Fundamentals and Applications of Supercritical Carbon Dioxide (SCO2) Based Power Cycles


Book Description

Fundamentals and Applications of Supercritical Carbon Dioxide (SCO2) Based Power Cycles aims to provide engineers and researchers with an authoritative overview of research and technology in this area. Part One introduces the technology and reviews the properties of SCO2 relevant to power cycles. Other sections of the book address components for SCO2 power cycles, such as turbomachinery expanders, compressors, recuperators, and design challenges, such as the need for high-temperature materials. Chapters on key applications, including waste heat, nuclear power, fossil energy, geothermal and concentrated solar power are also included. The final section addresses major international research programs. Readers will learn about the attractive features of SC02 power cycles, which include a lower capital cost potential than the traditional cycle, and the compounding performance benefits from a more efficient thermodynamic cycle on balance of plant requirements, fuel use, and emissions. Represents the first book to focus exclusively on SC02 power cycles Contains detailed coverage of cycle fundamentals, key components, and design challenges Addresses the wide range of applications of SC02 power cycles, from more efficient electricity generation, to ship propulsion




Supercritical Carbon Dioxide Cycle Control Analysis


Book Description

This report documents work carried out during FY 2008 on further investigation of control strategies for supercritical carbon dioxide (S-CO2) Brayton cycle energy converters. The main focus of the present work has been on investigation of the S-CO2 cycle control and behavior under conditions not covered by previous work. An important scenario which has not been previously calculated involves cycle operation for a Sodium-Cooled Fast Reactor (SFR) following a reactor scram event and the transition to the primary coolant natural circulation and decay heat removal. The Argonne National Laboratory (ANL) Plant Dynamics Code has been applied to investigate the dynamic behavior of the 96 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) S-CO2 Brayton cycle following scram. The timescale for the primary sodium flowrate to coast down and the transition to natural circulation to occur was calculated with the SAS4A/SASSYS-1 computer code and found to be about 400 seconds. It is assumed that after this time, decay heat is removed by the normal ABTR shutdown heat removal system incorporating a dedicated shutdown heat removal S-CO2 pump and cooler. The ANL Plant Dynamics Code configured for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) was utilized to model the S-CO2 Brayton cycle with a decaying liquid metal coolant flow to the Pb-to-CO2 heat exchangers and temperatures reflecting the decaying core power and heat removal by the cycle. The results obtained in this manner are approximate but indicative of the cycle transient performance. The ANL Plant Dynamics Code calculations show that the S-CO2 cycle can operate for about 400 seconds following the reactor scram driven by the thermal energy stored in the reactor structures and coolant such that heat removal from the reactor exceeds the decay heat generation. Based on the results, requirements for the shutdown heat removal system may be defined. In particular, the peak heat removal capacity of the shutdown heat removal loop may be specified to be 1.1 % of the nominal reactor power. An investigation of the oscillating cycle behavior calculated by the ANL Plant Dynamics Code under specific conditions has been carried out. It has been found that the calculation of unstable operation of the cycle during power reduction to 0 % may be attributed to the modeling of main compressor operation. The most probable reason for such instabilities is the limit of applicability of the currently used one-dimensional compressor performance subroutines which are based on empirical loss coefficients. A development of more detailed compressor design and performance models is required and is recommended for future work in order to better investigate and possibly eliminate the calculated instabilities. Also, as part of such model development, more reliable surge criteria should be developed for compressor operation close to the critical point. It is expected that more detailed compressor models will be developed as a part of validation of the Plant Dynamics Code through model comparison with the experiment data generated in the small S-CO2 loops being constructed at Barber-Nichols Inc. and Sandia National Laboratories (SNL). Although such a comparison activity had been planned to be initiated in FY 2008, data from the SNL compression loop currently in operation at Barber Nichols Inc. has not yet become available by the due date of this report. To enable the transient S-CO2 cycle investigations to be carried out, the ANL Plant Dynamics Code for the S-CO2 Brayton cycle was further developed and improved. The improvements include further optimization and tuning of the control mechanisms as well as an adaptation of the code for reactor systems other than the Lead-Cooled Fast Reactor (LFR). Since the focus of the ANL work on S-CO2 cycle development for the majority of the current year has been on the applicability of the cycle to SFRs, work has started on modification of the ANL Plant Dynamics Code to allow the dynamic simulation of the ABTR. The code modifications have reached the point where a transient simulation can be run in steady state mode; i.e., to determine the steady state initial conditions at full power without an initiating event. The results show that the steady state solution is maintained with minimal variations during at least 4,000 seconds of the transient. More SFR design specific modifications to the ANL Plant Dynamics Code are required to run the code in a full transient mode, including models for the sodium pumps and their control as well as models for reactivity feedback and control of the reactor power.




Analysis of Supercritical CO2 Cycle Control Strategies and Dynamic Response for Generation IV Reactors


Book Description

The analysis of specific control strategies and dynamic behavior of the supercritical carbon dioxide (S-CO2) Brayton cycle has been extended to the two reactor types selected for continued development under the Generation IV Nuclear Energy Systems Initiative; namely, the Very High Temperature Reactor (VHTR) and the Sodium-Cooled Fast Reactor (SFR). Direct application of the standard S-CO2 recompression cycle to the VHTR was found to be challenging because of the mismatch in the temperature drop of the He gaseous reactor coolant through the He-to-CO2 reactor heat exchanger (RHX) versus the temperature rise of the CO2 through the RHX. The reference VHTR features a large temperature drop of 450 C between the assumed core outlet and inlet temperatures of 850 and 400 C, respectively. This large temperature difference is an essential feature of the VHTR enabling a lower He flow rate reducing the required core velocities and pressure drop. In contrast, the standard recompression S-CO2 cycle wants to operate with a temperature rise through the RHX of about 150 C reflecting the temperature drop as the CO2 expands from 20 MPa to 7.4 MPa in the turbine and the fact that the cycle is highly recuperated such that the CO2 entering the RHX is effectively preheated. Because of this mismatch, direct application of the standard recompression cycle results in a relatively poor cycle efficiency of 44.9%. However, two approaches have been identified by which the S-CO2 cycle can be successfully adapted to the VHTR and the benefits of the S-CO2 cycle, especially a significant gain in cycle efficiency, can be realized. The first approach involves the use of three separate cascaded S-CO2 cycles. Each S-CO2 cycle is coupled to the VHTR through its own He-to-CO2 RHX in which the He temperature is reduced by 150 C. The three respective cycles have efficiencies of 54, 50, and 44%, respectively, resulting in a net cycle efficiency of 49.3 %. The other approach involves reducing the minimum cycle pressure significantly below the critical pressure such that the temperature drop in the turbine is increased while the minimum cycle temperature is maintained above the critical temperature to prevent the formation of a liquid phase. The latter approach also involves the addition of a precooler and a third compressor before the main compressor to retain the benefits of compression near the critical point with the main compressor. For a minimum cycle pressure of 1 MPa, a cycle efficiency of 49.5% is achieved. Either approach opens up the door to applying the SCO2 cycle to the VHTR. In contrast, the SFR system typically has a core outlet-inlet temperature difference of about 150 C such that the standard recompression cycle is ideally suited for direct application to the SFR. The ANL Plant Dynamics Code has been modified for application to the VHTR and SFR when the reactor side dynamic behavior is calculated with another system level computer code such as SAS4A/SYSSYS-1 in the SFR case. The key modification involves modeling heat exchange in the RHX, accepting time dependent tabular input from the reactor code, and generating time dependent tabular input to the reactor code such that both the reactor and S-CO2 cycle sides can be calculated in a convergent iterative scheme. This approach retains the modeling benefits provided by the detailed reactor system level code and can be applied to any reactor system type incorporating a S-CO2 cycle. This approach was applied to the particular calculation of a scram scenario for a SFR in which the main and intermediate sodium pumps are not tripped and the generator is not disconnected from the electrical grid in order to enhance heat removal from the reactor system thereby enhancing the cooldown rate of the Na-to-CO2 RHX. The reactor side is calculated with SAS4A/SASSYS-1 while the S-CO2 cycle is calculated with the Plant Dynamics Code with a number of iterations over a timescale of 500 seconds. It is found that the RHX undergoes a maximum cooldown rate of ≈ -0.3 C/s. The Plant Dynamics Code was also modified to decrease its running time by replacing the compressible flow form of the momentum equation with an incompressible flow equation for use inside of the cooler or recuperators where the CO2 has a compressibility similar to that of a liquid. Appendices provide a quasi-static control strategy for a SFR as well as the self-adaptive linear function fitting algorithm developed to produce the tabular data for input to the reactor code and Plant Dynamics Code from the detailed output of the other code.




Development of the ANL Plant Dynamics Code and Control Strategies for the Supercritical Carbon Dioxide Brayton Cycle and Code Validation with Data from the Sandia Small-scale Supercritical Carbon Dioxide Brayton Cycle Test Loop


Book Description

Significant progress has been made in the ongoing development of the Argonne National Laboratory (ANL) Plant Dynamics Code (PDC), the ongoing investigation and development of control strategies, and the analysis of system transient behavior for supercritical carbon dioxide (S-CO2) Brayton cycles. Several code modifications have been introduced during FY2011 to extend the range of applicability of the PDC and to improve its calculational stability and speed. A new and innovative approach was developed to couple the Plant Dynamics Code for S-CO2 cycle calculations with SAS4A/SASSYS-1 Liquid Metal Reactor Code System calculations for the transient system level behavior on the reactor side of a Sodium-Cooled Fast Reactor (SFR) or Lead-Cooled Fast Reactor (LFR). The new code system allows use of the full capabilities of both codes such that whole-plant transients can now be simulated without additional user interaction. Several other code modifications, including the introduction of compressor surge control, a new approach for determining the solution time step for efficient computational speed, an updated treatment of S-CO2 cycle flow mergers and splits, a modified enthalpy equation to improve the treatment of negative flow, and a revised solution of the reactor heat exchanger (RHX) equations coupling the S-CO2 cycle to the reactor, were introduced to the PDC in FY2011. All of these modifications have improved the code computational stability and computational speed, while not significantly affecting the results of transient calculations. The improved PDC was used to continue the investigation of S-CO2 cycle control and transient behavior. The coupled PDC-SAS4A/SASSYS-1 code capability was used to study the dynamic characteristics of a S-CO2 cycle coupled to a SFR plant. Cycle control was investigated in terms of the ability of the cycle to respond to a linear reduction in the electrical grid demand from 100% to 0% at a rate of 5%/minute. It was determined that utilization of turbine throttling control below 50% load improves the cycle efficiency significantly. Consequently, the cycle control strategy has been updated to include turbine throttle valve control. The new control strategy still relies on inventory control in the 50%-90% load range and turbine bypass for fine and fast generator output adjustments, but it now also includes turbine throttling control in the 0%-50% load range. In an attempt to investigate the feasibility of using the S-CO2 cycle for normal decay heat removal from the reactor, the cycle control study was extended beyond the investigation of normal load following. It was shown that such operation is possible with the extension of the inventory and the turbine throttling controls. However, the cycle operation in this range is calculated to be so inefficient that energy would need to be supplied from the electrical grid assuming that the generator could be capable of being operated in a motoring mode with an input electrical energy from the grid having a magnitude of about 20% of the nominal plant output electrical power level in order to maintain circulation of the CO2 in the cycle. The work on investigation of cycle operation at low power level will be continued in the future. In addition to the cycle control study, the coupled PDC-SAS4A/SASSYS-1 code system was also used to simulate thermal transients in the sodium-to-CO2 heat exchanger. Several possible conditions with the potential to introduce significant changes to the heat exchanger temperatures were identified and simulated. The conditions range from reactor scram and primary sodium pump failure or intermediate sodium pump failure on the reactor side to pipe breaks and valve malfunctions on the S-CO2 side. It was found that the maximum possible rate of the heat exchanger wall temperature change for the particular heat exchanger design assumed is limited to ±7 C/s for less than 10 seconds. Modeling in the Plant Dynamics Code has been compared with available data from the Sandia National Laboratories (SNL) small-scale S-CO2 Brayton cycle demonstration that is being assembled in a phased approach currently at Barber-Nichols Inc. and at SNL in the future. The available data was obtained with an earlier configuration of the S-CO2 loop involving only a single-turbo-alternator-compressor (TAC) instead of two TACs, a single low temperature recuperator (LTR) instead of both a LTR and a high temperature recuperator (HTR), and fewer than the later to be installed full set of electric heaters. Due to the absence of the full heating capability as well as the lack of a high temperature recuperator providing additional recuperation, the temperature conditions obtained with the loop are too low for the loop conditions to be prototypical of the S-CO2 cycle.




Handbook of Generation IV Nuclear Reactors


Book Description

Handbook of Generation IV Nuclear Reactors, Second Edition is a fully revised and updated comprehensive resource on the latest research and advances in generation IV nuclear reactor concepts. Editor Igor Pioro and his team of expert contributors have updated every chapter to reflect advances in the field since the first edition published in 2016. The book teaches the reader about available technologies, future prospects and the feasibility of each concept presented, equipping them users with a strong skillset which they can apply to their own work and research. Provides a fully updated, revised and comprehensive handbook dedicated entirely to generation IV nuclear reactors Includes new trends and developments since the first publication, as well as brand new case studies and appendices Covers the latest research, developments and design information surrounding generation IV nuclear reactors




Control System Options and Strategies for Supercritical CO2 Cycles


Book Description

The Supercritical Carbon Dioxide (S-CO2) Brayton Cycle is a promising alternative to Rankine steam cycle and recuperated gas Brayton cycle energy converters for use with Sodium-Cooled Fast Reactors (SFRs), Lead-Cooled Fast Reactors (LFRs), as well as other advanced reactor concepts. The S-CO2 Brayton Cycle offers higher plant efficiencies than Rankine or recuperated gas Brayton cycles operating at the same liquid metal reactor core outlet temperatures as well as reduced costs or size of key components especially the turbomachinery. A new Plant Dynamics Computer Code has been developed at Argonne National Laboratory for simulation of a S-CO2 Brayton Cycle energy converter coupled to an autonomous load following liquid metal-cooled fast reactor. The Plant Dynamics code has been applied to investigate the effectiveness of a control strategy for the S-CO2 Brayton Cycle for the STAR-LM 181 MWe (400 MWt) Lead-Cooled Fast Reactor. The strategy, which involves a combination of control mechanisms, is found to be effective for controlling the S-CO2 Brayton Cycle over the complete operating range from 0 to 100 % load for a representative set of transient load changes. While the system dynamic analysis of control strategy performance for STARLM is carried out for a S-CO2 Brayton Cycle energy converter incorporating an axial flow turbine and compressors, investigations of the S-CO2 Brayton Cycle have identified benefits from the use of centrifugal compressors which offer a wider operating range, greater stability near the critical point, and potentially further cost reductions due to fewer stages than axial flow compressors. Models have been developed at Argonne for the conceptual design and performance analysis of centrifugal compressors for use in the SCO2 Brayton Cycle. Steady state calculations demonstrate the wider operating range of centrifugal compressors versus axial compressors installed in a S-CO2 Brayton Cycle as well as the benefits in expanding the range over which individual control mechanisms are effective for cycle control. However, a combination of mechanisms is still required for control of the S-CO2 Brayton Cycle between 0 and 100 % load. An effort is underway to partially validate the Argonne models and codes by means of comparison with data from tests carried out using the small-scale Sandia Brayton Loop (SBL) recuperated gas closed Brayton cycle facility. The centrifugal compressor model has been compared with data from the SBL operating with nitrogen gas and good agreement is obtained between calculations and the measured data for the compressor outlet pressure versus flow rate, although it is necessary to assume values for certain model parameters which require information about the configuration or dimensions of the compressor components that is unavailable. Unfortunately, the compressor efficiency cannot be compared with experiment data due to the lack of outlet temperature data. A radial inflow turbine model has been developed to enable further comparison of calculations with data from the SBL which incorporates both a radial inflow turbine as well as a radial compressor. Preliminary calculations of pressure ratio and efficiency versus flow rate have been carried out using the radial inflow turbine model.




Combined-cycle Gas & Steam Turbine Power Plants


Book Description

This title provides a reference on technical and economic factors of combined-cycle applications within the utility and cogeneration markets. Kehlhofer - and hos co-authors give the reader tips on system layout, details on controls and automation, and operating instructions.




Compact Heat Exchangers


Book Description

This book presents the ideas and industrial concepts in compact heat exchanger technology that have been developed in the last 10 years or so. Historically, the development and application of compact heat exchangers and their surfaces has taken place in a piecemeal fashion in a number of rather unrelated areas, principally those of the automotive and prime mover, aerospace, cryogenic and refrigeration sectors. Much detailed technology, familiar in one sector, progressed only slowly over the boundary into another sector. This compartmentalisation was a feature both of the user industries themselves, and also of the supplier, or manufacturing industries. These barriers are now breaking down, with valuable cross-fertilisation taking place. One of the industrial sectors that is waking up to the challenges of compact heat exchangers is that broadly defined as the process sector. If there is a bias in the book, it is towards this sector. Here, in many cases, the technical challenges are severe, since high pressures and temperatures are often involved, and working fluids can be corrosive, reactive or toxic. The opportunities, however, are correspondingly high, since compacts can offer a combination of lower capital or installed cost, lower temperature differences (and hence running costs), and lower inventory. In some cases they give the opportunity for a radical re-think of the process design, by the introduction of process intensification (PI) concepts such as combining process elements in one unit. An example of this is reaction and heat exchange, which offers, among other advantages, significantly lower by-product production.To stimulate future research, the author includes coverage of hitherto neglected approaches, such as that of the Second Law (of Thermodynamics), pioneered by Bejan and co- workers. The justification for this is that there is increasing interest in life-cycle and sustainable approaches to industrial activity as a whole, often involving exergy (Second Law) analysis. Heat exchangers, being fundamental components of energy and process systems, are both savers and spenders of exergy, according to interpretation.




Advanced Power Generation Systems


Book Description

Advanced Power Generation Systems examines the full range of advanced multiple output thermodynamic cycles that can enable more sustainable and efficient power production from traditional methods, as well as driving the significant gains available from renewable sources. These advanced cycles can harness the by-products of one power generation effort, such as electricity production, to simultaneously create additional energy outputs, such as heat or refrigeration. Gas turbine-based, and industrial waste heat recovery-based combined, cogeneration, and trigeneration cycles are considered in depth, along with Syngas combustion engines, hybrid SOFC/gas turbine engines, and other thermodynamically efficient and environmentally conscious generation technologies. The uses of solar power, biomass, hydrogen, and fuel cells in advanced power generation are considered, within both hybrid and dedicated systems. The detailed energy and exergy analysis of each type of system provided by globally recognized author Dr. Ibrahim Dincer will inform effective and efficient design choices, while emphasizing the pivotal role of new methodologies and models for performance assessment of existing systems. This unique resource gathers information from thermodynamics, fluid mechanics, heat transfer, and energy system design to provide a single-source guide to solving practical power engineering problems. The only complete source of info on the whole array of multiple output thermodynamic cycles, covering all the design options for environmentally-conscious combined production of electric power, heat, and refrigeration Offers crucial instruction on realizing more efficiency in traditional power generation systems, and on implementing renewable technologies, including solar, hydrogen, fuel cells, and biomass Each cycle description clarified through schematic diagrams, and linked to sustainable development scenarios through detailed energy, exergy, and efficiency analyses Case studies and examples demonstrate how novel systems and performance assessment methods function in practice




Transcritical CO2 Heat Pump


Book Description

A timely and comprehensive introduction to CO2 heat pump theory and usage A comprehensive introduction of CO2 application in heat pump, authored by leading scientists in the field CO2 is a hot topic due to concerns over global warming and the 'greenhouse effect'. Its disposal and application has attracted considerable research and governmental interest Explores the basic theories, devices, systems and cycles and real application designs for varying applications, ensuring comprehensive coverage of a current topic CO2 heat transfer has everyday applications including water heaters, air-conditioning systems, residential and commercial heating systems, and cooling systems