The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys


Book Description

Metals and alloys rely for their application at high temperature on the formation and retention of oxide scales, which act as a barrier between the metallic substrate and the reactive species in the environment such as 0, S, N, C, Cl, etc. This protection concept requires that the oxide grows slowly, develops a dense, uniform layer, is well adherent, has sufficient ductility to accom modate plastic deformation of the substrate and is resistant to thermal cycling. For many years it has been known that small concentrations of certain "active elements" such as Y and the rare earths, as well as carbon and sulphur, can exercise a significant influence upon the oxidation! corrosion behaviour of high temperature metals and alloys. An increasing number of experimental studies on this topic have been published recently. However no generally accepted understanding with regard to the detailed mechanisms and the way in which alloy composition and structure, temperature and environmental conditions, etc., are interacting has yet been achieved, although many - often controversial - theories and ideas have been presented. It therefore seemed to be an appropriate time to bring together a group of experts to review and evaluate the current state-of-the-art and to discuss various aspects of this important topic.




High Temperature Coatings


Book Description

High Temperature Coatings, Second Edition, demonstrates how to counteract the thermal effects of rapid corrosion and degradation of exposed materials and equipment that can occur under high operating temperatures. This is the first true practical guide on the use of thermally protective coatings for high-temperature applications, including the latest developments in materials used for protective coatings. It covers the make-up and behavior of such materials under thermal stress and the methods used for applying them to specific types of substrates, as well as invaluable advice on inspection and repair of existing thermal coatings. With his long experience in the aerospace gas turbine industry, the author has compiled the very latest in coating materials and coating technologies, as well as hard-to-find guidance on maintaining and repairing thermal coatings, including appropriate inspection protocols. The book is supplemented with the latest reference information and additional support to help readers find more application- and industry-type coatings specifications and uses. - Offers an overview of the underlying fundamental concepts of thermally-protective coatings, including thermodynamics, energy kinetics, crystallography and equilibrium phases - Covers essential chemistry and physics of underlying substrates, including steels, nickel-iron alloys, nickel-cobalt alloys and titanium alloys - Provides detailed guidance on a wide variety of coating types, including those used against high temperature corrosion and oxidative degradation and thermal barrier coatings




Fatigue and Durability of Metals at High Temperatures


Book Description

From concept to application, this book describes the method of strain-range partitioning for analyzing time-dependent fatigue. Creep (time-dependent) deformation is first introduced for monotonic and cyclic loading. Multiple chapters then discuss strain-range partitioning in details for multi-axial loading conditions and how different loading permutations can lead to different micro-mechanistic effects. Notably, the total-strain method of strain-range partitioning (SRP) is described, which is a methodology that sees use in several industries. Examples from aerospace illustrate applications, and methods for predicting time-dependent metal fatigue are critiqued.




High Temperature Oxidation and Corrosion of Metals


Book Description

The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.







ASM Specialty Handbook


Book Description

Materials covered include carbon, alloy and stainless steels; alloy cast irons; high-alloy cast steels; superalloys; titanium and titanium alloys; refractory metals and alloys; nickel-chromium and nickel-thoria alloys; structural intermetallics; structural ceramics, cermets, and cemented carbides; and carbon-composites.







Encyclopedia of Iron, Steel, and Their Alloys (Online Version)


Book Description

The first of many important works featured in CRC Press’ Metals and Alloys Encyclopedia Collection, the Encyclopedia of Iron, Steel, and Their Alloys covers all the fundamental, theoretical, and application-related aspects of the metallurgical science, engineering, and technology of iron, steel, and their alloys. This Five-Volume Set addresses topics such as extractive metallurgy, powder metallurgy and processing, physical metallurgy, production engineering, corrosion engineering, thermal processing, metalworking, welding, iron- and steelmaking, heat treating, rolling, casting, hot and cold forming, surface finishing and coating, crystallography, metallography, computational metallurgy, metal-matrix composites, intermetallics, nano- and micro-structured metals and alloys, nano- and micro-alloying effects, special steels, and mining. A valuable reference for materials scientists and engineers, chemists, manufacturers, miners, researchers, and students, this must-have encyclopedia: Provides extensive coverage of properties and recommended practices Includes a wealth of helpful charts, nomograms, and figures Contains cross referencing for quick and easy search Each entry is written by a subject-matter expert and reviewed by an international panel of renowned researchers from academia, government, and industry. Also Available Online This Taylor & Francis encyclopedia is also available through online subscription, offering a variety of extra benefits for researchers, students, and librarians, including: Citation tracking and alerts Active reference linking Saved searches and marked lists HTML and PDF format options Contact Taylor and Francis for more information or to inquire about subscription options and print/online combination packages. US: (Tel) 1.888.318.2367; (E-mail) [email protected] International: (Tel) +44 (0) 20 7017 6062; (E-mail) [email protected]




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Book Description