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Far-from-equilibrium Dynamics

Author : Yasumasa Nishiura

Publisher : American Mathematical Soc.

Page : 340 pages

File Size : 40,51 MB

Release : 2002

Category : Mathematics

ISBN : 9780821826256

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Book Description

This book is devoted to the study of evolution of nonequilibrium systems. Such a system usually consists of regions with different dominant scales, which coexist in the space-time where the system lives. In the case of high nonuniformity in special direction, one can see patterns separated by clearly distinguishable boundaries or interfaces. The author considers several examples of nonequilibrium systems. One of the examples describes the invasion of the solid phase into the liquidphase during the crystallization process. Another example is the transition from oxidized to reduced states in certain chemical reactions. An easily understandable example of the transition in the temporal direction is a sound beat, and the author describes typical patterns associated with thisphenomenon. The main goal of the book is to present a mathematical approach to the study of highly nonuniform systems and to illustrate it with examples from physics and chemistry. The two main theories discussed are the theory of singular perturbations and the theory of dissipative systems. A set of carefully selected examples of physical and chemical systems nicely illustrates the general methods described in the book.



Non-Equilibrium Dynamics in Chemical Systems

Author : C. Vidal

Publisher : Springer Science & Business Media

Page : 260 pages

File Size : 22,55 MB

Release : 2012-12-06

Category : Science

ISBN : 3642701965

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Book Description

Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.



Introduction to Non-equilibrium Physical Chemistry

Author : R. P. Rastogi

Publisher : Elsevier

Page : 357 pages

File Size : 34,47 MB

Release : 2007-10-16

Category : Technology & Engineering

ISBN : 0080551807

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Book Description

Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. - The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium - Experimental studies have been reported which provide test of the theories and their limitations - Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed



Out-of-Equilibrium (Supra)molecular Systems and Materials

Author : Nicolas Giuseppone

Publisher : John Wiley & Sons

Page : 448 pages

File Size : 14,57 MB

Release : 2021-03-30

Category : Science

ISBN : 3527821988

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Book Description

A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.



Pattern Formation and Dynamics in Nonequilibrium Systems

Author : Michael Cross

Publisher : Cambridge University Press

Page : 547 pages

File Size : 30,79 MB

Release : 2009-07-16

Category : Mathematics

ISBN : 0521770505

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Book Description

An account of how complex patterns form in sustained nonequilibrium systems; for graduate students in biology, chemistry, engineering, mathematics, and physics.



Critical Dynamics

Author : Uwe C. Täuber

Publisher : Cambridge University Press

Page : 529 pages

File Size : 19,77 MB

Release : 2014-03-06

Category : Science

ISBN : 0521842239

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Book Description

A comprehensive and unified introduction to describing and understanding complex interacting systems.



Statistical Thermodynamics of Nonequilibrium Processes

Author : Joel Keizer

Publisher : Springer Science & Business Media

Page : 517 pages

File Size : 40,15 MB

Release : 2012-12-06

Category : Science

ISBN : 1461210542

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Book Description

The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.



Dynamics of Hierarchical Systems

Author : John S. Nicolis

Publisher : Springer Science & Business Media

Page : 408 pages

File Size : 11,46 MB

Release : 2012-12-06

Category : Science

ISBN : 3642696929

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Book Description

The main aim of these lectures is to tri gger the interest of the restless under graduate student of physical, mathematical, engineering, or biological sciences in the new and exciting multidisciplinary area of the evolution of "large-scale" dynamical systems. This text grew out of a synthesis of rather heterogeneous mate rial that I presented on various occasions and in different contexts. For example, from lectures given since 1972 to first- and final-year undergraduate and first year graduate students at the School of Engineering of the University of Patras and from informal seminars offered to an international group of graduate and post doctoral students and faculty members at the University of Stuttgart in the aca demic year 1982-1983. Those who search for rigor or even formality in this book are bound to be rather disappointed. My intention is to start from "scratch" if possible, keeping the rea soning heuristic and tied as closely as possible to physical intuition; I assume as prerequisites just basic knowledge of (classical) physics (at the level of the Berkeley series or the Feynman lectures), calculus, and some elements of probabil ity theory. This does not mean that I intended to write an easy book, but rather to eliminate any difficulty for an eager reader who, in spite of incomplete for malistic training, would like to become acquainted with the physical ideas and con cepts underlying the evolution and dynamics of complex systems.



Uncertainty and Surprise in Complex Systems

Author : Reuben R. McDaniel

Publisher : Springer Science & Business Media

Page : 220 pages

File Size : 27,17 MB

Release : 2005-03-11

Category : Science

ISBN : 9783540237730

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Book Description

Complexity science has been a source of new insight in physical and social systems and has demonstrated that unpredictability and surprise are fundamental aspects of the world around us. This book is the outcome of a discussion meeting of leading scholars and critical thinkers with expertise in complex systems sciences and leaders from a variety of organizations, sponsored by the Prigogine Center at The University of Texas at Austin and the Plexus Institute, to explore strategies for understanding uncertainty and surprise. Besides contributions to the conference, it includes a key digest by the editors as well as a commentary by the late nobel laureate Ilya Prigogine, "Surprises in half of a century". The book is intended for researchers and scientists in complexity science, as well as for a broad interdisciplinary audience of both practitioners and scholars. It will well serve those interested in the research issues and in the application of complexity science to physical and social systems.



Brain Dynamics

Author : H. Haken

Publisher : Springer Science & Business Media

Page : 266 pages

File Size : 26,1 MB

Release : 2002

Category : Mathematics

ISBN : 9783540430766

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Book Description

This book addresses a large variety of models in mathematical and computational neuroscience. It is written for the experts as well as for graduate students wishing to enter this fascinating field of research. The author studies the behaviour of large neural networks composed of many neurons coupled by spike trains. He devotes the main part to the synchronization problem. He presents neural net models more realistic than the conventional ones by taking into account the detailed dynamics of axons, synapses and dendrites, allowing rather arbitrary couplings between neurons. He gives a complete stabile analysis that goes significantly beyond what has been known so far. He also derives pulse-averaged equations including those of the Wilson--Cowan and the Jirsa-Haken-Nunez types and discusses the formation of spatio-temporal neuronal activity pattems. An analysis of phase locking via sinusoidal couplings leading to various kinds of movement coordination is included.