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Nickel Catalysis in Organic Synthesis

Author : Sensuke Ogoshi

Publisher : John Wiley & Sons

Page : 348 pages

File Size : 32,75 MB

Release : 2020-03-09

Category : Science

ISBN : 3527344071

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Book Description

A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more. Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide: -Reviews the numerous applications of nickel catalysis in synthesis -Explores the use of nickel as a relatively cheap and earth-abundant metal -Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations -Offers a resource for academics and industry professionals Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis.



The Organic Chemistry of Nickel

Author : P.W. Jolly

Publisher : Elsevier

Page : 533 pages

File Size : 48,1 MB

Release : 2012-12-02

Category : Science

ISBN : 0323146902

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Book Description

The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.



Organic Synthesis with Palladium Compounds

Author : Jiro Tsuji

Publisher : Springer Science & Business Media

Page : 221 pages

File Size : 24,86 MB

Release : 2012-12-06

Category : Science

ISBN : 3642674755

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Book Description

Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-



The Organic Chemistry of Nickel

Author : P.W. Jolly

Publisher : Elsevier

Page : 417 pages

File Size : 30,66 MB

Release : 2012-12-02

Category : Science

ISBN : 0323151302

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Book Description

The Organic Chemistry of Nickel, Volume II: Organic Synthesis describes the chemistry of the organonickel complexes and the use of nickel in organic synthesis. Composed of six chapters, this volume starts with discussions on the oligomerization, co-oligomerization, and polymerization of olefins, followed by short accounts of the mechanistically related isomerization and hydrogenation of olefins, as well as the hydrosilylation and hydrocyanation reactions. Chapter II examines the oligomerization of acetylene and substituted alkynes, the co-oligomerization of alkynes with olefins, the related oligomerization of allene, including a number of telomerization reactions involving alkynes or allenes. Chapters III and IV describe the oligomerization, co-oligomerization, and polymerization of butadiene and substituted 1,3-dienes. Chapter V explores the coupling of organic halides in the presence of stoichiometric amounts of zerovalent nickel complexes, and the nickel-catalyzed cross-coupling reaction between organic halides and Grignard reagents. Lastly, Chapter VI emphasizes the carbonylation of alkynes, olefins, and organic halides using nickel complexes. This book will be of great value to organic chemists and researchers who are interested in the application of nickel complexes to organic synthesis.





Application of Transition Metal Catalysts in Organic Synthesis

Author : L. Brandsma

Publisher : Springer Science & Business Media

Page : 349 pages

File Size : 42,27 MB

Release : 2012-12-06

Category : Science

ISBN : 3642603289

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Book Description

Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.



Modern Organonickel Chemistry

Author : Yoshinao Tamaru

Publisher : John Wiley & Sons

Page : 346 pages

File Size : 33,99 MB

Release : 2006-03-06

Category : Science

ISBN : 3527604235

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Book Description

Organonickel chemistry plays an increasingly important role in organic chemistry, and interest in this topic is now just as keen as in organopalladium chemistry. While there are numerous, very successful books on the latter, a book specializing in organonickel chemistry is long overdue. Edited by one of the leading experts in the field, this volume covers the many discoveries made over the past 30 years, and previously scattered throughout the literature. Active researchers working at the forefront of organonickel chemistry provide a comprehensive review of the topic, including cross-coupling reactions, asymmetric synthesis and heterogeneous catalysis reaction types. A must-have for both organometallic chemists and synthetic organic chemists.







Domino Reactions in Organic Synthesis

Author : Lutz F. Tietze

Publisher : John Wiley & Sons

Page : 631 pages

File Size : 14,18 MB

Release : 2006-12-13

Category : Science

ISBN : 3527608680

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Book Description

Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates- a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type - an approach for an efficiant, economically benificial and ecological benign synthesis. A definite must for every organic chemist.