Prussian Blue-Type Nanoparticles and Nanocomposites: Synthesis, Devices, and Applications


Book Description

Nanochemistry tools aid the design of Prussian blue and its analogue nanoparticles and nanocomposites. The use of such nanomaterials is now widely regarded as an alternative to other inorganic nanomaterials in a variety of scientific applications. This book, after addressing Prussian blue and its analogues in a historical context and their numerous applications over time, compiles and details the latest cutting-edge scientific research on these nanomaterials. It compiles and deatils the latest cutting-edge scientific research on these nanomaterials. The book provides an overview of the methodological concepts of the nanoscale synthesis of Prussian blue and its analogues, as well as the study and understanding of their properties and of the extent and diversity of application fields in relation to the major societal challenges of the 21st century on energy, environment, and health.




Biosensors – Recent Advances and Future Challenges


Book Description

The present book is devoted to all aspects of biosensing in a very broad definition, including, but not limited to, biomolecular composition used in biosensors (e.g., biocatalytic enzymes, DNAzymes, abiotic nanospecies with biocatalytic features, bioreceptors, DNA/RNA, aptasensors, etc.), physical signal transduction mechanisms (e.g., electrochemical, optical, magnetic, etc.), engineering of different biosensing platforms, operation of biosensors in vitro and in vivo (implantable or wearable devices), self-powered biosensors, etc. The biosensors can be represented with analogue devices measuring concentrations of analytes and binary devices operating in the YES/NO format, possibly with logical processing of input signals. Furthermore, the book is aimed at attracting young scientists and introducing them to the field, while providing newcomers with an enormous collection of literature references.




Hybrid Organic-Inorganic Interfaces


Book Description

Hybrid organic-inorganic materials and the rational design of their interfaces open up the access to a wide spectrum of functionalities not achievable with traditional concepts of materials science. This innovative class of materials has a major impact in many application domains such as optics, electronics, mechanics, energy storage and conversion, protective coatings, catalysis, sensing and nanomedicine. The properties of these materials do not only depend on the chemical structure, and the mutual interaction between their nano-scale building blocks, but are also strongly influenced by the interfaces they share. This handbook focuses on the most recent investigations concerning the design, control, and dynamics of hybrid organic-inorganic interfaces, covering: (i) characterization methods of interfaces, (ii) innovative computational approaches and simulation of interaction processes, (iii) in-situ studies of dynamic aspects controlling the formation of these interfaces, and (iv) the role of the interface for process optimization, devices, and applications in such areas as optics, electronics, energy and medicine.




Na-ion Batteries


Book Description

This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.




Molecular Magnetism


Book Description

Highly regarded and historic book covers basic concepts of magnetization and magnetic susceptibility, establishes the fundamental equations of molecular magnetism, and examines molecules containing a unique magnetic center. 2019 edition.




Advances in Nanotechnology Research and Application: 2011 Edition


Book Description

Advances in Nanotechnology Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Nanotechnology. The editors have built Advances in Nanotechnology Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Nanotechnology in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Advances in Nanotechnology Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.




Metal-Organic Framework Nanocomposites


Book Description

Metal-Organic Framework Nanocomposites: From Design to Application assembles the latest advances in MOF nanocomposites, emphasizing their design, characterization, manufacturing, and application and offering a wide-ranging view of these materials with exceptional physical and chemical properties. FEATURES Discusses various types of MOF materials, such as polyaniline MOF nanocomposites, magnetic MOF nanocomposites, and carbon nanotube-based MOF nanocomposites Includes chapters on the usage of these materials in pollutant removal, electrochemical devices, photocatalysts, biomedical applications, and other applications Covers different aspects of composite fabrication from energy storage and catalysts, including preparation, design, and characterization techniques Emphasizes the latest technology in the field of manufacturing and design Aimed at researchers, academics, and advanced students in materials science and engineering, this book offers a comprehensive overview and analysis of these extraordinary materials.




Towards a Better Understanding of Prussian Blue Nanoparticles: Bulk and Single Nanoparticle Electro Chemistry and Computational Studies


Book Description

Prussian blue and its analogues have been widely applied in the field of environment, energy, catalysis and sensor fabrication. In addition, they are very economical composed of low-cost abundant metals. To better understand their properties and working mechanisms, we carried out research work in three areas. Our first approach was the modification of the screen-printed carbon electrode (SPCE) with Prussian blue nanoparticles synthesized using two different couples of precursors with two different ratios and the analysis of their electrochemical performance by using cyclic voltammetry. SPCE modified with 20 layers of Prussian blue nanoparticles prepared by using potassium ferricyanide and ferrous chloride as precursors and polyvinyl pyrrolidone (PVP) as the surfactant with ratio [PVP] / [Fe2+]=11/40, produced the best results with a sensitivity of 6ÎơA8́9mM-1to hydrogen peroxide. Secondly, we successfully investigated single Prussian blue nanoparticle electrochemistry by electrochemical surface plasmon resonance microscopy technique before and after the addition of hydrogen peroxide. Lastly, computational studies were also performed to study the structural and electronic properties of Prussian blue, Prussian white, ferric hexacyanide and ferrous hexacyanide using NWChem ab initio computational chemistry software package. We successfully optimized ferric hexacyanide and ferrous hexacyanide at all three level of theories. We were able to optimize high and low spin Prussian blue at Hartree-Fock and Prussian white at the Hartree-Fock and density functional theory (DFT) level of theory for Becke, 3parameter, Lee-Yang-Parr (B3LYP) and density functional theory (DFT) and Minnesota 2006 local functionals (UM06-L) were combined with the 6-311G* basis set. These computational studies will significantly help to design Prussian blue analogues sensors tailored with higher capabilities for the reduction of hydrogen peroxide.




Nanozymes: Next Wave of Artificial Enzymes


Book Description

This book describes the fundamental concepts, the latest developments and the outlook of the field of nanozymes (i.e., the catalytic nanomaterials with enzymatic characteristics). As one of today’s most exciting fields, nanozyme research lies at the interface of chemistry, biology, materials science and nanotechnology. Each of the book’s six chapters explores advances in nanozymes. Following an introduction to the rise of nanozymes research in the course of research on natural enzymes and artificial enzymes in Chapter 1, Chapters 2 through 5 discuss different nanomaterials used to mimic various natural enzymes, from carbon-based and metal-based nanomaterials to metal oxide-based nanomaterials and other nanomaterials. In each of these chapters, the nanomaterials’ enzyme mimetic activities, catalytic mechanisms and key applications are covered. In closing, Chapter 6 addresses the current challenges and outlines further directions for nanozymes. Presenting extensive information on nanozymes and supplemented with a wealth of color illustrations and tables, the book offers an ideal guide for readers from disparate areas, including analytical chemistry, materials science, nanoscience and nanotechnology, biomedical and clinical engineering, environmental science and engineering, green chemistry, and novel catalysis.




Bio Monomers for Green Polymeric Composite Materials


Book Description

Presents new and innovative bio-based monomers to replace traditional petrochemical-based building blocks Featuring contributions from top experts in the field, this book discusses new developments in the area of bio monomers and green polymeric composite materials. It covers bio monomers, green polymeric composites, composites from renewable resources, bio-sourced polymers, green composites, biodegradation, processing methods, green polymeric gels, and green polymeric membranes. Each chapter in Bio Monomers for Green Polymeric Composites Materials presents the most recent research and technological ideas in a comprehensive style. It examines bio monomers for green polymer and the processing methods for the bio nanocomposites. It covers the preparation, characterization, and applications of bio-polymeric materials based blends, as well as the applications of biopolymeric gels in medical biotechnology. The book also explores the properties and applications of gelatins, pectins, and carrageenans gels. Additionally, it offers a plethora of information on green polymeric membranes; the bio-degradation of green polymeric composites materials; applications of green polymeric composites materials; hydrogels used for biomedical applications; and the use of natural aerogels as thermal insulations. Introduces readers to the innovative, new bio-based monomers that are taking the place of traditional petrochemical-based building blocks Covers green polymers, green composites, bio-sourced polymers, bio nanocomposites, biodegradable polymers, green polymer gels, and membranes Features input from leading researchers immersed in the area of study Bio Monomers for Green Polymeric Composites Materials is suitable for academics, researchers, scientists, engineers and advanced students in the field of bio monomers and green polymeric composites materials.