102 Monitor


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Federal Register


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Characterizing Mechanisms of Simultaneous Biological Nutrient Removal During Wastewater Treatment


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Simultaneous biological nutrient removal (SBNR) is the removal of nitrogen and/or phosphorus in excess of that required for biomass synthesis in biological wastewater treatment systems where there are no defined anaerobic and/or anoxic zones. The hypothesis is that one or more of three mechanisms is responsible within individual systems: variations in the bioreactor macroenvironment created by the mixing pattern, gradients within the floc microenvironment, and/or novel microorganism activity. Understanding of the mechanisms of SBNR can be expected to lead to improved efficiency and reliability in its application. Preliminary work documented SBNR in 7 full-scale OrbalTM closed loop bioreactors. A batch assay demonstrated that novel microorganism activity was of little importance in SBNR at the three plants tested. While the floc microenvironment likely plays an important role in nitrogen removal in such plants, it cannot explain phosphorus removal. A computational fluid dynamics (CFD) model was developed to elucidate the role of the bioreactor macroenvironment in SBNR. This is the first reported application of CFD to activated sludge biological wastewater treatment. Although the software and computational requirements limited model complexity, it still simulated the creation of dissolved oxygen gradients within the system, demonstrating that the anaerobic zones required for SBNR could occur.







Assessing Methods of Removing Metals from Wastewater: The Effect of Ferric Chloride Addition


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The presence of cationic pollutant metals in municipal wastewater effluent is a concern because stringent discharge requirements cannot always be met with conventional treatment methods. Attempts to improve metal removal are often unsuccessful because a significant fraction of the cationic metals are complexed by the synthetic chelating agent ethylenediamine tetraacetic acid (EDTA). To identify practical approaches for improving metal removal, an analytical method for measuring metal-EDTA complexes was used to survey metal speciation at a series of wastewater treatment plants. Following these analyses, bench-scale experiments were conducted. The survey data indicated that pollutant metal-EDTA complexes account for a significant fraction of the dissolved metals in wastewater. The bench-scale studies indicated that ferric chloride addition improves the removal of copper and zinc by approximately 20%. To test the results of the bench-scale experiments, a full-scale experiment was conducted by interrupting chemical addition at a municipal wastewater treatment plant that normally adds ferric chloride during primary treatment. Results indicated that ferric chloride addition had a slight impact on metal speciation but no effect on metals removal. The lack of an effect was attributed to changes in metal speciation that occurred during primary treatment irrespective of ferric chloride addition.