Quantitative Organic Microanalysis


Book Description

Quantitative Organic Microanalysis, Second Edition presents the recommendations of the American Chemical Society group for specification and methods of organic microanalysis. This book is organized into 23 chapters, and starts with discussions on test samples, blank tests, second type of efficient vibration-absorbing balance table, and microchemical balances. Other general topics covered include the Kjeldahl procedures to determine nitrogen compounds; oxygen flask combustions; determination of fluorine; and microhydrogenation. The final chapters present the modification of the procedure for the determination of oxygen using gravimetry. This book will be of great value to microanalysts, researchers, and college students who wants to expand their understanding in organic microanalysis.







Semimicro Quantitative Organic Analysis


Book Description

Semimicro Quantitative Organic Analysis focuses on the analytical phase of research and chemistry of natural products, as well as analysis of gases and methods used in identifying iodine and other substances. The manuscript first offers information on the determination of carbon, hydrogen, and nitrogen, and the use of Kjeldahl and Dumas methods in the determination of nitrogen. The book also ponders on the determination of halogens, including the use of ethanolamine-sodium, Carius, and sodium peroxide fusion methods and the Liepert volumetric method for iodine. The publication discusses the determination of sulfur and phosphorus, as well as the alkali-nitrate fusion method for converting organic phosphorus to orthophosphate and Woy's procedure for weighing phosphorus as phosphomolybdic anhydride. The text also reviews the determination of methoxyl and ethoxyl and acetyl groups; determination of neutralization equivalent and molecular weights; and determination of volatile fatty acids. The manuscript is a dependable reference for readers interested in the chemistry of natural products.




Qualitative Organic Microanalysis


Book Description

The most important task of the analytical chemist, aside from the acquisition of experimental data, is the coordination and interpretation of such data in terms of the qualitative and quantitative composition of the test substance. As in the old tale of the blind men and the elephant, a single observation or test, not considered in conjunction with others, may lead to entirely erroneous conclusions. On the other hand, mere in crease in the number of such tests, without regard to their need or to their relationship to each other, also may not suffice for drawing the correct inferences from the experimental evidence. The deductive reasoning which is usually associated with the analy tical chemist finds its greatest opportunity for application in the problems of cognition and recognition of carbon compounds. Since a rigid scheme of procedure tends to produce a corresponding rigidity of thought, the intent of the present book is to outline approaches which will minimize the chances of misinterpretation without restricting the analytical chemist in his choice of tests. The selection of subsequent tests or reactions should be governed by the results of the preceding ones rather than by an arbi trary list. The relationships of the various approaches (and the information derived from each) to the composition and constitution of the test sub stance are brought out in the discussion with the hope that they may serve as guide lines for such selection.







Analytical Chemistry of Organic Halogen Compounds


Book Description

Analytical Chemistry of Organic Halogen Compounds presents the procedures applied in the analysis of organic halogen compounds. This book is composed of eight chapters that discuss the methods involved in the production and application of organic halogen compounds and in overcoming contamination problems caused by these compounds. After briefly dealing with the preparation, characteristics, and reactions of organic halogen compounds, this book goes on discussing the fundamental concepts of methods for the detection of halogens in organic compounds, namely, chlorine, bromine, iodine, and fluorine. The following chapter describes the characteristic features, advantages, and disadvantages of ultramicro and submicro chemical methods. A chapter also examines the qualitative and quantitative studies of organic halogen compounds based on the thermal and chemical stability of these compounds. The concluding chapters discuss the interference or interfering effects of halogens and their elimination in the determination of other elements. A list of physical constants of organic halogen compounds of general pharmaceutical and industrial significance is provided. This book is an ideal source for analytical chemists and other workers who are interested in the theoretical bases of the methods.













Industrial Arts Index


Book Description