Advances in Catalyst Deactivation


Book Description

This book is a printed edition of the Special Issue "Advances in Catalyst Deactivation" that was published in Catalysts




Basic Principles in Applied Catalysis


Book Description

Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.




Deactivation and Regeneration of Zeolite Catalysts


Book Description

In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation and encompasses the state-of-the-art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration, by collecting a series of contributions by experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, an anthology of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice.




Catalysts Deactivation, Poisoning and Regeneration


Book Description

Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.







Progress in Catalyst Deactivation


Book Description

Most catalysts used in the chemical and petrochemical indus tries are strongly affected by one or another form of deactivation, leading to poor performances and reduced life. The increasing num ber of scientific communications devoted to the subject in recent years, and culminating with an International Symposium held in Antwerp in October 1980, is a measure of the interest it arouses in both the industrial and academic communities. A stage has been reached whereby it was thought that a NATO Advanced Study Institute on "Catalyst Deactivation" might be fruit ful in establishing the state of the art and in stimulating a more systematic research on the phenomenon. Such a meeting was held ~n Lagos, Portugal, from 18 to 29 May 1981. The purpose of the Institute was to present and discuss in a didatic and systematic way the various processes that lead to cata lyst deactivation, namely coking, poisoning and solid state trans formations, and at the same time to promote the exchange of ideas and experiences among the participants, drawn from industry and uni versity. The lectures presented at the Institute are collected in this volume with the exception of Dr. L.L.Hegedus "Catalyst Poisoning", which has been previously published (Catalysis Reviews, Science md Engineering, 23, 377-476, 1981).




Fouling Science and Technology


Book Description

The fouling of heat exchangers, reactors and catalysts remains one of the most urgent problems facing the process industries. Over the past ten years there has been limited research and investigation into the underlying mechanisms which give rise to this problem. For convenience, particularly in heat exchanger technology, the mechanisms involved have been subdivided into different subject areas. It is often the situation that individuals or groups of workers have concentra ted efforts in one or two of these specialist areas and there is a need to integrate the ideas across the whole spectrum of the subject. In addition, topics such as adhesion and surface phenomena have not been properly taken into account up till now in the assessment of the fouling processes. For this reason it was considered essential that the recognised experts from around the world, who are actively concerned with research, development and design in the fieId, should meet and exchange ideas and experience. Such a meeting was held at Alvor, Portugal, in May 1987, sponsored by the NATO Advanced St~dy Institutes Programme. In order to obtain a common basis for the work of the Advanced Study Institute, the whole technological field was reviewed right from the basic concepts to the frontiers of present knowledge. Each invited contributor was asked to make an overall presentation covering his or her area of expertise.




Catalysis Looks to the Future


Book Description

The impact of catalysis on the nation's economy is evidenced by the fact that catalytic technologies generate U.S. sales in excess of $400 billion per year and a net positive balance of trade of $16 billion annually. This book outlines recent accomplishments in the science and technology of catalysis and summarizes important likely challenges and opportunities on the near horizon. It also presents recommendations for investment of financial and human resources by industry, academe, national laboratories, and relevant federal agencies if the nation is to maintain continuing leadership in this fieldâ€"one that is critical to the chemical and petroleum processing industries, essential for energy-efficient means for environmental protection, and vital for the production of a broad range of pharmaceuticals.




Advances in Fluid Catalytic Cracking


Book Description

Refiners' efforts to conform to increasingly stringent laws and a preference for fuels derived from renewable sources have mandated changes in fluid cracking catalyst technology. Advances in Fluid Catalytic Cracking: Testing, Characterization, and Environmental Regulations explores recent advances and innovations in this important component of petr




Catalysis


Book Description

Students contemplating careers in chemistry, whether in research, practice, or academia, obviously need a solid grounding in proper research methodology, reasoning, and analysis. However, there are few resources available that efficiently and effectively introduce these concepts and techniques and inspire students to undertake advanced research, particularly in the area of catalysis. Catalysis: Principles and Applications evolved out of a special, resoundingly successful short course for graduate students interested in catalysis. It covers nearly the entire gamut of the subject, from its fundamentals to its modern, applied aspects. The chapters were contributed by catalysis specialists from leading academic institutions, national laboratories and industrial R&D labs. Because they are based on the authors' lecture notes, each chapter is highly accessible and for the most part self-contained. Topics include various spectroscopic methods, biocatalysis, x-ray and thermal analysis, photocatalysis, and recent developments, such as solid acid catalysts, fine chemical synthesis, and computer-aided catalyst design. The book also contains discussions on a variety of modern applications, including environmental pollution control, petroleum refining, fuel cells, and monomolecular films. Logically presented, well-illustrated, and thoroughly referenced, Catalysis: Principles and Applications offers an outstanding basis for courses in catalysis. It not only imparts the fundamentals, synthesis, characterization, and applications of catalysis, but does so in a way that will motivate students to pursue more advanced studies and ultimately careers in the field.




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