Multifunctional Coordination Materials for Green Energy Technologies


Book Description

As an emerging material platform, multifunctional coordination materials offer many advantages such as remarkable porosity, structural flexibility, crystallinity, and modifiable functionalities that render them highly suited to generate and store green energy. This book covers the design and fabrication approaches of multifunctional coordination materials for green energy-related technologies, including batteries, supercapacitors, solar cells, and nanogenerators. • Discusses fundamentals of multifunctional coordination materials. • Explains vital synthesis and design techniques as well as theoretical modeling. • Offers a comprehensive overview of preparation, structural and morphological properties, and applications in a wide variety of energy production, energy storage, and energy device technologies. • Assesses environmental impacts, recycling, challenges, and future perspectives. Multifunctional Coordination Materials for Green Energy Technologies is an ideal reference for advanced students and researchers working in materials engineering, including new catalyst development, battery design, and related areas.




Nanostructured Multifunctional Materials


Book Description

The development of nanomaterials plays a fundamental role in current and future technology applications, particularly nanomaterials that have multiple functionalities. This book provides a broad overview of the effect of nanostructuring in the multifunctionality of different widely studied nanomaterials. This book is divided into four sections constituting a road map that groups materials sharing certain types of nanostructuring, including nanoporous, nanoparticled, 2D laminar nanomaterials, and computational methods for characterizations of nanostructures. This structured approach in nanomaterials research will serve as a valuable reference material for chemists, (bio)engineers, physicists, nanotechnologists, undergraduates, and professors.




Structural Design and Properties of Coordination Polymers


Book Description

This book is a printed edition of the Special Issue "Structural Design and Properties of Coordination Polymers" that was published in Crystals




Modern Inorganic Synthetic Chemistry


Book Description

The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems




Introduction to Reticular Chemistry


Book Description

A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.




Supramolecular Chemistry on Surfaces


Book Description

Supramolecular Chemistry on Surfaces 2D Networks and 2D Structures Explore the cutting-edge in 2D chemistry on surfaces and its applications In Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures, expert chemist Neil R. Champness delivers a comprehensive overview of the rapidly developing field of two-dimensional supramolecular chemistry on surfaces. The book offers explorations of the state-of-the-art in the discipline and demonstrates the potential of the latest advances and the challenges faced by researchers in different areas. The editor includes contributions from leading researchers that address new spectroscopic methods which allow for investigations at a sub-molecular level, opening up new areas of understanding in the field. Included resources also discuss important supramolecular strategies, like hydrogen-bonding, van der Waals interactions, metal-ligand coordination, multicomponent assembly, and more. The book also provides: A thorough introduction to two-dimensional supramolecular chemistry on surfaces Comprehensive explorations of the characterization and interpretation of on-surface chemical reactions studied by ultra-high resolution scanning probe microscopy Practical discussions of complexity in two-dimensional multicomponent assembly, including explorations of coordination bonds and quasicrystalline structures In-depth examinations of covalently bonded organic structures via on-surface synthesis Perfect for polymer chemists, spectroscopists, and materials scientists, Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures will also earn a place in the libraries of physical and surface chemists, as well as surface physicists.




Metal-Organic Frameworks


Book Description

Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.




Molecular Networks


Book Description

In the future, many modern materials will be increasingly based on the assembly of preformed molecular entities. Their structural characteristics and functional prop- ties will be programmed at the molecular level and their formation as a completed entity will be achieved by self-assembly processes. This in essence is a bottom-up approach and its success will require a deep understanding not only of the chemistry of intermolecular interactions and associations but also of self-assembly processes in the condensed phase. Among various interesting innovations brought about by the development of supramolecular chemistry, supramolecular synthesis is a part- ularly powerful approach for the design and generation of molecular architectures displaying both structural and functional complexity. The combination of mol- ular synthesis (which allows chemists to design and prepare extremely sophis- cated biotic and abiotic molecules through the interconnection of atoms or group of atoms by strong covalent bonds) and supramolecular synthesis (which orch- trates the association of molecules by recognition processes through the use of weak and reversible interactions) opens up endless structural and functional possibilities. Following the perceptive observation by Dunitz that "A crystal is, in a sense, the supramolecule par excellence", molecular crystals may be seen as in'nite periodic architectures resulting from the interconnection of building blocks or tectons ca- ble of self-assembling through speci'c recognising events.




Lanthanide Metal-Organic Frameworks


Book Description

The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students.




Elaboration And Applications Of Metal-organic Frameworks


Book Description

This title takes researchers in as well as out of the field of metal-organic framework (MOF) and then guides them on a journey to rediscover and rethink how these designer coordination polymers will influence the realm of materials science. This book opens with a look at a deeply controversial issue, MOF stability, which has plagued many systems, but ultimately has led to better materials that proved to be more robust allowing them to be investigated for multiple applications. This book successfully highlights many of these useful applications that MOFs are well adapted for. Because MOF components, inorganic and organic, can combine the best of both chemical domains, MOFs will improve our environment by removing harmful contaminants from the air and water, reduce the energy required to perform chemical reactions, partition hard to separate molecular mixtures, and form the next-generation of magnetic and electronic materials. MOFs will eventually be used for everyday activities — for monitoring or reacting to changing conditions. Readers of this book can then take note and implement MOFs in their line of research.