Non-equilibrium Phenomena In Supercooled Fluids, Glasses And Amorphous Materials - Proceedings Of The Workshop


Book Description

This volume contains the Proceedings of the International Workshop on “Non-Equilibrium Phenomena in Supercooled Fluids, Glasses and Amorphous Materials”, held in Pisa in the early fall of 1995 as a joint initiative of the University of Pisa and of the Scuola Normale Superiore. The goal was to bring together liquid state physicists, chemists and engineers, to review current developments and comparatively discuss experimental facts and theoretical predictions in this vast scientific area. The core of the Workshop was a set of general lectures followed by more specific presentations on current issues in the main areas of the field. This structure has been maintained in this volume, in which a set of five overviews is followed by topically grouped contributions in the five areas of ionic glasses and glassy materials, the glass transition, viscous flow and microscopic relaxation, complex fluids, and polymers. The volume also preserves a record of the many short contributions given to the Workshop through posters, which are grouped in it under the subjects of inorganic glasses, organic glasses and complex fluids, polymers, and theoretical aspects.




The Glass Transition


Book Description

Describes and interrelates the following processes: cooperative alpha processes in a cold liquid, structural relaxation in the glass near Tg, the Johari-Goldstein beta process, the Williams-Götze process in a warm liquid, fast nonactivated cage rattling and boson peak, and ultraslow Fischer modes.







Scaling And Disordered Systems: International Workshop And Collection Of Articles Honoring Professor Antonio Coniglio On The Occasion Of His 60th Birthday


Book Description

Investigation of the fractal and scaling properties of disordered systems has recently become a focus of great interest in research. Disordered or amorphous materials, like glasses, polymers, gels, colloids, ceramic superconductors and random alloys or magnets, do not have a homogeneous microscopic structure. The microscopic environment varies randomly from site to site in the system and this randomness adds to the complexity and the richness of the properties of these materials. A particularly challenging aspect of random systems is their dynamical behavior. Relaxation in disordered systems generally follows an unusual time-dependent trajectory. Applications of scaling and fractal concepts in disordered systems have become a broad area of interdisciplinary research, involving studies of the physics, chemistry, mathematics, biology and engineering aspects of random systems.This book is intended for specialists as well as graduate and postdoctoral students working in condensed-matter or statistical physics. It provides state-of-the-art information on the latest developments in this important and timely topic. The book is divided into three parts: Part I deals with critical phenomena, Part II is devoted to discussion of slow dynamics and Part III involves the application of scaling concepts to random systems. The effects of disorder at the mesoscopic scale as well as the latest results on the dynamical properties of disordered systems are presented. In particular, recent developments in static and dynamic scaling theories and applications of fractal concepts to disordered systems are discussed.




Amorphous Insulators and Semiconductors


Book Description

The aim of this NATO ASI has been to present an up-to-date overview of current areas of interest in amorphous materials. In order to limit the material to a manageable amount, the meeting was concerned exclusively with insulating and semiconducting materials. The lectures and seminars fill the gap between graduate courses and research seminars. The lecturers and seminar speakers were chosen as experts in their respective areas and the lectures and seminars that were given are presented in this volume. During the first week of the meeting. an emphasis was placed on introductory lectures, mainly associated with questions relating to the glass-formation and the structure of glasses. The second week focused more on research seminars. Each day of the meeting. about four posters were presented during the coffee breaks, and these formed an important focus for discussions. The posters are not reproduced in this volume as the editors wanted to have only larger contributions to make this volume more coherent. This volume is organized into four sections, starting with general considerations of the glass forming ability and techniques for the preparation of different kinds of glasses.




Metastable Systems under Pressure


Book Description

recently discovered advantages of amorphous forms of medicines/pharmaceutical products which focused a significant part of industry-related efforts on the GFA (Glass Forming Ability) and the glass temperature (T) versus pressure g dependences. 1 b ? 0 ? ? o ? P ? Pg P ? Pg 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g ? 0 ? ? ? ? c + Pg ? ? ? ? 400 1 b 0 o ? ? ? ? P ? P P ? P g g 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g 0 ? ? ? ? c ? + P max g ? ? ? ? T ~7 GPa g max P ~ 304 K Liquid g 300 1 HS glass 0 200 -1 mSG ?=0. 044 Liquid -2 100 -3 glass ?=0. 12 -1. 2 -0. 9 -0. 6 -0. 3 0. 0 log T 10 scaled -1 0 1 2 3 4 5 6 7 8 9 10 11 12 P (GPa) g 19 Figure 1. T he pressure evolution of the glass temperature in gl Th ye s cerol ol . id curve shows the parameterization of experimental data via the novel, modifie d Glat Sizm elon type equation, given in the Figure.













Index of Conference Proceedings


Book Description