Supramolecular Polymers


Book Description

Supramolecular Polymers, Second Edition details assembly processes and structure-function correlation in natural and synthetic self-assembling materials, focusing on developments occurred over the past five years. The book highlights developments in the synthesis of complex structures, chemical design principles, and theoretical models of




Supramolecular Chemistry


Book Description

Supramolecular chemistry is ‘chemistry beyond the molecule’ - the chemistry of molecular assemblies and intermolecular bonds. It is one of today’s fastest growing disciplines, crossing a range of subjects from biological chemistry to materials science; and from synthesis to spectroscopy. Supramolecular Chemistry is an up-to-date, integrated textbook that tells the newcomer to the field everything they need to know to get started. Assuming little in the way of prior knowledge, the book covers the concepts behind the subject, its breadth, applications and the latest contemporary thinking in the area. It also includes coverage of the more important experimental and instrumental techniques needed by supramolecular chemists. The book has been thoroughly updated for this second edition. In addition to the strengths of the very popular first edition, this comprehensive new version expands coverage into a broad range of emerging areas. Clear explanations of both fundamental and nascent concepts are supplemented by up-to-date coverage of exciting emerging trends in the literature. Numerous examples and problems are included throughout the book. A system of “key references” allows rapid access to the secondary literature, and of course comprehensive primary literature citations are provided. A selection of the topics covered is listed below. Cation, anion, ion-pair and molecular host-guest chemistry Crystal engineering Topological entanglement Clathrates Self-assembly Molecular devices Dendrimers Supramolecular polymers Microfabrication Nanoparticles Chemical emergence Metal-organic frameworks Gels Ionic liquids Supramolecular catalysis Molecular electronics Polymorphism Gas sorption Anion-pinteractions Nanochemistry Supramolecular Chemistry is a must for both students new to the field and for experienced researchers wanting to explore the origins and wider context of their work. Review: "At just under 1000 pages, the second edition of Steed and Atwood's Supramolecular Chemistry is the most comprehensive overview of the area available in textbook form...highly recommended." —Chemistry World, August 2009




Metallo-Supramolecular Polymers


Book Description

This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.




Supramolecular Polymer Chemistry


Book Description

Presenting the work of pioneering experts in this exciting field of supramolecular polymer chemistry, this monograph covers an extensive range of applications, including drug delivery and catalysis. It focuses on new structures and phenomena of cyclodextrin-based supramolecular polymers and many other compound classes. While providing a deeper insight in macromolecular recognition and the mechanisms of living systems, this book also introduces fascinating novel phenomena beyond natural systems.




Handbook of Conducting Polymers, Second Edition,


Book Description

Discussing theory and transport, synthesis, processing, properties, and applications, this second edition of a standard resource covers advances in the field of electrically conducting polymers and contains more than 1500 drawings, photographs, tables, and equations. Maintaining the style of presentation and depth of coverage that made the first edition so popular, it contains the authoritative contributions of an interdisciplinary team of world-renowned experts encompassing the fields of chemistry, physics, materials science, and engineering. The Handbook of Conducting Polymers highlights progress, delineates improvements, and examines novel tools for polymer and materials scientists..




Supramolecular Chemistry


Book Description

This introductory textbook on supramolecular chemistry is a thoroughly revised and expanded version of the 1st edition, originally published in 2020. All chapters have been brought up to date and now include "Further Reading" sections that highlight relevant developments. In addition, a new chapter on supramolecular polymers has been added. With these changes, this book provides an even more comprehensive introduction to the exciting field of supramolecular chemistry than before. Readers will learn what forces hold supramolecular architectures together, how supramolecular systems are created and characterized, how molecular switches, motors, transporters, catalysts, chemosensors, and other functional systems work, and where supramolecular chemistry can play or already plays a role in our lives. In 2022 the first edition of this book won the Literature Prize of the German Chemical Industry Association VCI. For the full press release (in German): https://www.vci.de/fonds/presse-und-infos/pressemitteilungen/preisgeld-fuer-supramolekuele.jsp




Self-Healing Polymer-Based Systems


Book Description

Self-Healing Polymer-Based Systems presents all aspects of self-healing polymeric materials, offering detailed information on fundamentals, preparation methods, technology, and applications, and drawing on the latest state-of-the-art research. The book begins by introducing self-healing polymeric systems, with a thorough explanation of underlying concepts, challenges, mechanisms, kinetic and thermodynamics, and types of chemistry involved. The second part of the book studies the main categories of self-healing polymeric material, examining elastomer-based, thermoplastic-based, and thermoset-based materials in turn. This is followed by a series of chapters that examine the very latest advances, including nanoparticles, coatings, shape memory, self-healing biomaterials, ionomers, supramolecular polymers, photoinduced and thermally induced self-healing, healing efficiency, life cycle analysis, and characterization. Finally, novel applications are presented and explained. This book serves as an essential resource for academic researchers, scientists, and graduate students in the areas of polymer properties, self-healing materials, polymer science, polymer chemistry, and materials science. In industry, this book contains highly valuable information for R&D professionals, designers, and engineers, who are looking to incorporate self-healing properties in their materials, products, or components. - Provides comprehensive coverage of self-healing polymeric materials, covering principles, techniques, and applications - Includes the very latest developments in the field, such as the role of nanofillers in healing, life cycle analysis of materials, and shape memory assisted healing - Enables the reader to unlock the potential of self-healing polymeric materials for a range of advanced applications




Supramolecular Chemistry


Book Description

The aim of this book is to return to the biomimicry and medicinal potential that inspired many of the early supramolecular chemists and to set it in the context of current advances in the field. Following an overview of supramolecular chemistry, the first section considers the efforts made to synthesize artificial systems that mimic biological entities. The second section addresses the application of supramolecular principles to molecular diagnostics with a particular emphasis on the ‘receptor-relayreporter’ motif. Many of the examples chosen have clinical importance. The third section takes the clinical diagnostic theme further and demonstrates the therapeutic applications of supramolecular chemistry through photodynamic therapy, drug delivery, and the potential for synthetic peptides to form antibiotic tubes. The short epilogue considers the potential for supramolecular solutions to be found for further challenges in biomimetic and therapeutic chemistry.




Smart Polymers and Their Applications


Book Description

Smart Polymers and Their Applications, Second Edition presents an up-to-date resource of information on the synthesis and properties of different types of smart polymers, including temperature, pH, electro, magnetic and photo-responsive polymers, amongst others. It is an ideal introduction to this field, as well as a review of the latest research in this area. Shape memory polymers, smart polymer hydrogels, and self-healing polymer systems are also explored. In addition, a very strong focus on applications of smart polymers is included for tissue engineering, smart polymer nanocarriers for drug delivery, and the use of smart polymers in medical devices. Additionally, the book covers the use of smart polymers for textile applications, packaging, energy storage, optical data storage, environmental protection, and more. This book is an ideal, technical resource for chemists, chemical engineers, materials scientists, mechanical engineers and other professionals in a range of industries. - Includes a significant number of new chapters on smart polymer materials development, as well as new applications development in energy storage, sensors and devices, and environmental protection - Provides a multidisciplinary approach to the development of responsive polymers, approaching the subject by the different types of polymer (e.g. temperature-responsive) and its range of applications




Physical Properties of Polymers


Book Description

The contents have been divided into sections on physical states of polymers and characterization techniques. Chapters on physical states include discussions of the rubber elastic state, the glassy state, melts and concentrated solutions, the crystalline state, and the mesomorphic state. Characterization techniques described are molecular spectroscopy and scattering techniques.