The Diffuse Interstellar Bands


Book Description

The mystery of the diffuse interstellar bands has been variously a curiosity, a co nundrum, and a nuisance for astronomers in the seven decades since the features were first noticed, but recently they have become a forefront issue in astrophysics. Ever since Paul Merrill, in a series of papers starting in 1934, pointed out the interstellar and unidentified nature of the bands, a Who's Who of twentieth century astronomers have tried their hands at solving the problem of identifying the carriers. Henry Norris Russell, Pol Swings, Otto Struve, Paul Ledoux, W. W. Morgan, Walter Adams, Jesse Greenstein, Lawrence Aller, and Gerhard Herzberg all briefly entered the stage, only to move on quickly to other problems where the chances for progress appeared more realistic. In more recent times a number of equally prominent scientists have pursued the bands, but generally only as a sideline to their real astronomical research. But in the past decade, and particularly in the past three years, the view of the search for the diffuse band absorbers as an interesting but perhaps quixotic quest has changed. Today there are several astronomers, as well as laboratory chemists, who are devoting substantial research time and resources to the problem and, as perhaps the most reliable indicator of the newly elevated status of research in this field, some research grants have now been awarded for the study of the bands.




Solid State Astrochemistry


Book Description

The fundamentals of astrochemistry in the gas phase are relatively well established, in contrast to the special relevance attributed to processes involving interstellar dust grains - the solid component of matter diffused among the stars. This book presents the state of the art in relation to the ways grains interact with gases, the catalytic role played by dust that allows key molecular species (H2 as well as many complex, possibly prebiotic species) to be formed on its surface - which cannot be obtained efficiently by any other mechanisms, and the interaction between solids (dust grains, icy mantles, cometary nuclei, satellites of the giant planets and minor bodies in the Solar system) in space and energetic agents such as UV photons and fast particles. The presence and importance of PAH, which may represent the smallest component of the grains, is considered in relation to possible astrobiological pathways and the ever-present mystery of the ubiquitous presence of Diffuse Interstellar Bands and their carriers.




The Carcinogenic Effects Of Polycyclic Aromatic Hydrocarbons


Book Description

This book provides an overview on the molecular mode of action of carcinogenic polycyclic aromatic hydrocarbons (PAHs). PAHs are by-products arising from incomplete combustion of organic matter that are frequently released into our environment, and thus are ubiquitously detectable. Many PAHs are strong carcinogens in rodent bioassays and have been linked to increased incidences of various types of cancer in humans. The present book covers all aspects of PAH-induced carcinogenesis; it is a collection of articles written by some of the most recognizable PAH researchers, reviewing the present knowledge in this field. The topics include: exposure to and biomonitoring of PAHs in the human population; metabolic activation of PAHs; genotoxicity and repair of PAH-induced DNA damage; and factors modulating individual susceptibility to the deleterious effects of PAHs.




Orbital Interactions in Chemistry


Book Description

Explains the underlying structure that unites all disciplinesin chemistry Now in its second edition, this book explores organic,organometallic, inorganic, solid state, and materials chemistry,demonstrating how common molecular orbital situations arisethroughout the whole chemical spectrum. The authors explore therelationships that enable readers to grasp the theory thatunderlies and connects traditional fields of study withinchemistry, thereby providing a conceptual framework with which tothink about chemical structure and reactivity problems. Orbital Interactions in Chemistry begins by developingmodels and reviewing molecular orbital theory. Next, the bookexplores orbitals in the organic-main group as well as in solids.Lastly, the book examines orbital interaction patterns that occurin inorganic-organometallic fields as well as clusterchemistry, surface chemistry, and magnetism in solids. This Second Edition has been thoroughly revised andupdated with new discoveries and computational tools since thepublication of the first edition more than twenty-five years ago.Among the new content, readers will find: * Two new chapters dedicated to surface science and magneticproperties * Additional examples of quantum calculations, focusing oninorganic and organometallic chemistry * Expanded treatment of group theory * New results from photoelectron spectroscopy Each section ends with a set of problems, enabling readers totest their grasp of new concepts as they progress through the text.Solutions are available on the book's ftp site. Orbital Interactions in Chemistry is written for bothresearchers and students in organic, inorganic, solid state,materials, and computational chemistry. All readers will discoverthe underlying structure that unites all disciplines inchemistry.




Theory and Applications of Computational Chemistry


Book Description

Computational chemistry is a means of applying theoretical ideas using computers and a set of techniques for investigating chemical problems within which common questions vary from molecular geometry to the physical properties of substances. Theory and Applications of Computational Chemistry: The First Forty Years is a collection of articles on the emergence of computational chemistry. It shows the enormous breadth of theoretical and computational chemistry today and establishes how theory and computation have become increasingly linked as methodologies and technologies have advanced. Written by the pioneers in the field, the book presents historical perspectives and insights into the subject, and addresses new and current methods, as well as problems and applications in theoretical and computational chemistry. Easy to read and packed with personal insights, technical and classical information, this book provides the perfect introduction for graduate students beginning research in this area. It also provides very readable and useful reviews for theoretical chemists.* Written by well-known leading experts * Combines history, personal accounts, and theory to explain much of the field of theoretical and compuational chemistry* Is the perfect introduction to the field




Composition and Origin of Cometary Materials


Book Description

Comet nuclei are the most primitive bodies in the solar system. They have been created far away from the early Sun and their material properties have been altered the least since their formation. Thus, the composition and structure of comet nuclei provide the best information about the chemical and thermodynamic conditions in the nebula from which our solar system formed. In this volume, cometary experts review a broad spectrum of ideas and conclusions based on in situ measurement of Comet Halley and remote sensing observations of the recent bright Comets Hale-Bopp and Hyakutake. The chemical character of comet nuclei suggests many close similarities with the composition of interstellar clouds. It also suggests material mixing from the inner solar nebula and challenges the importance of the accretion shock in the outer nebula. The book is intended to serve as a guide for researchers and graduate students working in the field of planetology and solar system exploration. Several special indexes focus the reader's attention to detailed results and discussions. It concludes with recommendations for laboratory investigations and for advanced modeling of comets, the solar nebula, and the collapse of interstellar clouds.




Origins of Life


Book Description

Origins of Life: A Cosmic Perspective presents an overview of the concepts, methods, and theories of astrobiology and origins of life research while presenting a summary of the latest findings. The book provides insight into the environments and processes that gave birth to life on our planet, which naturally informs our assessment of the probability that has arisen (or will arise) elsewhere. In addition, the book encourages readers to go beyond basic concepts, to explore topics in greater depth, and to engage in lively discussions. The text is intended to be suitable for mid- and upper-level undergraduates and beginning graduate students and more generally as an introduction and overview for researchers and general readers seeking to follow current developments in this interdisciplinary field. Readers are assumed to have a basic grounding in the relevant sciences, but prior specialized knowledge is not required. Each chapter concludes with a list of questions and discussion topics as well as suggestions for further reading. Some questions can be answered with reference to material in the text, but others require further reading and some have no known answers. The intention is to encourage readers to go beyond basic concepts, to explore topics in greater depth, and, in a classroom setting, to engage in lively discussions with class members.




Astrochemistry


Book Description

The dynamic field of astrochemistry brings together ideas of physics, astrophysics, biology and chemistry to the study of molecules between stars, around stars and on planets. Astrochemistry: from Astronomy to Astrobiology provides a clear and concise introduction to this rapidly evolving multidisciplinary subject. Starting with the Molecular Universe, the text covers the formation of the elements, simple models of stars and their classification. It then moves on to draw on the theme of the Origins of Life to study interstellar chemistry, meteorite and comet chemistry as well as the chemistry of planets. Prebiotic chemistry and astrobiology are explored by examining the extremes of the biosphere on Earth, seeing how this may be applied to life in other solar systems. Astrochemsitry assumes a basic familiarity with principles of physical and organic chemistry but no prior knowledge of biology or astrophysics. This innovative text incorporates results from the latest research and ground and space missions, with key images enhanced by a colour plate section. includes latest research and results from ground and space missions colour plate section summary of concepts and calculations at the end of each chapter accompanying website www.wiley.co/go/shawastrochemistry This book will be an ideal text for an undergraduate course in Astrochemistry and an essential tool for postgraduates entering the field.




Planets, Stars and Stellar Systems


Book Description

This is volume 5 of Planets, Stars and Stellar Systems, a six-volume compendium of modern astronomical research, covering subjects of key interest to the main fields of contemporary astronomy. This volume on “Galactic Structure and Stellar Populations”, edited by Gerard F. Gilmore, presents accessible review chapters on Stellar Populations, Chemical Abundances as Population Tracers, Metal-Poor Stars and the Chemical Enrichment of the Universe, The Stellar and Sub-Stellar Initial Mass Function of Simple and Composite Populations, The Galactic Nucleus, The Galactic Bulge, Open Clusters and Their Role in the Galaxy, Star Counts and the Nature of Galactic Thick Disk, The Infrared Galaxy, Interstellar PAHs and Dust, Galactic Neutral Hydrogen, High-Velocity Clouds, Magnetic Fields in Galaxies, Astrophysics of Galactic Charged Cosmic Rays, Gamma-Ray Emission of Supernova Remnants and the Origin of Galactic Cosmic Rays, Galactic Distance Scales, Globular Cluster Dynamical Evolution, Dynamics of Disks and Warps, Mass Distribution and Rotation Curve in the Galaxy, Dark Matter in the Galactic Dwarf Spheroidal Satellites, and History of Dark Matter in Galaxies. All chapters of the handbook were written by practicing professionals. They include sufficient background material and references to the current literature to allow readers to learn enough about a specialty within astronomy, astrophysics and cosmology to get started on their own practical research projects. In the spirit of the series Stars and Stellar Systems published by Chicago University Press in the 1960s and 1970s, each chapter of Planets, Stars and Stellar Systems can stand on its own as a fundamental review of its respective sub-discipline, and each volume can be used as a textbook or recommended reference work for advanced undergraduate or postgraduate courses. Advanced students and professional astronomers in their roles as both lecturers and researchers will welcome Planets, Stars and Stellar Systems as a comprehensive and pedagogical reference work on astronomy, astrophysics and cosmology.