The Catalytic Activation of Small Molecules by Transition Metal Complexes
Author : Edward Mason Gordon
Publisher :
Page : 456 pages
File Size : 24,25 MB
Release : 1987
Category :
ISBN :
Author : Edward Mason Gordon
Publisher :
Page : 456 pages
File Size : 24,25 MB
Release : 1987
Category :
ISBN :
Author : William B. Tolman
Publisher : John Wiley & Sons
Page : 382 pages
File Size : 35,50 MB
Release : 2006-12-13
Category : Science
ISBN : 3527609377
The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.
Author : Helen R. Sharpe
Publisher :
Page : pages
File Size : 38,6 MB
Release : 2017
Category :
ISBN :
Author : Philip Vasil Yaneff
Publisher :
Page : pages
File Size : 17,55 MB
Release : 1976
Category :
ISBN :
Author : Ahmad Najafian
Publisher :
Page : 113 pages
File Size : 18,45 MB
Release : 2020
Category : Activation (Chemistry)
ISBN :
Author : David Morales-Morales
Publisher : Elsevier
Page : 756 pages
File Size : 46,42 MB
Release : 2018-04-11
Category : Science
ISBN : 0128129328
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. - Describes the chemistry and applications of this important class of organometallic and coordination compounds - Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes - Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry
Author : Françoise Colobert
Publisher : John Wiley & Sons
Page : 294 pages
File Size : 31,48 MB
Release : 2019-11-11
Category : Science
ISBN : 3527343407
Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.
Author : László I. Simándi
Publisher : Springer
Page : 397 pages
File Size : 37,61 MB
Release : 2012-10-04
Category : Science
ISBN : 9789401052658
The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspects are emphasized throughout the book. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.
Author : Junghee Seo
Publisher :
Page : 202 pages
File Size : 45,91 MB
Release : 2015
Category : Transition metal complexes
ISBN :
Author : Robert H. Crabtree
Publisher : Wiley-Interscience
Page : 520 pages
File Size : 37,49 MB
Release : 1994-04
Category : Science
ISBN :
Later chapters discuss applications of organometallics such as: catalytic uses of transition metals; activation of small molecules; applications to organic synthesis; and carbenes, metathesis, and polymerization. Also discussed are the role of organometallics in biochemical areas, clusters, metal-metal bonds, and high-oxidation-state complexes.