Investigation of the Electro-optic and Dielectric Properties of Epitaxial Ferroelectric Thin Films


Book Description

The electro-optic properties of epitaxial BaTiO3 and KTa xNb1-xO3 thin films were investigated to determine their utility as the active medium in electro-optic (EO) devices. The relationship between the EO properties, both static and dynamic, and the ferroelectric (FE) domain structure of the films was determined. A theoretical model was developed to describe the magnitude and dynamic response of the EO effect and dielectric properties of multidomain FE films. The effective linear EO coefficient of each film, reff, was modeled as a linear superposition of the EO response of each FE domain variant, and the dynamic EO response was described in terms of a statistical distribution of domain relaxation times.




Investigation of Ferroelectric Domain Structure and Nonlinear Optical Properties in Barium Titanate Epitaxial Thin Films


Book Description

The ferroelectric material barium titanate exhibits exceptional electro-optic and dielectric properties, making it desirable for electro-optic applications, especially in thin film form. The effective nonlinear optical and dielectric properties of BaTiO3 films are determined by the ferroelectric domain structure. The ferroelectric domain structures of epitaxial BaTiO3 films on MgO (100) substrates were investigated using x-ray diffraction (XRD), scanning probe microscopy (SPM), and second harmonic generation (SHG) techniques.




Mechanic and Dielectric Properties


Book Description

Mechanic and Dielectric Properties deals with the mechanical and dielectric properties of thin films. Topics covered range from the deposition and mechanical properties of superlattice thin films to the preparation of hard coatings by sputtering and arc evaporation. The use of thin films in microwave acoustics is also discussed, along with ferroelectric films for integrated electronics and the physics, chemistry, and technology of electrochromic tungsten-oxide-based thin films. Comprised of five chapters, this volume begins with an analysis of the growth, characterization, and mechanical behavior of films comprising multilayers primarily of metal and refractory metallic compound components. The next chapter reviews the mechanical properties of hard coatings prepared by sputtering and arc evaporation, together with the influence of multilayer and gradient structures, and of film crystallinity, crystal orientation, and morphology, on properties such as hardness, coating smoothness, and friction behavior. Subsequent chapters focus on the unique role played by piezoelectric films in signal processing devices utilizing bulk or surface acoustic waves; the properties and applications of ferroelectric films in integrated electronics; and the underlying physics and chemistry of electrochromic tungsten-oxide-based thin films. This book should be of interest to physicists.




Ferroelectric Thin Films: Volume 200


Book Description

The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.







Ferroelectric Thin Films


Book Description

The impetus for the rapid development of thin film technology, relative to that of bulk materials, is its application to a variety of microelectronic products. Many of the characteristics of thin film ferroelectric materials are utilized in the development of these products - namely, their nonvolatile memory and piezoelectric, pyroelectric, and electro-optic properties. It is befitting, therefore, that the first of a set of three complementary books with the general title Integrated Ferroelectric Devices and Technologies focuses on the synthesis of thin film ferroelectric materials and their basic properties. Because it is a basic introduction to the chemistry, materials science, processing, and physics of the materials from which integrated ferroelectrics are made, newcomers to this field as well as veterans will find this book self-contained and invaluable in acquiring the diverse elements requisite to success in their work in this area. It is directed at electronic engineers and physicists as well as process and system engineers, ceramicists, and chemists involved in the research, design, development, manufacturing, and utilization of thin film ferroelectric materials.




Thin Film Ferroelectric Materials and Devices


Book Description

The past five years have witnessed some dramatic developments in the general area of ferroelectric thin films materials and devices. Ferroelectrics are not new materials by any stretch ofimagination. Indeed, they have been known since the early partofthis century and popular ferroelectric materials such as Barium Titanate have been in use since the second world war. In the late sixties and seventies, a considerable amountofresearch and development effort was made to create a solid state nonvolatile memory using ferroelectrics in a vary simple matrix-addressed scheme. These attempts failed primarily due to problems associated with either the materials ordue to device architectures. The early eighties saw the advent of new materials processing approaches, such as sol-gel processing, that enabled researchers to fabricate sub-micron thin films of ferroelectric materials on a silicon substrate. These pioneering developments signaled the onsetofa revival in the areaofferroelectric thin films, especially ferroelectric nonvolatile memories. Research and development effort in ferroelectric materials and devices has now hit a feverish pitch, Many university laboratories, national laboratories and advanced R&D laboratories oflarge IC manufacturers are deeply involved in the pursuit of ferroelectric device technologies. Many companies worldwide are investing considerable manpower and resources into ferroelectric technologies. Some have already announced products ranging from embedded memories in micro controllers, low density stand-alone memories, microwave circuit elements, andrf identification tags. There is now considerable optimism that ferroelectric devices andproducts will occupy a significant market-share in the new millennium.




Ferroelectrics


Book Description

Combining both fundamental principles and real-life applications in a single volume, this book discusses the latest research results in ferroelectrics, including many new ferroelectric materials for the latest technologies, such as capacitors, transducers and memories. The first two chapters introduce dielectrics and microscopic materials properties, while the following chapter discusses pyroelectricity and piezoelectricity. The larger part of the text is devoted to ferroelectricity and ferroelectric ceramics, with not only their fundamentals but also applications discussed. The book concludes with a look at the future for laser printed materials and applications. With over 600 references to recent publications on piezoelectric and ferroelectric materials, this is an invaluable reference for physicists, materials scientists and engineers.




Growth of Ferro-Electric Tungsten Bronze Epitaxial Thin Films for Electro-Optic Device Applications


Book Description

Strontium Barium Biobates:60 doped with Ce and Fe crystals have now been grown with improved optical quality using the Czochralski technique. The liquid phase epitaxial (LPE) growth of SBN:46 on SBN:60 substrate has also been successfully demonstrated, with particularly good results for (100) and (110) film orientations. The recent photorefractive measurements on Ce doped SBN:60 crystals show that the Tungsten Bronze, SBN:60 crystals are superior in many respects to BaTi03 because of enhanced two beam coupling coefficients, sensitivity and the overall flexibility of tungsten bronze crystals. La3+-doped SBN:50 single crystals have also been grown for pyroelectric detector studies and it was found that the growth of doped crystals is possible. Crystals as large as 1 to 1.5 cm in diameter have been grown successfully. Current measurements show that this composition exhibits excellent pyroelectric and dielectric properties to use in longitudinal configuration; hence, work is in progress to use this composition for pyroelectric detector applications. The role of other cations such as calcium and yttrium has also been studied and they appear to be promising for the proposed device applications.




Ferroelectric Thin Films X: Volume 688


Book Description

The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.