Systematics and the Properties of the Lanthanides


Book Description

Science is not a mere collection of facts. It is the correlation of facts, the interpretative synthesis of the available knowledge and its application that excite the imagination of a scientist. Even in these days of modern technology, the need for quick and accurate dissemination of new information and current concepts still exists. Conferences and Symposia offer one direct method of communication. The Summer Schools are another approach. The success of a Summer School is mainly due to that human factor and under standing that goes with it and allows for extensive and often time-unrestricted discussions. During the course of the past 20 years, one of the most in tensively studied groups of elements in the Periodic Table is the Lanthanides. In this period, we have increased our knowledge on these once exotic elements, which were once considered to be a part of a lean and hungry industry, many-fold due to the involve ment of scientists from various disciplines. The purpose of our Summer School was to bring a group of ex perts and participants together for the exchange of ideas and in formation in an informal setting and to promote interdisciplinary interactions. Out of many conceivable topics, we selected the following five as the main basis to broaden our knowledge and understanding I) Systematics 2) Structure 3) Electronic and Magnetic Proper ties 4) Spectroscopic Properties and 5) Lanthanide Geochemistry.







Colour of Metal Compounds


Book Description

The Colour of Metal Compounds is devoted to the qualitative and quantitative treatment of colour in inorganic and coordination compounds. In order to understand the use of colour as a source of structural and analytical information, the book explains in depth the interrelation between colour and structural properties of compounds. Trichromatic colorimetry is introduced as a method for the quantitative evaluation of colour. Further chapters cover chromaticity and spectroscopy, lanthanides, colour centres, colour in mineralogy, pigments, coloured glass, and the colour use in teaching. Fully revised from the original Polish edition, this book is recommended as a supplementary text for undergraduate and graduate level courses on transition metal chemistry, coordination chemistry, spectroscopy and colour chemistry. It will also be of interest to researchers in chemistry, physics, mineralogy and the pigment and glass industry.




Handbook on the Physics and Chemistry of Rare Earths


Book Description

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements with two published volumes each year. - Presents up-to-date overviews and new developments in the field of rare earths, covering both their physics and chemistry - Contains Individual chapters that are comprehensive and broad, with critical reviews - Provides contributions from highly experienced, invited experts




Lanthanides Series Determination by Various Analytical Methods


Book Description

Lanthanides Series Determination by Various Analytical Methods describes the different spectroscopic and electrochemical methods used for the determination and measurement of lanthanides. Numerous examples of determination methods used in real sample analysis are gathered and explained, and the importance of lanthanides as applied in chemical industry, agriculture, clinical and pharmaceutical industry, and biology is discussed, with many applications and recent advantages given. - Written by world-leading experts in research on lanthanide determination - Discusses determination methods that range from very advanced and expensive techniques to simple and inexpensive methods - A single source of information for a broad collection of lanthanide detection techniques and applications - Includes a complete list of reports and patents on lanthanide determination - Discusses both advantages and disadvantages of each determination method, giving a well-balanced overview







Lanthanide and Actinide Chemistry


Book Description

The only introduction into the exciting chemistry of Lanthanides and Actinides. The book is based on a number of courses on "f elements" The author has a long experience in teaching this field of chemistry Lanthanides have become very common elements in research and technology applications; this book offers the basic knowledge The book offers insights into a vast range of applications, from lasers to synthesis The Inorganic Chemistry: A Textbook series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry. Lanthanide and Actinide Chemistry is a one-volume account of the Lanthanides (including scandium and yttrium), the Actinides and the Transactinide elements, intended as an introductory treatment for undergraduate and postgraduate students. The principal features of these elements are set out in detail, enabling clear comparison and contrast with the Transition Elements and Main Group metals. The book covers the extraction of the elements from their ores and their purification, as well as the synthesis of the man-made elements; the properties of the elements and principal binary compounds; detailed accounts of their coordination chemistry and organometallic chemistry, from both preparative and structural viewpoints, with a clear explanation of the factors responsible for the adoption of particular coordination numbers; spectroscopy and magnetism, especially for the lanthanides, with case studies and accounts of applications in areas like magnetic resonance imaging, lasers and luminescence; nuclear separations and problems in waste disposal for the radioactive elements, particularly in the context of plutonium. Latest developments are covered in areas like the synthesis of the latest man-made elements, whilst there is a whole chapter on the application of lanthanide compounds in synthetic organic chemistry. End-of-chapter questions suitable for tutorial discussions are provided, whilst there is a very comprehensive bibliography providing ready access to further reading on all topics.




Lanthanide Luminescence


Book Description

Lanthanides have fascinated scientists for more than two centuries now, and since efficient separation techniques were established roughly 50 years ago, they have increasingly found their way into industrial exploitation and our everyday lives. Numerous applications are based on their unique luminescent properties, which are highlighted in this volume. It presents established knowledge about the photophysical basics, relevant lanthanide probes or materials, and describes instrumentation-related aspects including chemical and physical sensors. The uses of lanthanides in bioanalysis and medicine are outlined, such as assays for in vitro diagnostics and research. All chapters were compiled by renowned scientists with a broad audience in mind, providing both beginners in the field and advanced researchers with comprehensive information on on the given subject.




The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)


Book Description

The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.




Lanthanides, Tantalum and Niobium


Book Description

Rare Earth Elements (REE) as well as tantalum and niobium are of tremendous importance because of their specific high-technology applications. The contributions gathered in this volume give an up-to-date survey on the mineralogy, primary ore deposits, prospecting, processing and applications of REE, Ta, and Nd, making this volume a useful handbook for practitioners and students. Finally, the comprehensive coverage of the fundamental aspects, especially as regards REE as tracers of geological phenomena, will prove extremely helpful.