The Chemistry Of Solid Wood


Book Description

This 15-chapter book is divided into four sections that discuss wood's structure and basic chemistry, its properties and reactivity, and its surface and degradation chemistry. The very basis of how wood is formed and the structure it assumes during this growth are given in the first section. Various wood science terms are defined and discussed thoroughly to give a clear and adequate foundation for the rest of the book. Wood water relationship important in almost any wood applications- are also discussed in this section. The subsequent three sections discuss relations and chemistry important for the beginning wood chemist to understand. These topics include wood's cell wall components, strength, interaction with preservatives, and adhesion. Wood polymer materials, wood surface activation, weathering and protection, and pyrolysis and fire retardancy are topics also embraced.







Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion


Book Description

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications. Details thermochemical properties and "ab initio" calculations of elementary reaction rates Details kinetic mechanisms of pyrolysis and combustion processes Explains experimental data for improving reaction models and for kinetic mechanisms assessment Describes surrogate fuels and molecular reconstruction of hydrocarbon liquid mixtures Describes pollutant formation in combustion systems Solves and validates the kinetic mechanisms using numerical and statistical methods Outlines optimal design of industrial burners and optimization and dynamic control of pyrolysis furnaces Outlines large eddy simulation of turbulent reacting flows




Soot Formation in Combustion


Book Description

Soot Formation in Combustion represents an up-to-date overview. The contributions trace back to the 1991 Heidelberg symposium entitled "Mechanism and Models of Soot Formation" and have all been reedited by Prof. Bockhorn in close contact with the original authors. The book gives an easy introduction to the field for newcomers, and provides detailed treatments for the specialists. The following list of contents illustrates the topics under review:




Pyrolysis of Organic Molecules


Book Description

Pyrolysis of Organic Molecules with Applications to Health and Environmental Issues, the 28th volume in the Techniques and Instrumentation in Analytical Chemistry series, gives a systematic and comprehensive description of pyrolysis of non-polymeric organic molecules. Pyrolysis is involved in many practical applications as well as in many common human activities, but harmful compounds can be generated in the process. The study of pyrolysis and of the formation of undesirable compounds as a result of pyrolytic processes is of considerable interest to chemists, chemical engineers, and toxicologists. - Pyrolysis results for compounds not previously studied or reported - Updated information from a large body of results published on pyrolysis of individual compounds or classes of compounds - Information on mechanisms and kinetics of numerous pyrolytic processes




Bimodal Oxidation


Book Description

This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists




Inhibition of Chain Reactions


Book Description

This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.




Fire Debris Analysis


Book Description

The study of fire debris analysis is vital to the function of all fire investigations, and, as such, Fire Debris Analysis is an essential resource for fire investigators. The present methods of analysis include the use of gas chromatography and gas chromatography-mass spectrometry, techniques which are well established and used by crime laboratories throughout the world. However, despite their universality, this is the first comprehensive resource that addresses their application to fire debris analysis.Fire Debris Analysis covers topics such as the physics and chemistry of fire and liquid fuels, the interpretation of data obtained from fire debris, and the future of the subject. Its cutting-edge material and experienced author team distinguishes this book as a quality reference that should be on the shelves of all crime laboratories. - Serves as a comprehensive guide to the science of fire debris analysis - Presents both basic and advanced concepts in an easily readable, logical sequence - Includes a full-color insert with figures that illustrate key concepts discussed in the text




Fundamentals of the Physical-Chemistry of Pulverized Coal Combustion


Book Description

The study of coal for the production of energy is certainly not a new area of research. Many research works were carried out to improve the efficiency of industrial and domestic facilities. In the sixties, however, because of the availability and low cost of petroleum, coal consumption decreased and the research effort in this area was minimum. Meanwhile, the situation has totally changed. Considering the reserves of oil and the instability ofregions where they are located, it is becoming absolutely necessary to develop other sources of energy.The major alternative to oil appears to be coal, at least for the near future. Indeed, the reserves known today represent several centuries of energy consumption.!t is therefore becoming urgent to develop efficient and non polluting technologies to produce energy from coal. The main possibilities are : · liquefaction · gasification · directed combustion. Research and development efforts on liquefaction have been considerably reduced because of high cost of technologies involved and poor prospects for the next two decades. Research works on gasification are progressing; it is a promising approach. However, direct combustion either in pulverized coal furnaces or in fluidized beds is the more promising way of expanding rapidly the utilization of coal. These techniques are already used in some facilities but many environmental problems remain, slowing down their development.