CO2 and CO as Feedstock


Book Description

Climate protection and raw material change require new, sustainable carbon sources for the chemical and fuel industries. In fact, processes that recycle carbon-containing emission and gas streams industrially are reaching industrial practice. They will make an important contribution to reducing carbon emissions and moving towards a true carbon circular economy. This book describes the basics of chemical and biotechnological processes for converting CO and CO2 into chemicals and fuels. Furthermore, it addresses potentials for the manufacturing economy, industrial sites and regions and answers the following questions. Which emission and gas streams offer feedstock potential? What processes are already implemented, being tested and under development? What products can be made from gaseous carbon sources? How can carbon emitting and consuming industries be linked into new value chains? What is the regulatory framework? What does the ecological footprint look like? How do the new processes contribute to the regional economy and thus to social acceptance among consumers and among decision-makers in companies and politics? Providing companies with sustainable carbon sources is a central question of the circular economy, which must be answered with technical processes, new cross-sector value chains, adapted infrastructure and further developed framework conditions. This concerns scientists and decision-makers in companies alike. In this book, they as well as interested laymen will find a comprehensive overview of the state of the art in both, technology and research, and of the overriding issues involved in establishing CO2 and CO as feedstocks.




Carbon Dioxide as Chemical Feedstock


Book Description

Filling the need for an up-to-date handbook, this ready reference closely investigates the use of CO2 for ureas, enzymes, carbamates, and isocyanates, as well as its use as a solvent, in electrochemistry, biomass utilization and much more. Edited by an internationally renowned and experienced researcher, this is a comprehensive source for every synthetic chemist in academia and industry.




Carbon Management


Book Description

Considerable international concerns exist about global climate change and its relationship to the growing use of fossil fuels. Carbon dioxide is released by chemical reactions that are employed to extract energy from fuels, and any regulatory policy limiting the amount of CO2 that could be released from sequestered sources or from energy-generating reactions will require substantial involvement of the chemical sciences and technology R&D community. Much of the public debate has been focused on the question of whether global climate change is occurring and, if so, whether it is anthropogenic, but these questions were outside the scope of the workshop, which instead focused on the question of how to respond to a possible national policy of carbon management. Previous discussion of the latter topic has focused on technological, economic, and ecological aspects and on earth science challenges, but the fundamental science has received little attention. This workshop was designed to gather information that could inform the Chemical Sciences Roundtable in its discussions of possible roles that the chemical sciences community might play in identifying and addressing underlying chemical questions.




Gaseous Carbon Waste Streams Utilization


Book Description

In the quest to mitigate the buildup of greenhouse gases in Earth's atmosphere, researchers and policymakers have increasingly turned their attention to techniques for capturing greenhouse gases such as carbon dioxide and methane, either from the locations where they are emitted or directly from the atmosphere. Once captured, these gases can be stored or put to use. While both carbon storage and carbon utilization have costs, utilization offers the opportunity to recover some of the cost and even generate economic value. While current carbon utilization projects operate at a relatively small scale, some estimates suggest the market for waste carbon-derived products could grow to hundreds of billions of dollars within a few decades, utilizing several thousand teragrams of waste carbon gases per year. Gaseous Carbon Waste Streams Utilization: Status and Research Needs assesses research and development needs relevant to understanding and improving the commercial viability of waste carbon utilization technologies and defines a research agenda to address key challenges. The report is intended to help inform decision making surrounding the development and deployment of waste carbon utilization technologies under a variety of circumstances, whether motivated by a goal to improve processes for making carbon-based products, to generate revenue, or to achieve environmental goals.




Carbon Dioxide to Chemicals and Fuels


Book Description

Carbon Dioxide to Chemicals and Fuels provides a snapshot of the present status of this rapidly growing field, examining ongoing breakthroughs in research and development, motivations, innovations and their respective impacts and perspectives. It also covers in detail the existing technical barriers to achieving key goals in this area. This book details the various methods, both currently available and potential, for conversion of CO2 into fuels and chemicals. With explanation of concepts and their applications, Carbon Dioxide to Chemicals and Fuels offers an interdisciplinary approach that draws on and clarifies the most recent research trends. - Explains the fundamental aspects of CO2 utilization - Provides recent developments in CO2 utilization for the production of chemicals - Answers the questions surrounding why some processes have not commercialized - Discusses and analyses in detail many available catalytic conversion methods




Carbon Dioxide Utilisation


Book Description

Carbon Dioxide Utilisation: Closing the Carbon Cycle explores areas of application such as conversion to fuels, mineralization, conversion to polymers, and artificial photosynthesis as well as assesses the potential industrial suitability of the various processes. After an introduction to the thermodynamics, basic reactions, and physical chemistry of carbon dioxide, the book proceeds to examine current commercial and industrial processes, and the potential for carbon dioxide as a green and sustainable resource. While carbon dioxide is generally portrayed as a "bad" gas, a waste product, and a major contributor to global warming, a new branch of science is developing to convert this "bad" gas into useful products. This book explores the science behind converting CO2 into fuels for our cars and planes, and for use in plastics and foams for our homes and cars, pharmaceuticals, building materials, and many more useful products. Carbon dioxide utilization is a rapidly expanding area of research that holds a potential key to sustainable, petrochemical-free chemical production and energy integration. - Accessible and balanced between chemistry, engineering, and industrial applications - Informed by blue-sky thinking and realistic possibilities for future technology and applications - Encompasses supply chain sustainability and economics, processes, and energy integration




Advances in Chemical Conversions for Mitigating Carbon Dioxide


Book Description

Global environmental problems, especially global warming caused by the accelerative accumulation of carbon dioxide in the atmosphere, are of great importance for humans. The world's population is now approaching 6 billion, and is still increasing. Developments in communication systems and transportation tools have made the circulation of information, technologies and materials easier, which results in rapid economic growth, particularly in the East and Southeastern Asian countries. Increased affluence leads to an increased consumption of fossil fuels. Inevitably, this leads to an increase in carbon dioxide emission and environmentally hazardous materials which in turn precipitates climatic changes on a global scale. Recent studies showed that the increase in carbon dioxide emission for last year was the highest in the past seven years, and the total amount of carbon dioxide emission from all over the world reached 6.5 billion tons. Furthermore, one cannot overlook the report which appeared recently in Nature, that the floor-area of the iceberg in the South Pole has already decreased by 25% in the past five decades.Over 260 scientists and engineers from 21 countries who had a strong interest and wished to contribute to solve the carbon dioxide problem attended this conference. The papers presented in this volume cover most of the possibilities of the chemical conversion of carbon dioxide.




The Story of CO2


Book Description

The climate crisis requires that we drastically reduce carbon dioxide emissions across all sectors of society. The Story of CO2 contributes to this vital conversation by highlighting the cutting-edge science and emerging technologies – a number of which are already commercially available – that can transform carbon dioxide into a myriad of products such as feedstock chemicals, polymers, pharmaceuticals, and fuels. This approach allows us to reconsider CO2 as a resource, and to add "carbon capture and use" to our other tools in the fight against catastrophic climate change. The Story of CO2 explores all aspects of carbon dioxide, from the atomic to the universal perspective, and takes the reader on an epic journey into our physical world, starting from the moment of the Big Bang, all the way to the present world in which atmospheric CO2 concentrations continue to grow. This story seeks to inspire readers with the latest carbon utilization technologies and explain how they fit within the broader context of carbon mitigation strategies in the shift towards a sustainable energy economy.




Electrochemical and Electrocatalytic Reactions of Carbon Dioxide


Book Description

The recycling of atmospheric molecules for use as fuels and chemicals is a goal which can only be achieved through a deeper understanding of catalytic processes, particularly electrocatalysis whereby redox transformations can be interfaced with solar or nuclear energy input. Carbon dioxide is a prototypical small molecule in many regards since it is chemically inert. In addition, because of the likely role of carbon dioxide in global temperature cycles, it will be imperative in the future to regulate the output from industrial processes. The purpose of this book is to present a unified discussion of the carbon dioxide chemistry which is necessary for the understanding and design of electrochemically-driven processes for the reduction of carbon dioxide and to provide an impetus for the further development of electrocatalytic carbon dioxide chemistry.