Surface Mobilities on Solid Materials


Book Description

The surface of solids had long been considered simply the external boundary which determined the outside appearance of the solids but had no intrinsic character of its own. The concept that surfaces have specific properties and are the first and foremost means of communication between individual things and the rest of the universe is fairly new, coming into prominence only in the early sixties. This new concept of surface properties was the result of a vast accumulation of knowledge due to recent development of research in this area. This breakthrough of surface science resulted from the combined action of four factors: (i) control of surface sample prep aration, (ii) control of the surface's environment, (iii) improve ment of measurement tools and techniques, and (iv) the importance of surface properties in many new industrial areas. Nearly eighty techniques are now available to help us answer to the following questions: what is the surface structure or arrangement of surface atoms? what are the atomic species present? what is the spatial distribution of foreign atoms? what are the nature and distribution of possible defects on the surface? what is the electronic structure of the surface atoms? what is the motion of atoms on the surface? In general, two or more analytical techniques are used concurrently to assure unequivocal answers to problems. Different techniques employ different combina. tions of incident probes and the scattered or secondary particles that convey information regarding the sur faces.




Surfaces and Interfaces of Solid Materials


Book Description

Surfaces and Interfaces of Solid Materials emphasises both experimental and theoretical aspects of surface and interface physics. Beside the techniques of preparing well-defined solid surfaces and interfaces basic models for the description of structural, vibronic and electronic properties of interfaces are described, as well as fundamental aspects of adsorption and layer growth. Because of its importance for modern microelectronics special emphasis is placed on the electronic properties of semiconductor interfaces and heterostructures. Experimental topics covering the basics of ultrahigh-vacuum technology, electron optics, surface spectroscopies and electrical interface characterization techniques are presented in the form of separate panels.




Surface Diffusion


Book Description

The interest in the problem of surface diffusion has been steadily growing over the last fifteen years. This is clearly evident from the increase in the number of papers dealing with the problem, the development of new experimental techniques, and the specialized sessions focusing on diffusion in national and international meetings. Part of the driving force behind this increasing activity is our recently acquired ability to observe and possibly control atomic scale phenomena. It is now possible to look selectively at individual atomistic processes and to determine their relative importance during growth and reactions at surfaces. The number of researchers interested in this problem also has been growing steadily which generates the need for a good reference source to farniliarize newcomers to the problem. While the recent emphasis is on the role of diffusion during growth, there is also continuing progress on the more traditional aspects of the problem describing mass transport in an ensemble of particles. Such a description is based on the statistical mechanical analysis of a collection of particles that mutually interact and develop correlations. An average over the multitude of atomistic processes that operate under these conditions is necessary to fully describe the dynamics in the system.




Diffusion in Materials


Book Description

This volume is the proceedings of the NATO Advanced Study Institute, "Diffusion in Materials", held at "Centre Paul Langevin", Aussois, during March 12-25, 1989. There were 105 participants of whom 24 were lecturers and members of the international advisory committee. In addition to the participants from NATO countries, a small number of participants came from Australia, Hungary, Poland and Tunisia. The principal aim of the organizing committee was to bring together scientists of wide interest and expertise in the field of diffusion and to familiarize the young workers in material science with the wide range of theoretical models and methods and of experimental techniques . The Institute was concerned with the study of diffusion and related phenomena in solids which are at the cutting edge of novel technologies. The discussion of basic theories of defects in solids and their transport, with their applications in the understanding of diffusion processes in "simple solids" was followed by the wide range of current theoretical models and methods, experimental techniques and their potential. The lectures on the diffusion in specific materials included : metals, dilute and concentrated alloys, simple and compound semiconductors, stoichiometric and non-stoichiometric oxides, high-Tc compounds, carbides, nitrides, silicates, conducting polymers and thin films, ionic, superionic, amorphous and irradiated materials.




The Synergy Between Dynamics and Reactivity at Clusters and Surfaces


Book Description

The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.




Handbook of Self-Cleaning Surfaces and Materials


Book Description

Handbook of Self-Cleaning Surfaces and Materials The first truly comprehensive work on this rapidly developing field in two volumes Self-cleaning surfaces are those that can be cleaned, for instance, by sun or rainwater, without human intervention. They are sometimes found in nature but developing man-made equivalents has been a major area of nanotechnology research in recent years. Self-cleaning tiles, glasses, paints, and textiles have been developed to date, and the number of applications for this technology is growing. Handbook of Self-Cleaning Surfaces and Materials provides a comprehensive overview of this field of study. It includes two volumes, with the first presenting the basic principles of the field and the second supplying specific examples and applications. It is a one-stop shop for anyone looking to familiarize themselves with this area of technological research, as well as for existing professionals who want a handy and thorough reference. Readers of the Handbook of Self-Cleaning Surfaces and Materials will also find: An editor and contributor team with decades of experience in both academic and industrial research Detailed treatment of subjects including TiO2 photocatalysis, hydrophobic self-cleaning surfaces, and more Figures throughout illustrating important concepts and chemical formulas Handbook of Self-Cleaning Surfaces and Materials is an essential resource for researchers and industry professionals in chemistry, surface physics, and materials science.




Diffusion at Interfaces: Microscopic Concepts


Book Description

Diffusion in solids and at interfaces is a very active area of research, as the contributions to this volume attest.




Fractals, Scaling and Growth Far from Equilibrium


Book Description

A comprehensive, 1998 account of the practical aspects and pitfalls of the applications of fractal modelling in the physical sciences.




Emerging Two Dimensional Materials and Applications


Book Description

This book details 2D nanomaterials, and their important applications—including recent developments and related scalable technologies crucial to addressing strong societal demands of energy, environmental protection, and worldwide health concerns—are systematically documented. It covers syntheses and structures of various 2D materials, electrical transport in graphene, and different properties in detail. Applications in important areas of energy harvesting, energy storage, environmental monitoring, and biosensing and health care are elaborated. Features: Facilitates good understanding of concepts of emerging 2D materials and its applications. Covers details of highly sensitive sensors using 2D materials for environmental monitoring. Outlines the role of 2D materials in improvement of energy harvesting and storage. Details application in biosensing and health care for the realization of next-generation biotechnologies for personalized health monitoring and so forth. Provides exclusive coverage of inorganic 2D MXenes compounds. This book is aimed at graduate students and researchers in materials science and engineering, nanoscience and nanotechnology, and electrical engineering.




Handbook of Surfaces and Interfaces of Materials, Five-Volume Set


Book Description

This handbook brings together, under a single cover, all aspects of the chemistry, physics, and engineering of surfaces and interfaces of materials currently studied in academic and industrial research. It covers different experimental and theoretical aspects of surfaces and interfaces, their physical properties, and spectroscopic techniques that have been applied to a wide class of inorganic, organic, polymer, and biological materials. The diversified technological areas of surface science reflect the explosion of scientific information on surfaces and interfaces of materials and their spectroscopic characterization. The large volume of experimental data on chemistry, physics, and engineering aspects of materials surfaces and interfaces remains scattered in so many different periodicals, therefore this handbook compilation is needed.The information presented in this multivolume reference draws on two decades of pioneering research on the surfaces and interfaces of materials to offer a complete perspective on the topic. These five volumes-Surface and Interface Phenomena; Surface Characterization and Properties; Nanostructures, Micelles, and Colloids; Thin Films and Layers; Biointerfaces and Applications-provide multidisciplinary review chapters and summarize the current status of the field covering important scientific and technological developments made over past decades in surfaces and interfaces of materials and spectroscopic techniques with contributions from internationally recognized experts from all over the world. Fully cross-referenced, this book has clear, precise, and wide appeal as an essential reference source long due for the scientific community. The complete reference on the topic of surfaces and interfaces of materialsThe information presented in this multivolume reference draws on two decades of pioneering researchProvides multidisciplinary review chapters and summarizes the current status of the fieldCovers important scientific and technological developments made over past decades in surfaces and interfaces of materials and spectroscopic techniquesContributions from internationally recognized experts from all over the world