Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals


Book Description

Since the early 1930's, Soviet chemists have played a lead ing role in the study of unfamiliar oxidation state compounds of the peroxide, superoxide, and ozonide types. Interest in the alkali and alkaline earth metal derivatives is now widespread and diverse, and numerous practical applications of these com pounds have evolved, ranging from their use as air revitaliza tion materials in space cabins to their use in compounding semiconductor materials. Professor Vol'nov is eminently qualified to write this monograph since for many years he has been a leading investi gator and prolific writer in the field of peroxide, superoxide, and ozonide chemistry. He has succeeded in presenting a lucid and detailed discussion of past work, the present state, and the future potential of this area of unfamiliar oxidation state chemistry. Of particular interest is Professor Vol 'nov's extensive compilation of available thermodynamic, kinetic, and structural data for the alkali and alkaline earth peroxides, superoxides, and ozonides. In addition, he has reviewed the known methods of synthesis, as well as the practical applications for which these compounds are suited. This monograph will be of interest and value to chemists, not only for the information it imparts, but equally for the information it does not impart, thereby illuminating the re search paths and investigation which must be undertaken in order to increase our knowledge concerning the chemistry of this important class of chemical compounds.




Fire and Explosion Hazards of Peroxy Compounds


Book Description




The Chemistry of Organic Derivatives of Gold and Silver


Book Description

The 100th volume in this highly successful and renowned Patai andRappoport series 'The Chemistry of Functional Groups' is fittinglydevoted to the precious metals, gold and silver. Gold is a soft metal occurring naturally as particles in quartz oras nuggets. Gold was initially used extensively in coinage andjewellery and has recently found applications in biochemistry,medicine and material science. Gold readily forms organometalliccompounds (R-Au-L with L = sulphide, phosphine and isocyanide),oxides and halides. Silver is a ductile metal which was used incoinage and for mirrors. It is now used for jewellery, electricalconductors, dental and surgical components. Silver forms stablesilver halides for use in Photography and i.r. spectroscopy as asupport material. Other silver compounds are also used incatalysis. This volume contains 16 chapters dealing with calculations onorganogold compounds, physical and spectroscopic properties (NMR,ESR, PES, Mossbauer spectra), thermochemical and analyticalproperties, the synthesis and uses of the title compounds and theirreactions such as rearrangements, pyrolysis and photochemicalreactions. The medicinal use of organogold compounds and theincreased use of gold-thiol monolayers are also summarized. Each of the chapters has been prepared by leading scientists inthis field making this volume invaluable for researchers inacademia and industry working with gold and silver, inbiochemistry, pharmaceutical and materials chemistry. Organic compunds containg Nitrogen are of outstanding importnce inbiochemistry and in environmental systems. This volume gives asound introduction into physical chemistry of amino, nitriso, nitroand related functional groups. This volume is now available in electronic format from BooksOnline.




Catalytic Oxidations with Hydrogen Peroxide as Oxidant


Book Description

Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.




March's Advanced Organic Chemistry


Book Description

The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations




The Chemistry of Peroxides, Parts 1 and 2, 2 Volume Set


Book Description

The Chemistry of Peroxides is a new volume in the Chemistry of Functional Groups series. This series covers all aspects of organic chemistry with each volume containing chapters on: General and theoretical aspects Computational approaches Thermodynamics and kinetics NMR and ESR Mass Spectrometry Spectroscopies Analytical aspects Reaction mechanisms Syntheses Biological effects Environmental effects Industrial applications Edited by Zvi Rappoport, this series provides outstanding reviews on all aspects of functional groups in analytical, physical, synthetic and applied chemistry.







The Chemistry of Peroxides, Volume 3


Book Description

The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.




Hydrogen Peroxide Metabolism in Health and Disease


Book Description

Much of the biology of oxidative stress and oxidative signalling centres on the generation and handling of hydrogen peroxide. The overall aim for this book would be to provide an insightful and useful forum to assist with the understanding of the relevance of hydrogen peroxide generation and how this is managed in human biology. The target audience would be those who currently have an interest in the generation of ROS, but who do not have expertise in chemistry, as well as those experts in the chemistry of oxidative stress, but without detailed understanding of the biologically relevant setting. We would aim to bridge the gap in understanding between chemistry and biology.