Waste and Supplementary Cementitious Materials in Concrete


Book Description

Waste and Supplementary Cementitious Materials in Concrete: Characterisation, Properties and Applications provides a state-of-the-art review of the effective and efficient use of these materials in construction. Chapters focus on a specific type of material, addressing their characterization, strength, durability and structural applications. Sections include discussions of the properties of materials, including their physical, chemical and characterization, their strength and durability, modern engineering applications, case studies, the state of codes and standards of implementation, cost considerations, and the role of materials in green and sustainable construction. The book concludes with a discussion of research needs. - Focuses on material properties and applications (as well as 'sustainability' aspects) of cementitious materials - Assembles leading researchers from diverse areas of study - Ideas for use as a 'one stop' reference for advanced postgraduate courses focusing on sustainable construction materials




A Practical Guide to Microstructural Analysis of Cementitious Materials


Book Description

A Practical Guide from Top-Level Industry Scientists As advanced teaching and training in the development of cementitious materials increase, the need has emerged for an up-to-date practical guide to the field suitable for graduate students and junior and general practitioners. Get the Best Use of Different Techniques and Interpretations of the Results This edited volume provides the cement science community with a state-of-the-art overview of analytical techniques used in cement chemistry to study the hydration and microstructure of cements. Each chapter focuses on a specific technique, not only describing the basic principles behind the technique, but also providing essential, practical details on its application to the study of cement hydration. Each chapter sets out present best practice, and draws attention to the limitations and potential experimental pitfalls of the technique. Databases that supply examples and that support the analysis and interpretation of the experimental results strengthen a very valuable ready reference. Utilizing the day-to-day experience of practical experts in the field, this book: Covers sample preparation issues Discusses commonly used techniques for identifying and quantifying the phases making up cementitious materials (X-ray diffraction and thermogravimetric analysis) Presents good practice oncalorimetry and chemical shrinkage methods for studying cement hydration kinetics Examines two different applications of nuclear magnetic resonance (solid state NMR and proton relaxometry) Takes a look at electron microscopy, the preeminent microstructural characterization technique for cementitious materials Explains how to use and interpret mercury intrusion porosimetry Details techniques for powder characterization of cementitious materials Outlines the practical application of phase diagrams for hydrated cements Avoid common pitfalls by using A Practical Guide to Microstructural Analysis of Cementitious Materials. A one-of-a-kind reference providing the do’s and don’ts of cement chemistry, the book presents the latest research and development of characterisation techniques for cementitious materials, and serves as an invaluable resource for practicing professionals specializing in cement and concrete materials and other areas of cement and concrete technology.







Supplementary Cementing Materials


Book Description

This book is an attempt to consolidate the published research related to the use of Supplementary Cementing Materials in cement and concrete. It comprises of five chapters. Each chapter is devoted to a particular supplementing cementing material. It is based on the literature/research findings published in journals/conference proceeding, etc. Topics covered in the book are; coal fly ash, silica fume (SF), granulated blast furnace slag (GGBS), metakaolin (MK), and rice husk ash (RHA). Each chapter contains introduction, properties of the waste material/by-product, its potential usage, and its effect on the properties of fresh and hardened concrete and other cement based materials.




Cementitious Materials


Book Description

Aside from water the materials which are used by mankind in highest quantities arecementitious materials and concrete. This book shows how the quality of the technical product depends on mineral phases and their reactions during the hydration and strengthening process. Additives and admixtures infl uence the course of hydration and the properties. Options of reducing the CO2-production in cementitious materials are presented and numerous examples of unhydrous and hydrous phases and their formation conditions are discussed. This editorial work consists of four parts including cement composition and hydration, Special cement and binder mineral phases, Cementitious and binder materials, and Measurement and properties. Every part contains different contributions and covers a broad range within the area. Contents Part I: Cement composition and hydration Diffraction and crystallography applied to anhydrous cements Diffraction and crystallography applied to hydrating cements Synthesis of highly reactive pure cement phases Thermodynamic modelling of cement hydration: Portland cements – blended cements – calcium sulfoaluminate cements Part II: Special cement and binder mineral phases Role of hydrotalcite-type layered double hydroxides in delayed pozzolanic reactions and their bearing on mortar dating Setting control of CAC by substituted acetic acids and crystal structures of their calcium salts Crystallography and crystal chemistry of AFm phases related to cement chemistry Part III: Cementitious and binder materials Chemistry, design and application of hybrid alkali activated binders Binding materials based on calcium sulphates Magnesia building material (Sorel cement) – from basics to application New CO2-reduced cementitious systems Composition and properties of ternary binders Part IV: Measurement and properties Characterization of microstructural properties of Portland cements by analytical scanning electron microscopy Correlating XRD data with technological properties No cement production without refractories




Properties of Fresh and Hardened Concrete Containing Supplementary Cementitious Materials


Book Description

This volume represents the current knowledge on the effect of SCMs (slag, fly ash, silica fume, limestone powder, metakaolin, natural pozzolans, rice husk ash, special SCMs, ternary blends) on the properties of fresh and hardened concrete (e.g. early strength development, workability, shrinkage) and curing requirements. Other topics treated in the book are postblending vs preblending, implications of SCM variability, interaction between SCM and commonly used admixtures (e.g. superplasticizers, air entrainers).




Carbon Dioxide Sequestration in Cementitious Construction Materials


Book Description

Carbon Dioxide Sequestration in Cementitious Construction Materials – Second Edition follows on the success of the previous edition and provides an up-to-date review on recent research developments on cementitious construction materials based on carbon dioxide storage. Along with the addition of an entire new section on bio- sequestration. Brand new chapters are included on carbonation methods such as carbon sequestration of cement pastes during pressurized CO2 curing; carbon dioxide sequestration of low-calcium fly ash via direct aqueous carbonation; increasing the efficiency of carbon dioxide sequestration through high temperature carbonation; and carbon sequestration in engineered cementitious composites. There are also several new case studies on sequestration of industrial wastes, which include carbon dioxide sequestration by direct mineralization of fly ash; the effect of direct carbonation routes of basic oxygen furnace slag on strength and hydration of blended cement paste; carbon sequestration of mine waste and utilization as a supplementary cementitious material and carbon dioxide sequestration on masonry blocks based on industrial wastes. This updated edition will be a valuable reference resource for academic researchers, materials scientists and civil engineers, and other construction professionals looking for viable routes for carbon sequestration in building materials. - Promotes the importance of CO2 storage in carbonation of construction materials, especially reincorporation of CO2 during fabrication - Discusses a wide range of cementitious materials with CO2 storage capabilities - Features redesign of cementation mechanisms to utilize CO2 during fabrication - Includes a new section on bio-sequestration




Pozzolanic and Cementitious Materials


Book Description

This volume provides an overview of the mineral admixtures used in concrete, including silica fume, slag, rice-husk ash, fly ash and natural pozzolans. It also includes the mineral/chemical composition of the admixtures, their chemical reactions with cement and as a method of recycling.




Performance of Cement-Based Materials in Aggressive Aqueous Environments


Book Description

Concrete and cement-based materials must operate in increasingly aggressive aqueous environments, which may be either natural or industrial. These materials may suffer degradation in which ion addition and/or ion exchange reactions occur, leading to a breakdown of the matrix microstructure and consequent weakening. Sometimes this degradation can be extremely rapid and serious such as in acidic environments, while in other cases degradation occurs over long periods. Consequences of material failure are usually severe – adversely affecting the health and well-being of human communities and disturbing ecological balances. There are also large direct costs of maintaining and replacing deteriorated infrastructure and indirect costs from loss of production during maintenance work, which place a great burden on society. The focus of this book is on addressing issues concerning performance of cement-based materials in aggressive aqueous environments , by way of this State-of-the-Art Report. The book represents the work of many well-known and respected authors who contributed chapters or parts of chapters. Four main themes were addressed: I. Nature and kinetics of degradation and deterioration mechanisms of cement-based materials in aggressive aqueous environments, II. Modelling of deterioration in such environments, III. Test methods to assess performance of cement-based materials in such environments, and which can be used to characterise and rate relative performance and inform long term predictions, IV. Engineering implications and consequences of deterioration in aggressive aqueous environments, and engineering approaches to the problem.




Cementitious Materials for Nuclear Waste Immobilization


Book Description

Cementitious materials are an essential part in any radioactive waste disposal facility. Conditioning processes such as cementation are used to convert waste into a stable solid form that is insoluble and will prevent dispersion to the surrounding environment. It is incredibly important to understand the long-term behavior of these materials. This book summarises approaches and current practices in use of cementitious materials for nuclear waste immobilisation. It gives a unique description of the most important aspects of cements as nuclear waste forms: starting with a description of wastes, analyzing the cementitious systems used for immobilization and describing the technologies used, and ending with analysis of cementitious waste forms and their long term behavior in an envisaged disposal environment. Extensive research has been devoted to study the feasibility of using cement or cement based materials in immobilizing and solidifying different radioactive wastes. However, these research results are scattered. This work provides the reader with both the science and technology of the immobilization process, and the cementitious materials used to immobilize nuclear waste. It summarizes current knowledge in the field, and highlights important areas that need more investigation. The chapters include: Introduction, Portland cement, Alternative cements, Cement characterization and testing, Radioactive waste cementation, Waste cementation technology, Cementitious wasteform durability and performance assessment.