Optical Spectra of Phthalocyanines and Related Compounds


Book Description

This book displays how optical (absorption, emission, and magnetic circular dichroism) spectra of phthalocyanines and related macrocyclic dyes can be varied from their prototypical ones depending on conditions. As these compounds can be involved in colorful chemistry (which might be driven by impurities in solvents), their spectra behave like the sea-god Proteus in their mutability. Therefore, those who have been engaged with phthalocyanines for the first time, including even educated professional researchers and engineers, may have been embarrassed by the deceptive behavior of their compounds and could have, in the worst cases, given up their projects. This book is aimed not merely at reviewing the optical spectra, but also at helping such people, particularly beginners, to figure them out by showing some examples of their prototypical spectra and their variations in several situations. For the purpose of better understanding, the book also provides an introduction to their theoretical backgrounds as graphically as possible and without mathematicization for readers who are weak in mathematics.




Infrared Absorbing Dyes


Book Description

New laser technology has developed a new dye chemistry! Development of the gallium-arsenic semiconductor laser (diode laser) that emits laser light at 780-830 nm has made possible development of new opto-electronic systems including laser optical recording systems, thermal writing display systems, laser printing systems, and so on. Medical applications of lasers in photodynamic therapy for the treatment of cancer were also developed. In such systems, the infrared absorbing dyes OR dyes) are currently used as effective photoreceivers for diode lasers, and will become the key materials in high technology. At the present time the chemistry of IR dyes is the most important and interesting field in dye chemistry. Laser light can be highly monochromatic, very well collimated, coher ent, and, in some cases, extremely powerful. These characteristics make diode lasers a very cheap, convenient, and useful light source for a variety of applications in science and technology. For these purposes, however, IR dyes with special characteristics are required. To develop new IR dyes, it is most important to establish the correlation between the chemical structures of dyes and other characteristics of dyes, such as their absorption spectra. Molecular design of IR dyes predicting the Amax and Emax values by molecular orbital (MO) calculations is now possible even by using a personal computer, and many types of new IR dyes have been demonstrated. Also, new opto-electronic systems using IR dyes as photoreceivers have been reported recently.




Phthalocyanine Research and Applications


Book Description

The purpose of this monograph is to provide a summary for those who are active in the field of phthalocyanine research. This volume allows the reader to quickly-and at a reasonable cost-determine what is being accomplished so that he may plan his own research programs. It covers such topics as synthesis, reactions, inks, energy systems, coatings, toners, and electrophotographic plates and developers, just to name a few. Packed with over 40 structural drawings of phthalocyanine molecules, this one-of-a-kind reference provides the necessary description and visualization to stimulate further research. This work is an indispensable resource for researchers and practitioners, both novice and experienced, in the field of phthalocyanine science and technology.




Phthalocyanine Materials


Book Description

This monograph describes the preparation, fabrication and structure of phthalocyanine-based materials.




Molecular Semiconductors


Book Description

During the past thirty years considerable efforts have been made to design the synthesis and the study of molecular semiconductors. Molecular semiconductors - and more generally molecular materials - involve interactions between individual subunits which can be separately synthesized. Organic and metallo-organic derivatives are the basis of most of the molecular materials. A survey of the literature on molecular semiconductors leaves one rather confused. It does seem to be very difficult to correlate the molecular structure of these semiconductors with their experimental electrical properties. For inorganic materials a simple definition delimits a fairly homogeneous family. If an inorganic material has a conductivity intermediate between that of an 12 1 1 3 1 1 insulator « 10- n- cm- ) and that of a metal (> 10 n- cm- ), then it is a semiconductor and will exhibit the characteristic properties of this family, such as junction formation, photoconductivity, and the photovoltaic effect. For molecular compounds, such simplicity is certainly not the case. A huge number of molecular and macromolecular systems have been described which possess an intermediate conductivity. However, the various attempts which have been made to rationalize their properties have, more often than not, failed. Even very basic electrical properties such as the mechanism of the charge carrier formation or the nature and the density ofthe dopants are not known in detail. The study of molecular semiconductor junctions is very probably the most powerful approach to shed light on these problems.




Electronic Properties of Polymers and Related Compounds


Book Description

At the International Winter School on "Electronic Properties of Polymers and Related Compounds" particular attention was paid to a very new and special field in polymer research. It is concerned with the study of the electronic structure of polymers and with physical and chemical properties directly re lated to this structure. In particular, tutorial and research contributions on electrical, electrochemical, optical, magnetic, lattice dynamical and structural properties were presented. In addition, review reports on related topics such as charge transfer complexes and linear-chain compounds (transi tion-metal trichalcogenides) were included. In two discussion meEjtings, the special role of polyacetylene and possible present and future applications of the electronic properties of polymers, as e.g. conductors or as electrodes in electrochemical cells, were elucidated. The electronic properties of polymers cover a wide range of research problems which are of particular interest for polymers with a 1T-electron system. Thus, a great part of the work presented was concerned with conjuga ted systems. Additional presentations dealt with other systems such as bio polymers, photopolymers or electrets, which are of significant scientific and technical importance. It was demonstrated how their electronic proper ties are increasingly being investigated from a fundamental point of view by applying known concepts of snlid-state science.




The Porphyrin Handbook


Book Description

The Porphyrin Handbook, Volume 16: Phthalocyanines: Spectroscopic and Electrochemical Characterization provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the photophysical properties of phthalocyanines that are important in relation to photosensitizers in photodynamic therapy, photoconductor, solar cells, and artificial photosynthesis. This text then describe how the data obtained from magnetic circular dichroism spectroscopy has provided the critical information required to describe the excited and ground state degeneracies of main group metallophthalocyanines complexes. Other chapters consider the electrocatalysis by electrodes modified with phthalocyanine sensors and complexes. This book discusses as well the properties of phthalocyanines and of their complexes. The final chapter deals with the experiments with organic pigment thin films. This book is a valuable resource for research scientists, engineers, and clinicians.







Functional Dyes


Book Description

In the last 10 years organic dyes, traditionally used for coloring textiles and other materials, have become increasingly important in the hi-tech industries of electronics and optoelectronics. They can be used in optical data storage, new solar cells and biomedical sensors.Functional Dyes discusses the synthesis of these new, high-value dyes and pigments as well as their applications and performance. The chapters are arranged so that the reader logically advances from the fundamental concepts to more practical aspects of the technology in which they are used.In providing the reader with current information on functional dye chemistry, as well as important developments within the field, Functional Dyes is a valuable information source for dye and material chemists, researchers and graduates, who want a summary of the key advances in the field over the last 10 years and an authoritative view on future developments.* Provides a broad introduction to the science technology of the functional dye application* Reviews recent advances on synthesis and characteristics of the functional dyes and their applications* Is a valuable information source for dye and material chemists and researchers




Handbook of Porphyrin Science: with Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine (volume 5)


Book Description

This is the first set of Handbook of Porphyrin Science.Porphyrins, phthalocyanines and their numerous analogues and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives demonstrated new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as platforms for study of theoretical principles and applications in a wide variety of fields, the Handbook of Porphyrin Science represents a timely ongoing series dealing in detail with the synthesis, chemistry, physicochemical and medical properties and applications of polypyrrole macrocycles. Professors Karl Kadish, Kevin Smith and Roger Guilard are internationally recognized experts in the research field of porphyrins, each having his own separate area of expertise in the field. Between them, they have published over 1500 peer-reviewed papers and edited more than three dozen books on diverse topics of porphyrins and phthalocyanines. In assembling the new volumes of this unique Handbook, they have selected and attracted the very best scientists in each sub-discipline as contributing authors of the chaptersThis Handbook will prove to be a modern authoritative treatise on the subject as it is a collection of up-to-date works by world-renowned experts in the field. Complete with hundreds of figures, tables and structural formulas, and thousands of literature citations, all researchers and graduate students in this field will find the Handbook of Porphyrin Science an essential, major reference source for many years to come.