Chemical Thermodynamics of Uranium


Book Description

This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.




Gaseous Hydrogen Embrittlement of Materials in Energy Technologies


Book Description

Many modern energy systems are reliant on the production, transportation, storage, and use of gaseous hydrogen. The safety, durability, performance and economic operation of these systems is challenged by operating-cycle dependent degradation by hydrogen of otherwise high performance materials. This important two-volume work provides a comprehensive and authoritative overview of the latest research into managing hydrogen embrittlement in energy technologies.Volume 1 is divided into three parts, the first of which provides an overview of the hydrogen embrittlement problem in specific technologies including petrochemical refining, automotive hydrogen tanks, nuclear waste disposal and power systems, and H2 storage and distribution facilities. Part two then examines modern methods of characterization and analysis of hydrogen damage and part three focuses on the hydrogen degradation of various alloy classesWith its distinguished editors and international team of expert contributors, Volume 1 of Gaseous hydrogen embrittlement of materials in energy technologies is an invaluable reference tool for engineers, designers, materials scientists, and solid mechanicians working with safety-critical components fabricated from high performance materials required to operate in severe environments based on hydrogen. Impacted technologies include aerospace, petrochemical refining, gas transmission, power generation and transportation. - Summarises the wealth of recent research on understanding and dealing with the safety, durability, performance and economic operation of using gaseous hydrogen at high pressure - Reviews how hydrogen embrittlement affects particular sectors such as the petrochemicals, automotive and nuclear industries - Discusses how hydrogen embrittlement can be characterised and its effects on particular alloy classes




The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components


Book Description

By drawing together the current theoretical and experimental understanding of the phenomena of delayed hydride cracking (DHC) in zirconium alloys, The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components: Delayed Hydride Cracking provides a detailed explanation focusing on the properties of hydrogen and hydrides in these alloys. Whilst the emphasis lies on zirconium alloys, the combination of both the empirical and mechanistic approaches creates a solid understanding that can also be applied to other hydride forming metals. This up-to-date reference focuses on documented research surrounding DHC, including current methodologies for design and assessment of the results of periodic in-service inspections of pressure tubes in nuclear reactors. Emphasis is placed on showing how our understanding of DHC is supported by progress in general understanding of such broad fields as the study of hysteresis associated with first order phase transformations, phase relationships in coherent crystalline metallic solids, the physics of point and line defects, diffusion of substitutional and interstitial atoms in crystalline solids, and continuum fracture and solid mechanics. Furthermore, an account of current methodologies is given illustrating how such understanding of hydrogen, hydrides and DHC in zirconium alloys underpins these methodologies for assessments of real life cases in the Canadian nuclear industry. The all-encompassing approach makes The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Component: Delayed Hydride Cracking an ideal reference source for students, researchers and industry professionals alike.




Gaseous Hydrogen Embrittlement of Materials in Energy Technologies


Book Description

Many modern energy systems are reliant on the production, transportation, storage, and use of gaseous hydrogen. The safety, durability, performance and economic operation of these systems is challenged by operating-cycle dependent degradation by hydrogen of otherwise high performance materials. This important two-volume work provides a comprehensive and authoritative overview of the latest research into managing hydrogen embrittlement in energy technologies.Volume 2 is divided into three parts, part one looks at the mechanisms of hydrogen interactions with metals including chapters on the adsorption and trap-sensitive diffusion of hydrogen and its impact on deformation and fracture processes. Part two investigates modern methods of modelling hydrogen damage so as to predict material-cracking properties. The book ends with suggested future directions in science and engineering to manage the hydrogen embrittlement of high-performance metals in energy systems.With its distinguished editors and international team of expert contributors, Volume 2 of Gaseous hydrogen embrittlement of materials in energy technologies is an invaluable reference tool for engineers, designers, materials scientists, and solid mechanicians working with safety-critical components fabricated from high performance materials required to operate in severe environments based on hydrogen. Impacted technologies include aerospace, petrochemical refining, gas transmission, power generation and transportation. - Summarises the wealth of recent research on understanding and dealing with the safety, durability, performance and economic operation of using gaseous hydrogen at high pressure - Chapters review mechanisms of hydrogen embrittlement including absorption, diffusion and trapping of hydrogen in metals - Analyses ways of modelling hydrogen-induced damage and assessing service life




Methods for Phase Diagram Determination


Book Description

Phase diagrams are "maps" materials scientists often use to design new materials. They define what compounds and solutions are formed and their respective compositions and amounts when several elements are mixed together under a certain temperature and pressure. This monograph is the most comprehensive reference book on experimental methods for phase diagram determination. It covers a wide range of methods that have been used to determine phase diagrams of metals, ceramics, slags, and hydrides.* Extensive discussion on methodologies of experimental measurements and data assessments * Written by experts around the world, covering both traditional and combinatorial methodologies* A must-read for experimental measurements of phase diagrams




Concise Encyclopedia of Magnetic and Superconducting Materials


Book Description

Magnetic and superconducting materials pervade every avenue of the technological world – from microelectronics and mass-data storage to medicine and heavy engineering. Both areas have experienced a recent revitalisation of interest due to the discovery of new materials, and the re-evaluation of a wide range of basic mechanisms and phenomena.This Concise Encyclopedia draws its material from the award-winning Encyclopedia of Materials and Engineering, and includes updates and revisions not available in the original set -- making it the ideal reference companion for materials scientists and engineers with an interest in magnetic and superconducting materials. - Contains in excess of 130 articles, taken from the award-winning Encyclopedia of Materials: Science and Technology, including ScienceDirect updates not available in the original set - Each article discusses one aspect of magnetic and superconducting materials and includes photographs, line drawings and tables to aid the understanding of the topic at hand - Cross-referencing guides readers to articles covering subjects of related interest










Chemical Thermodynamics of Zirconium


Book Description

This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.* Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.