Agromining: Farming for Metals


Book Description

This second and expanded edition of the first book on agromining (phytomining) presents a comprehensive overview of the metal farming & recovery of the agromining production chain. Agromining is an emerging technology that aims to transform the extraction of sources of target elements not accessible by traditional mining and processing techniques. Agromining, which is based on sustainable development, uses hyperaccumulator plants as 'metal crops' farmed on sub-economic soils or minerals wastes to obtain valuable target elements. This volume is edited and authored by the pioneers in the rapidly expanding field of agromining and presents the latest insights and developments in the field. This book provides in-depth information on the global distribution and ecology of hyperaccumulator plants, their biogeochemical pathways, the influence of rhizosphere microbes, the physiology and molecular biology of hyperaccumulation, as well as aspects of propagation and conservation of these unusual plants. It describes the agronomy of metal crops and opportunities for incorporating agromining into rehabilitation and mine closure, including test cases for agromining of nickel, cobalt, manganese, arsenic, selenium, cadmium, zinc, thallium, rare earth elements and platinum group elements. Since the first edition was published, there have successful nickel agromining field trials in the tropics (in Malaysia and Guatemala), and these are presented in a dedicated case study chapter. Other new chapters focus on the processing of bio-ore for elements other than nickel, such as rare earth elements and cadmium, and on agromining from industrial wastes such as tailings, and industrial by-products and sites. Furthermore, the book features two new chapters that provide a comprehensive assessment of accumulation a very wide range elements from the Periodic Table in various plant species around the globe, and a chapter on practical methods for discovery of hyperaccumulator plant species in the field and in the herbarium. This book is of interest to environmental professionals in the minerals industry, government regulators, and academics.




Extractive Metallurgy of Niobium


Book Description

The growth and development witnessed today in modern science, engineering, and technology owes a heavy debt to the rare, refractory, and reactive metals group, of which niobium is a member. Extractive Metallurgy of Niobium presents a vivid account of the metal through its comprehensive discussions of properties and applications, resources and resource processing, chemical processing and compound preparation, metal extraction, and refining and consolidation. Typical flow sheets adopted in some leading niobium-producing countries for the beneficiation of various niobium sources are presented, and various chemical processes for producing pure forms of niobium intermediates such as chloride, fluoride, and oxide are discussed. The book also explains how to liberate the metal from its intermediates and describes the physico-chemical principles involved. It is an excellent reference for chemical metallurgists, hydrometallurgists, extraction and process metallurgists, and minerals processors. It is also valuable to a wide variety of scientists, engineers, technologists, and students interested in the topic.




Handbook on Rare Earth Metals and Alloys (Properties, Extraction, Preparation and Applications)


Book Description

Rare earths are essential constituents of more than 100 mineral species and present in many more through substitution. They have a marked geochemical affinity for calcium, titanium, niobium, zirconium, fluoride, phosphate and carbonate ions. Industrially important minerals, which are utilized at present for rare earths production, are essentially three, namely monazite, bastnasite and xenotime. In modern time techniques for exploration of rare earths and yttrium minerals include geologic identification of environments of deposition and surface as well as airborne reconnaissance with magnetometric and radiometric equipment. There are numerous applications of rare earths such as in glass making industry, cracking catalysts, electronic and optoelectronic devices, medical technology, nuclear technology, agriculture, plastic industry etc. Lot of metals and alloys called rare earth are lying in the earth which required to be processed. Some of the important elements extracted from rare earths are uranium, lithium, beryllium, selenium, platinum metals, tantalum, silicon, molybdenum, manganese, chromium, cadmium, titanium, tungsten, zirconium etc. There are different methods involved in production of metals and non metals from rare earths for example; separation, primary crushing, secondary crushing, wet grinding, dry grinding etc. The rare earths are silver, silverymwhite, or gray metals; they have a high luster, but tarnish readily in air, have high electrical conductivity. The rare earths share many common properties this makes them difficult to separate or even distinguish from each other. There are very small differences in solubility and complex formation between the rare earths. The rare earth metals naturally occur together in minerals. Rare earths are found with non metals, usually in the 3+ oxidation state. At present all the rare earth resources in India are in the form of placer monazite deposits, which also carry other industrially important minerals like ilmenite, rutile, zircon, sillimanite and garnet. Some of the fundamentals of the book are commercially important rare earth minerals, exploration for rare earth resources, rare earth resources of the world, some rare earth minerals and their approximate compositions, rare earths in cracking catalysts, rare earth based phosphors, interdependence of applications and production of rare earths, uranium alloys, conversion of ores to lithium chemicals, characterization and analysis of very pure silicon, derivation of molybdenum metal, electoplating and chromizing, electrolytic production of titanium, heat treatment of titanium alloys, tensile properties of alloys etc. The book covers occurrence of rare earth, resources of the world, production of lithium metals, compounds derived from the metals, chemical properties of beryllium, uses of selenium, derivation of molybdenum metals, ore concentration and treatment and many more. This is a unique book of its kind, which will be a great asset for scientists, researchers, technocrats and entrepreneurs. 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Light Emitting Silicon for Microphotonics


Book Description

A fascinating insight into the state-of-the-art in silicon microphotonics and on what we can expect in the near future. The book presents an overview of the current understanding of getting light from silicon. It concentrates mainly on low dimensional silicon structures, like quantum dots, wires and wells, but covers also alternative approaches like porous silicon and the doping of silicon with rare-earths. The emphasis is on the experimental and theoretical achievements concerning the optoelectronic properties of confined silicon structures obtained during recent years. Silicon based photonic crystals are in particular considered. An in depth discussion of the route towards a silicon laser is presented.




Environmental Barrier Coatings


Book Description

The global increase in air travel will require commercial vehicles to be more efficient than ever before. Advanced engine hot section materials are a key technology required to keep fuel consumption and emission to a minimum in next-generation gas turbines. Ceramic matrix composites (CMCs) are the most promising material to revolutionize gas turbine hot section materials technology because of their excellent high‐temperature properties. Rapid surface recession due to volatilization by water vapor is the Achilles heel of CMCs. Environmental barrier coatings (EBCs) is an enabling technology for CMCs, since it protects CMCs from water vapor. The first CMC component entered into service in 2016 in a commercial engine, and more CMC components are scheduled to follow within the next few years. One of the most difficult challenges to CMC components is EBC durability, because failure of EBC leads to a rapid reduction in CMC component life. Key contributors to EBC failure include recession, oxidation, degradation by calcium‐aluminum‐magnesium silicates (CMAS) deposits, thermal and thermo‐mechanical strains, particle erosion, and foreign object damage (FOD). Novel EBC chemistries, creative EBC designs, and robust processes are required to meet EBC durability challenges. Engine-relevant testing, characterization, and lifing methods need to be developed to improve EBC reliability. The aim of this Special Issue is to present recent advances in EBC technology to address these issues. In particular, topics of interest include but are not limited to the following: • Novel EBC chemistries and designs; • Processing including plasma spray, suspension plasma spray, solution precursor plasma spray, slurry process, PS-PVD, EB-PVD, and CVD; • Testing, characterization, and modeling; • Lifing.




Hydrometallurgy of Rare Earths


Book Description

Hydrometallurgy of Rare Earths: Extraction and Separation provides the basic knowledge for rare earth extraction and separation, including flow sheet selection criteria and related technology. The book includes the latest research findings on all rare earth separation processes, methods of controlling operation costs, and strategies that help lower wastewater and waste solid discharge. It discusses many real process parameters and actual situations in rare earth separation plants, also examining the basic principles, technologies, process parameters and advances and achievements in the area of rare earth extraction and separation. In addition, the book covers extraction separation theory as developed by Professor Guanxian Xu and Professor Chunhua Yan and the creative use of a computational simulation program to replace the bench scale and pilot plant tests and directly design rare earth extraction separation processes. - Outlines the theory of solvent extraction and separation of rare earths (REs) - Provides the necessary tools for a REs separation plant design - Includes a unique simulation program for the calculation of all process parameters - Includes Chinese nomenclature that is useful for identifying the various processes, also comparing it to the global literature







Properties of Crystalline Silicon


Book Description

A unique and well-organized reference, this book provides illuminating data, distinctive insight and expert guidance on silicon properties.




Fluid Cracking Catalysts


Book Description

Reviews recent accomplishments in the field of fluid cracking catalysts (FCC). Discusses the development of more specialized and effective catalysts and processes as well as the modification of current technology to meet future challenges in fuel refining. Written by nearly 50 internationally recognized experts from academia and industry.