Geochemistry of Marine Sediments


Book Description

The processes occurring in surface marine sediments have a profound effect on the local and global cycling of many elements. This graduate text presents the fundamentals of marine sediment geochemistry by examining the complex chemical, biological, and physical processes that contribute to the conversion of these sediments to rock, a process known as early diagenesis. Research over the past three decades has uncovered the fact that the oxidation of organic matter deposited in sediment acts as a causative agent for many early diagenetic changes. Summarizing and discussing these findings and providing a much-needed update to Robert Berner's Early Diagenesis: A Theoretical Approach, David J. Burdige describes the ways to quantify geochemical processes in marine sediment. By doing so, he offers a deeper understanding of the cycling of elements such as carbon, nitrogen, and phosphorus, along with important metals such as iron and manganese. No other book presents such an in-depth look at marine sediment geochemistry. Including the most up-to-date research, a complete survey of the subject, explanatory text, and the most recent mathematical formulations that have contributed to our greater understanding of early diagenesis, Geochemistry of Marine Sediments will interest graduate students of geology, geochemistry, and oceanography, as well as the broader community of earth scientists. It is poised to become the standard text on the subject for years to come.




Biogeochemistry of Marine Dissolved Organic Matter


Book Description

Marine dissolved organic matter (DOM) is a complex mixture of molecules found throughout the world's oceans. It plays a key role in the export, distribution, and sequestration of carbon in the oceanic water column, posited to be a source of atmospheric climate regulation. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, focuses on the chemical constituents of DOM and its biogeochemical, biological, and ecological significance in the global ocean, and provides a single, unique source for the references, information, and informed judgments of the community of marine biogeochemists. Presented by some of the world's leading scientists, this revised edition reports on the major advances in this area and includes new chapters covering the role of DOM in ancient ocean carbon cycles, the long term stability of marine DOM, the biophysical dynamics of DOM, fluvial DOM qualities and fate, and the Mediterranean Sea. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, is an extremely useful resource that helps people interested in the largest pool of active carbon on the planet (DOC) get a firm grounding on the general paradigms and many of the relevant references on this topic. - Features up-to-date knowledge of DOM, including five new chapters - The only published work to synthesize recent research on dissolved organic carbon in the Mediterranean Sea - Includes chapters that address inputs from freshwater terrestrial DOM




Interactions of C, N, P and S Biogeochemical Cycles and Global Change


Book Description

This book is a natural extension of the SCOPE (Scientific Committee of Problems on the Environment) volumes on the carbon (C), nitrogen (N), phosphorus (P) and sulfur (S) biogeochemical cycles and their interactions (Likens, 1981; Bolin and Cook, 1983). Substantial progress in the knowledge of these cycles has been made since publication of those volumes. In particular, the nature and extent of biological and inorganic interactions between these cycles have been identified, positive and negative feedbacks recognized and the relationship between the cycles and global environmental change preliminarily elucidated. In March 1991, a NATO Advanced Research Workshop was held for one week in Melreux, Belgium to reexamine the biogeochemical cycles of C, N, P and S on a variety of time and space scales from a holistic point of view. This book is the result of that workshop. The biogeochemical cycles of C, N, P and S are intimately tied to each other through biological productivity and subsequently to problems of global environmental change. These problems may be the most challenging facing humanity in the 21 st century. In the broadest sense, "global change" encompasses both changes to the status of the large, globally connected atmospheric, oceanic and terrestrial environments (e. g. tropospheric temperature increase) and change occurring as the result of nearly simultaneous local changes in many regions of the world (e. g. eutrophication).




Chemistry of Marine Water and Sediments


Book Description

The most important processes on the Earth`s surface occur in the Ocean where materials and energy are primarily exchanged. In the case of marine chemistry different fields of chemistry from organic to inorganic as well as thermodynamics and biochemistry are involved. Analytical Chemistry is a very important tool for the quantification of biogeochemical processes by providing correct and even more sophisticated methodologies. These are often directly applied 'in situ', in order to detect trace and ultra-trace natural and anthropogenic substances. Kinetic and thermodynamic studies allow us to establish whether the process occurs. Once discovered it is then possible to build up general models for environmental systems. This book gathers many aspects with the aim of creating a general picture of the chemical processes occurring in the marine environment




Organic Geochemistry


Book Description

For many years, the subject matter encompassed by the title of this book was largely limited to those who were interested in the two most economically important organic materials found buried in the Earth, namely, coal and petroleum. The point of view of any discussions which might occur, either in scientific meetings or in books that have been written, was, therefore, dominated largely by these interests. A great change has occurred in the last decade. This change had as its prime mover our growing knowledge of the molecular architecture of biological systems which, in turn, gave rise to a more legitimate asking of the question: "How did life come to be on the surface of the Earth?" A second motivation arose when the possibilities for the exploration of planets other than the Earth-the moon, Mars, and other parts of the solar system-became a reality. Thus the question of the possible existence of life elsewhere than on Earth conceivably could be answered.




Organic Phosphorus in Marine Sediments


Book Description

Phosphorus, an essential nutrient, is removed from the oceans only through burial with marine sediments. Organic phosphorus (Porg) constitutes an important fraction (ca. 25%) of total-P in marine sediments. However, given the inherent lability of primary Porg biochemicals, it is a puzzle that any Porg is preserved in marine sediments. The goal of this thesis was to address this apparent paradox by linking bulk and molecular-level Porg information. A newly-developed sequential extraction method, which isolates sedimentary Porg reservoirs based on solubility, was used in concert with 31P nuclear magnetic resonance spectroscopy (31P-NMR) to quantify Porg functional group concentrations. The coupled extraction/31P-NMR method was applied to three sediment cores from the Santa Barbara Basin, and the first-ever high-resolution depth profiles of molecular-level Porg distribution during diagenesis were generated. These depth profiles were used to consider regulation of Porg distribution by biomass abundance, chemical structure, and physical protection mechanisms. Biomass cannot account for more than a few percent of sedimentary Porg. No evidence for direct structural control on remineralization of Porg was found. Instead, sorptive protection appears to be an important mechanism for Porg preservation, and structure may act as a secondary control due to preferential sorption of specific Porg compound classes.




Coastal Upwelling Its Sediment Record


Book Description

NATO Advanced Research Institutes are designed to explore unre solved problems. By focusing complementary expertise from various disciplines onto one unifying theme, they approach old problems in new ways. In line with this goal of the NATO Science Committee, and with substantial support from the u.s. Office of Naval Research and the Seabed Assessment Program of the u.s. National Science Founda tion, such a Research Institute on the theme of Coastal Qpw llinq and Its Sediment Record was held September 1-4, 1981, in Vilamoura, Portuqal. The theme implies a modification of uniformitarian thinking in earth science. Expectations were directed not so much towards find ing the key to the past as towards explorinq the limits of interpret inq the past based on present upwelling oceanography. Coastal up wellinq and its imprint on sediments are particularly well-suited for such a scientific inquiry. The oceanic processes and conditions characteristic of upwelling are well understood and are a well packaqed representation of ocean science that are familiar to qeolo gists, just as the maqnitude of bioproduction and sedimentation in upwellinq reqimes --among other bioloqical and geoloqical processes- have made oceanographers realize that the bottom has a feedback role for their models.




Geochemistry of Organic Matter in the Ocean


Book Description

My work Geochemistry oj organic matter in the ocean first appeared in Russian in 1978. Since then much progress has been made in the exploration of various forms of organic matter in the ocean: dissolved, colloidal, organic matter sus pended in particles and that contained in bottom sediments and in interstitial waters. The appropriate evidence is found in hundreds of articles and several re view works, such as Andersen (1977), Biogeochimie de [a matiere organique a ['interjace eau-sedimentmarine (1980), Duursma and Dawson (1981). A great amount of new information has been obtained in the Soviet Union's scientific institutions on the composition and distribution in natural waters and bottom sediments of organic matter and its separate components playing a crucial role in the formation of the chemical and biological structure of the ocean and its productivity, in the biogeochemistry of the elements and geochemistry of organic matter in the Earth's sedimentary cover. The areas of exploration have expanded over the past four-and-a-half years to embrace many new, little-known regions, including the Arctic seas. In contrast to the three preceeding decades, the research has been focused on investigating the existing forms, the distribution and accumulation of organic matter in near continental oceanic zones between land and sea, and in river estuaries.




Sediment Diagenesis


Book Description

The topic of sediment diagenesis is of fundamental importance to industry in the evaluation of hydrocarbon and water reservoir rocks. Detailed knowledge of the diagenetic textures, fabrics, and minerals, and a prediction of the regional diagenetic response, partly controls hydrocarbon recovery programmes. In other words, knowledge of the diagenesis can aid (or even control) conservation policy. Similarly, facies and diagenetic trends w.ithin basins can influence exploration policy. This volume incorporates the majority of the principal contributions given to the NATO Advanced Study Institute held in the University of Reading, U.K., from July 12th-25th, 1981, at which the major themes of carbonate and terrigenous clastic sediments were treated sequentially from deposition to deep burial. Eighty selected scientists from twelve NATO and three other countries participated in the Institute. The keynote addresses which acted as the touchstones for discussion are presented here in the expectation that they will stimulate a still wider audience. We gratefully acknowledge the award of a grant from the Scientific Affairs Division of NATO to run the Institute, and also the cooperation of the University of Reading. Mrs. D. M. Powell helped in many ways with the organisation, and also retyped the entire manuscript of this book. A. Parker B. lv. Sellwood vii FACIES, SEQUENCES AND SAND-BODIES OF THE PRINCIPAL CLASTIC DEPOSITIONAL ENVIRONMENTS T.Elliott Department of Geology University College of Swansea Singleton Park, Swansea SA 2 8PP Wales, U.K.




Treatise on Geochemistry


Book Description

This extensively updated new edition of the widely acclaimed Treatise on Geochemistry has increased its coverage beyond the wide range of geochemical subject areas in the first edition, with five new volumes which include: the history of the atmosphere, geochemistry of mineral deposits, archaeology and anthropology, organic geochemistry and analytical geochemistry. In addition, the original Volume 1 on "Meteorites, Comets, and Planets" was expanded into two separate volumes dealing with meteorites and planets, respectively. These additions increased the number of volumes in the Treatise from 9 to 15 with the index/appendices volume remaining as the last volume (Volume 16). Each of the original volumes was scrutinized by the appropriate volume editors, with respect to necessary revisions as well as additions and deletions. As a result, 27% were republished without major changes, 66% were revised and 126 new chapters were added. In a many-faceted field such as Geochemistry, explaining and understanding how one sub-field relates to another is key. Instructors will find the complete overviews with extensive cross-referencing useful additions to their course packs and students will benefit from the contextual organization of the subject matter Six new volumes added and 66% updated from 1st edition. The Editors of this work have taken every measure to include the many suggestions received from readers and ensure comprehensiveness of coverage and added value in this 2nd edition The esteemed Board of Volume Editors and Editors-in-Chief worked cohesively to ensure a uniform and consistent approach to the content, which is an amazing accomplishment for a 15-volume work (16 volumes including index volume)!