The Oxidation of Cyclohexane


Book Description

The Oxidation of Cyclohexane focuses on the processes, methodologies, reactions, and approaches involved in the oxidation of cyclohexane. The publication first offers information on the theory of slow chain oxidations and the products of liquid-phase cyclohexane oxidation. Discussions focus on the applicability of the stationary state method to liquid-phase oxidation reactions; mechanism of liquid hydrocarbon chain oxidation; kinetic equations for product accumulation in degenerate branching chain reactions; and changes of the volume of the liquid phase due to oxidation product formation. The text then ponders on experimental apparatus for the study of the liquid-phase oxidation of cyclohexane, including prevention of cyclohexane losses in the waste gases, explosion danger and problems of safety, and characteristics of gas sampling in cyclohexane oxidation apparatus. The manuscript takes a look at the kinetics of uncatalyzed cyclohexane oxidation and kinetics of cyclohexane oxidation in continuous flow systems. Topics include effect of temperature on the relative yield of cyclohexane oxidation products; kinetics of cyclohexane oxidation in a glass reactor; rate of oxygen absorption and accumulation of reaction products; ideal displacement reactor; and determination of diffusion factor. The publication is a dependable reference for readers interested in the oxidation of cyclohexane.




Liquid Phase Aerobic Oxidation Catalysis


Book Description

The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.




Industrial Arene Chemistry


Book Description

Industrial Arene Chemistry Explore the wide array of uses for aromatic hydrocarbons in this comprehensive reference Aromatics are a class of compounds—normally but not exclusively organic—which tend to be produced as by-products of various industrial processes. Their importance as petrochemical materials in themselves, along with the range of inter-relations between different aromatic chemicals, creates a complex and opportunity-filled market for aromatics. Industrial Arene Chemistry provides a thorough look at the conventional techniques required to use and produce these aromatic hydrocarbons. Beginning with an overview of the global aromatic market—including, but not limited to, manufacturers, markets of BTX, and downstream functional aromatics, aromatics derived from renewable sources, and economic forecasts—the book will also explore the impact shifting environmental factors will have on the future of aromatic chemistry. The text further explores BTX production processes differentiated according to the raw materials used. Importantly, this will establish the importance and growth of the biobased chemical industry. Industrial Arene Chemistry readers will also find: Case studies that describe major elements of specific technologies prototyped by contributors/companies as part of ongoing market development efforts Process chapters that include summaries of the conventional techniques and a more detailed discussion of recent high-impact studies Recent advances in conventional aromatic reactions, including alkylation, acylation and carboxylation, hydrogenation/reduction, oxidation, nitration/amination, sulfonation, and halogenation Industrial Arene Chemistry is a useful reference for chemists and chemical engineers who work with aromatics.










Reaction Engineering, Catalyst Preparation, and Kinetics


Book Description

This book serves as an introduction to the subject, giving readers the tools to solve real-world chemical reaction engineering problems. It features a section of fully solved examples as well as end of chapter problems. It includes coverage of catalyst characterization and its impact on kinetics and reactor modeling. Each chapter presents simple ideas and concepts which build towards more complex and realistic cases and situations. Introduces an in-depth kinetics analysis Features well developed sections on the major topics of catalysts, kinetics, reactor design, and modeling Includes a chapter that showcases a fully worked out example detailing a typical problem that is faced when performing laboratory work Offers end of chapter problems and a solutions manual for adopting professors Aimed at advanced chemical engineering undergraduates and graduate students taking chemical reaction engineering courses as well as chemical engineering professionals, this textbook provides the knowledge to tackle real problems within the industry.







Industrial Organic Chemistry


Book Description

'Ideal for getting an overview of applied organic chemistry' This bestselling standard, now in its 3rd completely revised English edition, is an excellent source of technological and economic information on the most important precursors and intermediates used in the chemical industry. Right and left columns containing synopsis of the main text and statistical data, and numerous fold-out flow diagrams ensure optimal didactic presentation of complex chemical processes. The translation into eight languages, the four German and three English editions clearly evidence the popularity of this book. '... it is where I look first to get a quick overview of the manufacturing process of a product... Weissermel/Arpe has been serving me for years as an indispensable reference work.' (Berichte der Bunsengesellschaft für Physikalische Chemie) 'Whether student or scientist, theorist or practician - everyboby interested in industrial organic chemistry will appreciate this work.' (farbe + lack) '...it should be ready to hand to every chemist or process engineer envolved directly or indirectly with industrial organic chemistry . It should be in the hand of every higher-graduate student, especially if chemical technology is not part of the study, like in many college universities...' (Tenside-Surfactants-Detergents)




Lees' Loss Prevention in the Process Industries


Book Description

Over the last three decades the process industries have grown very rapidly, with corresponding increases in the quantities of hazardous materials in process, storage or transport. Plants have become larger and are often situated in or close to densely populated areas. Increased hazard of loss of life or property is continually highlighted with incidents such as Flixborough, Bhopal, Chernobyl, Three Mile Island, the Phillips 66 incident, and Piper Alpha to name but a few. The field of Loss Prevention is, and continues to, be of supreme importance to countless companies, municipalities and governments around the world, because of the trend for processing plants to become larger and often be situated in or close to densely populated areas, thus increasing the hazard of loss of life or property. This book is a detailed guidebook to defending against these, and many other, hazards. It could without exaggeration be referred to as the "bible" for the process industries. This is THE standard reference work for chemical and process engineering safety professionals. For years, it has been the most complete collection of information on the theory, practice, design elements, equipment, regulations and laws covering the field of process safety. An entire library of alternative books (and cross-referencing systems) would be needed to replace or improve upon it, but everything of importance to safety professionals, engineers and managers can be found in this all-encompassing reference instead. Frank Lees' world renowned work has been fully revised and expanded by a team of leading chemical and process engineers working under the guidance of one of the world’s chief experts in this field. Sam Mannan is professor of chemical engineering at Texas A&M University, and heads the Mary Kay O’Connor Process Safety Center at Texas A&M. He received his MS and Ph.D. in chemical engineering from the University of Oklahoma, and joined the chemical engineering department at Texas A&M University as a professor in 1997. He has over 20 years of experience as an engineer, working both in industry and academia. New detail is added to chapters on fire safety, engineering, explosion hazards, analysis and suppression, and new appendices feature more recent disasters. The many thousands of references have been updated along with standards and codes of practice issued by authorities in the US, UK/Europe and internationally. In addition to all this, more regulatory relevance and case studies have been included in this edition. Written in a clear and concise style, Loss Prevention in the Process Industries covers traditional areas of personal safety as well as the more technological aspects and thus provides balanced and in-depth coverage of the whole field of safety and loss prevention. * A must-have standard reference for chemical and process engineering safety professionals * The most complete collection of information on the theory, practice, design elements, equipment and laws that pertain to process safety * Only single work to provide everything; principles, practice, codes, standards, data and references needed by those practicing in the field




Chemical kinetics


Book Description

The volume is devoted to the problem of chemical kinetics on modern level. The book includes information on chemical physics of nanocomposites, degradation, stabilization and flammability of polymeric materials as well as free radical mechanism of oxidation of organic compounds, thermostability, mechanism of action of catalytical systems and inhibi