The Analytical Chemistry of Silicones


Book Description

High-Resolution Solid-State NMR of Silicates and Zeolites Gunter Engelhardt and Dieter Michel "I strongly recommend this book as an important reference for scientists concerned with the structural properties of siliceous materials." --Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with emphasis on the kinds of chemical information retrievable from NMR experiments. 1988 (0 471-91597-1) 485 pp. The Chemistry of Silica Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry Ralph K. Iler A major component of the earth's solid surface and the constituent of sand, silica--an ageless natural staple--is also integral to industries as diverse as chemistry, biology, medicine, agriculture, metallurgy, and mining. This landmark reference details the chemistry surrounding the research and development of silica as well as information on its production and production control. 1979 (0 471-02404-X) 866 pp. The Chemistry of Organic Silicon Compounds Parts 1 and 2 Edited by Saul Patai and Zvi Rappoport "This volume will probably become the first reference consulted for C-Si chemistry." --Choice This authoritative account of organic compounds containing carbon-silicon bonds brings specialists up-to-date to the field's latest innovative turns. The emphasis in this compilation of studies--from 17 prominent researchers--is on small molecules, single bonds, analysis, structure, synthesis, spectroscopy, and reaction mechanisms. Part 1:1989 (0 471-91441-X) 892 pp. Part 2:1989 (0 471-91992-6) 1,668 pp.




Efficient Methods for Preparing Silicon Compounds


Book Description

Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter




Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb


Book Description

Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry




Organometallic Chemistry


Book Description

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.




The Chemistry of Organogold Compounds, 2 Volume Set


Book Description

The first book in the PATAI Series was published in 1964 and the Series will celebrate its 50th Anniversary in 2014. This "Golden Jubilee" is accompanied by the publication of the first volume on the chemistry of organogold. In the history of the PATAI Series there was, so far, no volume dedicated to gold alone. In 1999 we published a volume on The Chemistry of Gold and Silver Compounds. Since then a lot of new chemistry using gold has been developed and it is timely to focus a volume on methods and applications of organogold compounds in organic synthesis, reflecting the enormous progress which has been made in the use of gold compounds as reagents and catalysts. A second area of great importance covered in the book is the use of gold surfaces in the synthesis of peptides, proteins and other natural products. A whole range of applications in the area of biochemistry has resulted from these developments. A third area of interest is the synthesis and engineering of nanostructures, where organogold chemistry has opened the door for a wide range of methods and applications in the field of nanoscience and materials science. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.




Organosilicon Chemistry


Book Description




Reviews of Reactive Intermediate Chemistry


Book Description

The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes: Relevant, practical applications Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces Discussions of emerging areas, particularly those involving dynamics and theories Concluding sections identifying key directions for future research are provided at the end of each chapter




Organosilicon Compounds


Book Description

Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology