Book Description

Irradiation growth behavior of zirconium, Zircaloy-2 and Zircaloy-4,Zr-2.5Nb, and Zr-3.5Sn-0.8Mo-0.8Nb (EXCEL) was studied on specimens irradiated in the Experimental Breeder Reactor II (EBR-II) to fluences of 1.2 to 16.9 x 1025 neutrons (n).m-2 (E > 1 MeV) in the temperature range 644 to 725 K. In Zircaloy, growth and growth rate were observed to increase continuously with fluence up to 16.9 x 1025 n.m-2 with no indication of saturation in either recrystallized or cold-worked materials. Positive growth strains of 1.5% and negative strains of approximately 2% to 2.5% were observed in both recrystallized and cold-worked Zircaloy. The formation of both a-type loops and c component dislocations is recrystallized Zircaloy under irradiation appears to be the basis in this material for growth strains similar in magnitude to those in cold-worked Zircaloy. Alloy additions to zirconium can increase growth by as much as an order of magnitude for a given texture at the higher irradiation temperatures and fluences. A sharp change to increasing growth rate with temperature occurs in Zircaloy at ~670 K, with a similar trend indicated for the other alloys. Although growth in all these alloys is a strong function of crystallographic texture, an exact (1-3f) type of dependence is not always apparent. In Zr-2.5Nb the dependence of growth on texture appears to be masked by the precipitation of betaniobium, with a transition to a well-defined texture dependence being a function of fluence and temperature. Significant differences in growth behavior were observed in nominally similar Zircaloys, apparently due to minor microstructural or chemical differences.