Electrochemistry in a Divided World


Book Description

In this collection of interrelated essays, the authors review landmark developments in electrochemistry building on biographic material and personal insight. The book facilitates understanding of the innate pathways of developments in electrochemical science as a result of lucky circumstances fitting to objective conditions. Thus the book will help to understand the present state of electrochemistry and offer inspiration for solving today’s scientific challenges. The authors as experienced electrochemists from the U.S., Western and Eastern Europe also provide guidance for scientific careers by presenting biographical examples of famous electrochemists.




Electrochemistry of Technetium


Book Description

This book provides detailed information on the electrochemistry of technetium compounds. After a brief physico-chemical characterization of this element, it presents the comparative chemistry of technetium, manganese and rhenium. Particular attention is paid to the stability, disproportionation, comproportionation, hydrolysis and polymerization reactions of technetium ions and their influence on the observed redox systems. The electrochemical properties of both inorganic as well as organic technetium species in aqueous and non-aqueous solutions are also discussed. The respective chapters cover the whole spectrum of topics related to the application of technetium in nuclear medicine, electrochemistry of technetium in spent nuclear fuel (including corrosion properties of technetium alloys), and detecting trace amounts of technetium with the aid of electrochemical methods. Providing readers with information not easily obtained in any other single source, the book will appeal to researchers working in nuclear chemistry, nuclear medicine or the nuclear industry.




Electrochemistry for Cultural Heritage


Book Description

This monograph overviews the importance of electrochemistry in the field of cultural heritage, including archaeology, conservation and restoration topics. The application of electrochemical techniques in these domains have experienced a notable growth during the last ten years, in particular with regards to the elucidation of composition, manufacturing techniques and chronology of archaeological artefacts. This book describes the application of solid state electrochemistry techniques for the use of samples at the nanogram level from paintings, metallic, ceramic, glass, glazed, wooden, and other objects, and it also includes the description of new dating procedures for archaeological objects made of these materials. It is a valuable contribution to the field of cultural heritage and will be of great interest to archaeologists, conservators and restorers as well as to physicists and chemists working on the scientific examination of works of art.




Wilhelm Ostwald


Book Description

This book is the translated and commented autobiography of Wilhelm Ostwald (1853-1932), who won the Nobel Prize for Chemistry in 1909. It is the first translation of the German original version “Lebenslinien: Eine Selbstbiographie,” published by Ostwald in 1926/27, and has been painstakingly translated. The book includes comments and explanations, helping readers to understand Ostwald’s text in the historical context of Germany at the beginning of the 20th century.In his autobiography, Ostwald describes his impressive research career and his life from his own personal view. Readers will find information on how Ostwald immortalized himself through his research on catalysis, chemical equilibria, technical chemistry, and especially as one of the founders of modern physical chemistry. His broad interests in science, ranging from philosophy to the theory of colors and the idea of a universal scientific language are further remarkable aspects covered.This work will appeal to a broad audience of contemporary scientists: Wilhelm Ostwald has been tremendously influential for the development of chemistry and science, and many of today’s best-known international scientific schools can be traced back to Ostwald’s students. Ostwald was active in Germany and what is now Latvia and Estonia, while also travelling to the USA, England and France. In his discussions and analyses of the working conditions of the time, readers will find many issues reflected that continue to be of relevance today.




Chemometrics in Electroanalysis


Book Description

This monograph covers the most relevant applications of chemometrics in electrochemistry with special emphasis on electroanalytical chemistry. It reviews the use of chemometric methods for exploratory data analysis, experimental design and optimization, calibration, model identification, and experts systems. The book also provides a brief introduction to the fundamentals of the main chemometric methods and offers examples of data treatment for calibration and model identification. Due to the comprehensive coverage, this book offers an invaluable resource for graduate and postgraduate students, as well as for researchers in academic and industrial laboratories working in the area of electroanalysis and electrochemical sensors.




Electrolytic Production of Al–Si Alloys


Book Description

This monograph presents the theoretical background of the industrial process for the production of Al-Si alloys in standard aluminum electrolyzers. It reviews the physical chemistry and electrochemistry of cryolite melts containing silica and focuses on analyzing the exchange reactions in Na3AlF6–Al2O3–SiO2 melts. It presents the kinetics and mechanism of Si(IV) electroreduction in Na3AlF6–Al2O3–SiO2 melts on Al cathodes while the current yields as well as industrial tests performed are discussed. The modern research trends in the field are also overviewed. Providing readers with information not easily obtained in any other single source, this book is of great interest to researchers, graduates, and professionals working in the fields of electrochemistry and technology of cryolite-based melts.




Russian Contributions to Analytical Chemistry


Book Description

This book offers a unique perspective and novel information on the significant contributions of Russian scientists to analytical chemistry and chemical analysis. Written by the Editor-in-Chief of the Journal of Analytical Chemistry, it discusses various examples of new methods and approaches originating in Russia, such as chromatography, electrothermal atomic absorption spectrometry, Kumakhov X-ray optics, the Spolský effect in fluorescent analysis and important innovations in mass spectrometry, which are already widely used. Other original developments, such as the chromatomembrane and stoichiographic methods, are on their way to international recognition. Tremendous expertise in the analysis of minerals and high-purity and special-purpose substances has accumulated in Russian laboratories, and as such this book appeals to anyone interested in the development of science in Russia; to physicists, chemists, and other specialists dealing with chemical analysis; and to postgraduates and students of chemistry-related disciplines.




Hydrogen in an International Context


Book Description

Hydrogen in an International Context: Vulnerabilities of Hydrogen Energy in Emerging Markets describes strategies and developments for hydrogen civilization efforts realised by various stakeholders such as authorities, institutes, research, industry, and individuals, in different countries and at different stages of the development cycle. Through their contributions, the chapter authors in this book propose a new approach to actual and relevant topics of interest, generically called the hydrogen economy and civilization.Hydrogen vulnerabilities is a topic that includes new challenges that face the hydrogen energy market. Weaknesses for the hydrogen stakeholder are becoming more refined, and it is necessary to be an active and sensitive player to understand these. A prosperous development of hydrogen will require the assimilation of numerous, diverse and unfamiliar contexts. Challenges for hydrogen will not only be in scientific, technical, economical or public acceptance, but challenges also lie in the genesis of this topic and the neglect of some aspects, however marginal, which negatively influence the desired hydrogen developed.This book informs the reader about the status of hydrogen energy in the international market, and it includes a series of examples and case studies about hydrogen activities in various countries. Thus, due to the synergy of this library of contexts, the reader should be able to reach a level of intuition enabling them to see the strengths and weaknesses of hydrogen.




Handbook of Electrochemistry


Book Description

Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)




Electrochemistry of Nucleic Acids and Proteins


Book Description

DNA (sometimes referred to as the molecule of life), is the most interesting and most important of all molecules. Electrochemistry of Nucleic Acids and Proteins: Towards Electrochemical Sensors for Genomics and Proteomics is devoted to the electrochemistry of DNA and RNA and to the development of sensors for detecting DNA damage and DNA hybridization. Volume 1, in the brand new series Perspectives in Bioanalysis, looks at the electroanalytical chemistry of nucleic acids and proteins, development of electrochemical sensors and their application in biomedicine and in the new fields of genomics and proteomics. The authors have expertly formatted the information for a wide variety of readers, including new developments that will inspire students and young scientists to create new tools for science and medicine in the 21st century.* Covers highly sophisticated methods of electrochemical analysis of nucleic acids and proteins* Summarises the present state of electrochemical analysis of nucleic acids and proteins* Includes future trends in the electrochemical analysis in genomics and proteomics