Rubber Product Failure


Book Description

Rubber components are used in many demanding applications, from tyres and seals to gloves and medical devices, and failure can be catastrophic. This review of Rubber Product Failure outlines and illustrates the common causes of failure, while addressing ways of avoiding it. There has been increasing pressure to improve performance so that rubbers can be used at higher temperatures and in harsher environments. For example, the under-the-bonnet temperature has increased in some vehicles and new medical devices require longer lifetimes in potentially degrading biological fluids. The expectations of tyre performance in particular are increasing, and retreads have been in the spotlight for failures. The definition of failure depends on the application. For example, a racing car engine seal that lasts for one race may be acceptable, but in a normal car a life span of 10 years is more reasonable. If appearance is critical as in surface coatings and paints, then discolouration is failure, whilst in seals leakage is not acceptable. Each rubber product must be fit for the use specified by the consumer. Failure analysis is critical to product improvement. the cause of the problem can be much harder to find. It can range from a design fault to poor material selection, to processing problems, to manufacturing errors such as poor dimensional tolerances, to poor installation, product abuse and unexpected service conditions. The rubber technologist must become a detective, gathering evidence, understanding the material type and using deductive reasoning. Testing and analysis of failed materials and components add to the information available for failure analysis. For example, stored aged tyres appeared superficially to be alright for use, but on drum testing small cracks grew more quickly than in new tyres leading to rapid failure in service. Quality control procedures such as product inspection, testing and material quality checks can help to reach 100 percent reliability. In critical applications such as electricians' gloves for high voltage working, gloves are inspected before each use, while engine seals may be routinely replaced before the expected lifetime to avoid problems. in the literature is not high. However, several reviews have been written on specific products and references can be found at the end of this review. Around 400 abstracts from papers in the Polymer Library are included with an index. Subjects covered include tyre wear and failure, seals, engine components, rubber bonding failure, rubber failure due to chloramine in water, tank treads, gloves and condoms, medical devices and EPDM roofing membranes.




Failure of Plastics and Rubber Products


Book Description

Plastics and rubbers together make up the most adaptable and varied class of materials available to product designers. They may be transparent or opaque, rigid or flexible, lightweight, insulating, and weatherproof. They are used in almost every industry, and in every part of the home. Applications range from the humble hot water bottle to the sheathing on a high voltage cable, and from a simple scrubbing brush to a tank for storing hydrochloric acid. Products may be disposable (e.g. packaging goods) or intended to last for decades, such as a buried sewage pipe. However, it is this very diversity which makes materials selection so difficult, and appropriate design so important. Indeed the one thing that all these particular products have in common is their presence in this book of failures. Failures due to degradation may result from exposure to the weather or an aggressive operating environment. Alternatively they may be caused by the introduction of an external agent unforeseen by the product designer. They may be rapid or very slow, and they may result from a combination of factors. In this book Dr. Wright describes the following mechanisms of polymer degradation, and then illustrates each failure mechanism with a number of case studies: Thermo-oxidation, Photo-oxidation, Degradation due to ionising radiation, Chemical attack, Environmental stress cracking, Other miscellaneous effects, including treeing, electrochemical degradation and biodegradation. Many of the case studies are based on Dr. Wrights own experiences whilst working at Rapra. In each case he describes the circumstances of the failure, and discusses both the consequences of the failure and the lessons that may be learned from it. Most of the failed products are familiar to us all, and his style is both readable and informative. Photographs are included where available. The book will be essential reading for designers, engineers, product specifiers and forensic engineers. Materials suppliers and processors will also benefit from the pragmatic analysis and advice it contains. It will also be of value to all students of polymer science and technology, providing an essential insight into the practical application of plastics and rubbers and the potential problems. Finally, it will be of interest to a much broader readership, including anyone who ever wondered why things break, and it should become a standard reference work in all technical libraries. This book was written with the support of the UK Department of Trade and Industry. It is intended to raise awareness of the causes and consequences of polymer product failures, in order to reduce the future incidences of such failures, and their considerable costs to industry




Rubber Analysis


Book Description

Rubber analysis plays a vital part in ensuring that manufactured products are fit for purpose. This comprehensive, application-based book with up-to-date referencing covers all important applications and subject area associated with the analysis of rubber compounds and rubber products. Includes characterization of rubber polymers, rubber fumes, identification of extractables and leachables, as well as reverse engineering on compounded products.




Rubber Products


Book Description

Rubber Products describes cost-effective and environmentally friendly technologies in the field of rubber. The book covers rubber compounding, innovations in rubber-based products, devulcanisation of cured rubber and provides lean management techniques. It explains the commercial advantages of graphene-rubber nanocomposites, details the morphology of most common reinforcing carbon blacks and explores innovative applications of rubber in automotive and Defence sectors. The title is also discussing potential alternative technologies which could disrupt the rubber industry in the future. All chapters are written by prominent rubber scientists from both the industry and academia.




Reverse Engineering of Rubber Products


Book Description

Reverse engineering is widely practiced in the rubber industry. Companies routinely analyze competitors’ products to gather information about specifications or compositions. In a competitive market, introducing new products with better features and at a faster pace is critical for any manufacturer. Reverse Engineering of Rubber Products: Concepts, Tools, and Techniques explains the principles and science behind rubber formulation development by reverse engineering methods. The book describes the tools and analytical techniques used to discover which materials and processes were used to produce a particular vulcanized rubber compound from a combination of raw rubber, chemicals, and pigments. A Compendium of Chemical, Analytical, and Physical Test Methods Organized into five chapters, the book first reviews the construction of compounding ingredients and formulations, from elastomers, fillers, and protective agents to vulcanizing chemicals and processing aids. It then discusses chemical and analytical methods, including infrared spectroscopy, thermal analysis, chromatography, and microscopy. It also examines physical test methods for visco-elastic behavior, heat aging, hardness, and other features. A chapter presents important reverse engineering concepts. In addition, the book includes a wide variety of case studies of formula reconstruction, covering large products such as tires and belts as well as smaller products like seals and hoses. Get Practical Insights on Reverse Engineering from the Book’s Case Studies Combining scientific principles and practical advice, this book brings together helpful insights on reverse engineering in the rubber industry. It is an invaluable reference for scientists, engineers, and researchers who want to produce comparative benchmark information, discover formulations used throughout the industry, improve product performance, and shorten the product development cycle.




Rubber Analysis


Book Description

Rubber analysis plays a vital part in ensuring that manufactured products are fit for purpose. This comprehensive, application-based book with up-to-date referencing covers all important applications and subject area associated with the analysis of rubber compounds and rubber products. Includes characterization of rubber polymers, rubber fumes, identification of extractables and leachables, as well as reverse engineering on compounded products.




Fatigue Crack Growth in Rubber Materials


Book Description

The book summarizes recent international research and experimental developments regarding fatigue crack growth investigations of rubber materials. It shows the progress in fundamental as well as advanced research of fracture investigation of rubber material under fatigue loading conditions, especially from the experimental point of view. However, some chapters will describe the progress in numerical modeling and physical description of fracture mechanics and cavitation phenomena in rubbers. Initiation and propagation of cracks in rubber materials are dominant phenomena which determine the lifetime of these soft rubber materials and, as a consequence, the lifetime of the corresponding final rubber parts in various fields of application. Recently, these phenomena became of great scientific interest due to the development of new experimental methods, concepts and models. Furthermore, crack phenomena have an extraordinary impact on rubber wear and abrasion of automotive tires; and understanding of crack initiation and growth in rubbers will help to support the growthing number of activities and worldwide efforts of reduction of tire wear losses and abrasion based emissions.




Polymer Product Failure


Book Description

Use of polymers in product design has continued to grow at a rate unrivalled by conventional materials such as metal, ceramics or glass. More polymeric materials are becoming available to the designer, and this report highlights the need for caution in new design work, for careful use of new materials, and for awareness of the product environment. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database gives useful references for further reading.




Mixing of Vulcanisable Rubbers and Thermoplastic Elastomers


Book Description

This report describes the current state-of-the-art in mixing from a practical viewpoint. It begins by offering historical background against which the latest developments are set. It considers both batch and continuous systems, containing details of key developments by equipment manufacturers, with the different concepts discussed in layman's terms. This report also summarises the range of mixing techniques applied in the industry as well as methods for monitoring mixing quality both off- and on-line are also covered. Recent academic research in rubber mixing is briefly considered, providing an indication of possible future practical advances in this field. This review of rubber mixing is supported by an indexed section containing several hundred key references and abstracts selected from the Rapra Abstracts database.




Fractography in Failure Analysis of Polymers


Book Description

Fractography in Failure Analysis of Polymers provides a practical guide to the science of fractography and its application in the failure analysis of plastic components. In addition to a brief background on the theory of fractography, the authors discuss the various fractographic tools and techniques used to identify key fracture characteristics. Case studies are included for a wide range of polymer types, applications, and failure modes, as well as best practice guidelines enabling engineers to apply these lessons to their own work. Detailed images and their appropriate context are presented for reference in failure investigations. This text is vital for engineers who must determine the root causes of failure when it occurs, helping them further study the ramifications of product liability claims, environmental concerns, and brand image. - Presents a comprehensive guide to applied fractography, enabling improved reliability and longevity of plastic parts and products - Includes case studies that demonstrate material selection decisions and how to reduce failure rates - Provides best practices on how to analyze the cause of material failures, along with guidelines on improving design and manufacturing decisions




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