: autoignition or spontaneous ignition. 12. Deflagration or propagation of flame. 13. Conditions governing flame propagation capability. 14. Detonation in the gaseous phase. 15. Prevention of and protection against explosions. References. Index.
Author : D.M. Bibby
Publisher : Elsevier
Page : 759 pages
File Size : 25,80 MB
Release : 1988-03-01
Category : Technology & Engineering
ISBN : 0080960707
This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered.The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.
