Pb Organolead Compounds


Book Description

This volume is exclusively devoted to tetramethyllead. Owing to the recent large-scale use as an antiknock agent, its application, toxicological, biological, and environmental aspects are given much attention besides its chemical and physical properties. - Literature coverage up to 1986.




PB Organolead Compounds


Book Description




Pb Organolead Compounds


Book Description

The discovery in 1922 of the exceptional effectiveness of tetraethyllead in suppressing knock in the combustion of gasoline in engines and its introduction as a gasoline additive in 1923 stimulated an enormous number of studies on procedures for its synthesis and industrial production, on its behavior and uses, and also on the toxicology of this compound and on its environmental impact resulting from large scale lead distribution. The results of these investigations are collected in more than 3000 papers and patents. The quantity of information on this prominent compound fills the second volume of the series on organo lead compounds. Complete literature coverage was strived for but not all of the voluminous patent data have been considered. Certain publications on production of tetraethyllead or on use as a gasoline additive that are not reported in Chemical Abstracts (C.A.) may not have been found; similarly, publications that could not be clearly identified as relevant to the subject might be missing. Publications concerning the fate of inorganic lead compounds that are products of the combustion of leaded gasoline as weil as the vast amount of related papers on analytical and toxicological studies and on health and environmental aspects have been deliberately omitted. The literature is covered through 1988; C.A. has been evaluated through volume 110 of 1989.




Gmelin Handbook of Inorganic Chemistry


Book Description

The discovery in 1922 of the exceptional effectiveness of tetraethyllead in suppressing knock in the combustion of gasoline in engines and its introduction as a gasoline additive in 1923 stimulated an enormous number of studies on procedures for its synthesis and industrial production, on its behavior and uses, and also on the toxicology of this compound and on its environmental impact resulting from large scale lead distribution. The results of these investigations are collected in more than 3000 papers and patents. The quantity of information on this prominent compound fills the second volume of the series on organo lead compounds. Complete literature coverage was strived for but not all of the voluminous patent data have been considered. Certain publications on production of tetraethyllead or on use as a gasoline additive that are not reported in Chemical Abstracts (C.A.) may not have been found; similarly, publications that could not be clearly identified as relevant to the subject might be missing. Publications concerning the fate of inorganic lead compounds that are products of the combustion of leaded gasoline as weil as the vast amount of related papers on analytical and toxicological studies and on health and environmental aspects have been deliberately omitted. The literature is covered through 1988; C.A. has been evaluated through volume 110 of 1989.




Pb Organolead Compounds


Book Description

The discovery in 1922 of the exceptional effectiveness of tetraethyllead in suppressing knock in the combustion of gasoline in engines and its introduction as a gasoline additive in 1923 stimulated an enormous number of studies on procedures for its synthesis and industrial production, on its behavior and uses, and also on the toxicology of this compound and on its environmental impact resulting from large scale lead distribution. The results of these investigations are collected in more than 3000 papers and patents. The quantity of information on this prominent compound fills the second volume of the series on organo lead compounds. Complete literature coverage was strived for but not all of the voluminous patent data have been considered. Certain publications on production of tetraethyllead or on use as a gasoline additive that are not reported in Chemical Abstracts (C.A.) may not have been found; similarly, publications that could not be clearly identified as relevant to the subject might be missing. Publications concerning the fate of inorganic lead compounds that are products of the combustion of leaded gasoline as weil as the vast amount of related papers on analytical and toxicological studies and on health and environmental aspects have been deliberately omitted. The literature is covered through 1988; C.A. has been evaluated through volume 110 of 1989.







Biological Effects of Organolead Compounds


Book Description

First published in 1984: This book is a compilation of research on Organolead Compounds.




Tetraalkyllead, Tetraaryllead


Book Description

The present volume on organolead compounds deals with about 130 compounds of the type PbR4 (R = CH3, C2H5) in which the lead atom is surrounded by four identical ligands, including symmetrical spiro compounds. Also four perfluorinated compounds are known. The first two volumes of the series exclusively describe Pb(CH3)4 and Pb(C2H5)4. Like the methyl and ethyl derivatives, PbR4 compounds with R = C3H7 and C4H9 have been extensively tested for their possible use as antiknock agents in combustion engines; sporadically, other PbR4 compounds have also been studied for this purpose. The emphasis is on Pb(C6H5)4, a key compound in organolead chemistry. About 40 pages deal with the chemical behaviour of this species. It often serves as a C6H5 source for the formation of other aryl compounds of main group elements and transition metals. It is the one PbR4-type compound which itself can serve as a ligand in transition metal chemistry. This comprehensive compilation also identifies gaps compared to the chemistry of other group 14 compounds; this could stimulate further studies. For instance, lead compounds with cyclopentadienyl ligands are missing as well as numerous species with bulkier R groups which are known with the lower homologues Sn or Ge. A formula index completes the volume.




Pb


Book Description




Organolead compounds


Book Description