New Trends in CO Activation


Book Description

The aim of this volume is to provide scientists with a comprehensive summary of new research areas in the activation of carbon monoxide, as one of the most reactive molecules, and in its applications. In order to understand the variety of the reactivity of CO, a quantum-chemical approach helps the reader to understand the binding state of CO to the solid surface (Chapter 1). The structure of the adsorbed CO can be better understood by examining its reactivity towards single crystals in the absence and in the presence of promoters (Chapter 2). The first approach in the reactivity study is that of studying catalytic activity of single crystals and structure sensitivity which are summarized in Chapter 3. One of the most prominent effects in the CO activation process is ascribed to the presence of additives, promoters which, in a real catalyst system, are far more complicated than on single crystal surfaces (Chapter 4). The original Fischer-Tropsch process applied fused iron or cobalt catalysts which were suitable for producing mainly straight chain hydrocarbons. The two most important processes involving CO activation, the new FT process and alcohol formation are discussed in Chapters 5 and 7. An important type of catalyst, the bimetallic catalysts, is discussed in Chapter 6. The role of hydrogen as one of the most frequently used partners in CO activation is discussed in Chapter 8. The field of production of specialty chemicals is an excellent example of the homogeneous catalytic activation of CO (Chapter 9). In Chapter 10 an overview is given of the industrial applications of CO chemistry and these are illustrated by working processes. The final chapter gives the reader some hints about future progress in the field.







Introduction to Zeolite Science and Practice


Book Description

In view of the substantial progress made in the last decade in the fields of zeolites and related materials it was decided to go for an extended 2nd Edition of "Introduction to Zeolite Science and Practice". Unfortunately - as often is the case - this process took more time than expected by the Editors.In the mean time some new texts on zeolites were issued. Nevertheless, the combination of data, discussion and dedication provided by the present book is a unique coverage of the field, in the opinion of the Editors.In the present Edition the number of chapters rose from 16-22. The contributions can be divided into three categories: updated chapters by the original authors, updated chapters by an expanded or new team of authors and completely new chapters. This 2nd Edition also contains new chapters on "Zeolite-based supramolecular assemblies" (by Dirk De Vos and Pierre Jacobs, experts in this area) and on "The use of bulky probe molecules" (by Paul Kunkeler, Roger Downing and one of the Editors).Finally, the super large pore zeolites and the fast growing area of ordered mesoporous materials are dealt with by Eelco Vogt, Charlie Kresge and and Jim Vartuli. The latter two authors belong to the discoverers of the M41S family of mesoporous materials.




Preparation of Catalysts VII


Book Description

The proceedings of the VIIth International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, are in line with the general scope of this series of events. Emphasis in all Symposia has been on the scientific aspects of the preparation of new and industrial catalysts, or on new methods of preparation, rather than on the catalytic reactions in which such solids are ultimately used. In the present context, the catalytic event itself has only been considered as another, though often decisive, method of catalyst characterization.




Applications in Industry


Book Description

Volume I contains a brief review of adsorption history and its development for practical purposes up until now. It also presents some important information on adsorbents and catalysts as well as on the methods of their characterization. The part of this volume dealing with practical industrial applications includes chapters presenting advanced technical tools for high capacity adsorption separation of liquid and gas mixtures, development of new adsorbents for removal of hazardous contaminants from combustion flue gases and wastewaters, degasification of coal seams and fabrication of inorganic membranes and their applications. A comprehensive review is also included on contemporary utility of self-assembled monolayers, adsorption proteins and their role in modern industry, adsorption methods in technology of optical fibre glasses, sol-gel technology, solid desiccant dehumidification systems, etc. The articles give both the scientific backgrounds of the phenomena discussed and emphasize their practical aspects.The chapters give not only brief current knowledge about the studied problems, but are also a source of topical literature on the subject. A comprehensive bibliography on adsorption principles, design data and adsorbent materials for industrial applications for the period 1967-1997 concludes the book.




Fischer-Tropsch Technology


Book Description

Fischer-Tropsch Technology is a unique book for its state-of-the-art approach to Fischer Tropsch (FT) technology. This book provides an explanation of the basic principles and terminology that are required to understand the application of FT technology. It also contains comprehensive references to patents and previous publications. As the first publication to focus on theory and application, it is a contemporary reference source for students studying chemistry and chemical engineering. Researchers and engineers active in the development of FT technology will also find this book an invaluable source of information. * Is the first publication to cover the theory and application for modern Fischer Tropsch technology * Contains comprehensive knowledge on all aspects relevant to the application of Fischer Tropsch technology* No other publication looks at past, present and future applications




Porous Materials in Environmentally Friendly Processes


Book Description

To leave our planet liveable in the next millennium mankind is forced to find environmentally friendly ways in solving the problems of everyday life. Among others, technologies of producing chemicals, absolutely necessary for maintaining a comfortable life, have to be modified, in some instances fundamentally changed now, or in the very near future.Developing new technologies requires strong and innovative fundamental research. In order to provide opportunity for crossfertilization the Federation of European Zeolite Associations (FEZA) decided to organise a conference, where researchers from academia as well as industry can meet, exchange ideas, show and discuss research efforts and results concerning the development of environmentally friendly processes and technologies.The conference, and thus the proceedings are divided into two main parts. The first part contains works concerning the synthesis, modification and characterisation of zeolitic materials as catalyst candidates in environmentally friendly technologies. Works in the second part describe various applications starting from developing highly selective reactions for the fine chemical industry, through waste-water treatment to applying zeolite for formulating bacteria for pest control.




Methods for Monitoring and Diagnosing the Efficiency of Catalytic Converters


Book Description

The dramatic evolution of catalytic converters in the last thirty years was a result of a need worldwide to reduce pollution created by the exhaust gases of internal combustion engines. Environmental concerns have led American, Japanese and European Union (EU) legislation to pose continuously stricter emission limits for petrol engines in the last decades. The catalytic converter has become the most important means of exhaust treatment to achieve the desired emission limits. The international legislation has also created a need for a regular assessment of the efficiency of the catalytic converter in order to detect a deterioration of its conversion efficiency as soon as this deterioration takes place. The assessment of conversion efficiency of a catalytic converter can take place during normal driving of a vehicle (on-board diagnosis or OBD) or in a workshop by specialized technicians. The most important methods nowadays are the OBD methods. The evolution of methods concerned with OBD and non-OBD monitoring and diagnosing of efficiency of catalytic converters of internal combustion engines is described based on patents and published patent applications. Non-patent references are also used. The basic principles of modern catalytic converters are described in an extensive Introduction, where the importance of monitoring and diagnosing the efficiency of catalytic converters is demonstrated. The book is divided into four parts. The first part describes methods involving the use of oxygen or air/fuel exhaust gas sensors to determine the oxygen storage capacity of a catalytic converter. The second part describes methods involving the use of temperature sensors to determine the exothermic reaction capacity of a catalytic converter. The third part describes all other methods existing in patent literature that monitor and diagnose the efficiency of catalytic converters. The great majority of the methods of the third part involves exhaust gas concentration measurements. The fourth part comprises a general discussion of all methods described. In the beginning of each part, a short introduction is given to explain the problem that the methods attempt to solve. The methods in each part are presented in chronological order per patent applicant. This helps to evaluate how the patent applicant has improved his methods over time. A patent number index with information about the patent applicants, inventors, priorities and patent-families, an inventor index, a company index and a subject index can be found at the end of the book.




Scientific Bases for the Preparation of Heterogeneous Catalysts


Book Description

This volume of Studies in Surface Science and Catalysis contains the Proceedings of the 9th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, held on the campus of the "Universit catholique de Louvain" (UCL) in Louvain-la-Neuve, Belgium, on September 10-14, 2006. This series of symposia was initiated in 1975 on a regular 4-year interval basis. The Symposium covered the following topics: key aspects in catalysts preparation, micro- and mesoporous supports, supported metal catalysts, structured catalysts, tailored zeolites, catalysis by bases, and catalysts for fuel production. These topics served as guidelines for the sessions both in the programs of oral communications (41 contributions including 7 keynote communications – one for each topic) and poster presentations (101 contributions). In addition, the opening invited lecture addressed the question of scaling-up high-throughput experimental approaches.* Contains a collection of the papers presented at the workshop




Hydrotreatment and Hydrocracking of Oil Fractions


Book Description

The 2nd International Symposium on Hydrotreatment and Hydrocracking of Oil Fractions, which is also the 7th in the series of European Workshops on Hydrotreatment, took place in Antwerpen, Belgium from November 14 to 17. The Symposium emphasized how oil refining faces increasingly severe environmental regulations. These and the increasing application of heavier crudes containing more S-, N- and metal components call for more efficient hydrotreatment and hydrocracking processes. It is clear from the keynote lectures, the oral contributions and the posters of this meeting that adapting the operating conditions will not suffice. Adequate catalysts need to be developed, with different composition and structure. Surface science techniques and molecular modeling are now well established tools for such a development. They should be of help in widely different aspects, like the role of precursors in the preparation or the modifications undergone by the catalyst under reaction conditions. The improvement of hydrotreatment and hydrocracking also needs accurate modeling of the chemical reactor. This requires more representative hydrodynamics and kinetic models whose validity extends to the very low S- and N-contents. These areas should be vigorously developed.