Thermochemical Data for Reactor Materials and Fission Products


Book Description

This volume presents a collection of critically assessed data on inorganic compounds which are of special interest in nuclear reactor safety studies. Thermodynamic equilibrium calculations are an important and widely used instrument in the understanding of the chemical behaviour and release of fission products in the course of nuclear reactor accidents. The reliability of such calculations is, nevertheless, limited by the availability of accurate input data for relevant compounds. The present work examines a wide variety of elements and compounds (oxides, hydroxides, actinides, iodides, tellurides, alloys, and ternary oxides) relevant to light water and fast nuclear reactors, in their condensed and gaseous state, many of which have been evaluated here for the first time. Recommended values, obtained from a critical evaluation of the literature, are given in an extensive explanatory text, and compiled in thermochemical tables from 298 to 3000 K. Special attention is also given to the crystallographic properties of the condensed phases.




Comprehensive Nuclear Materials


Book Description

Materials in a nuclear environment are exposed to extreme conditions of radiation, temperature and/or corrosion, and in many cases the combination of these makes the material behavior very different from conventional materials. This is evident for the four major technological challenges the nuclear technology domain is facing currently: (i) long-term operation of existing Generation II nuclear power plants, (ii) the design of the next generation reactors (Generation IV), (iii) the construction of the ITER fusion reactor in Cadarache (France), (iv) and the intermediate and final disposal of nuclear waste. In order to address these challenges, engineers and designers need to know the properties of a wide variety of materials under these conditions and to understand the underlying processes affecting changes in their behavior, in order to assess their performance and to determine the limits of operation. Comprehensive Nuclear Materials, Second Edition, Seven Volume Set provides broad ranging, validated summaries of all the major topics in the field of nuclear material research for fission as well as fusion reactor systems. Attention is given to the fundamental scientific aspects of nuclear materials: fuel and structural materials for fission reactors, waste materials, and materials for fusion reactors. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource of information. Most of the chapters from the first Edition have been revised and updated and a significant number of new topics are covered in completely new material. During the ten years between the two editions, the challenge for applications of nuclear materials has been significantly impacted by world events, public awareness, and technological innovation. Materials play a key role as enablers of new technologies, and we trust that this new edition of Comprehensive Nuclear Materials has captured the key recent developments. Critically reviews the major classes and functions of materials, supporting the selection, assessment, validation and engineering of materials in extreme nuclear environments Comprehensive resource for up-to-date and authoritative information which is not always available elsewhere, even in journals Provides an in-depth treatment of materials modeling and simulation, with a specific focus on nuclear issues Serves as an excellent entry point for students and researchers new to the field




The Phebus Fission Product Project


Book Description

Proceedings of the Seminar of the Phebus-FP [Fission Product] Project, held at the Chateau Cadarache, St Paul-Lez-Durance, France, 5-7 June 1991.




Thermodynamic Modeling and Materials Data Engineering


Book Description

J.-P. CALISTE, A. TRUYOL AND J. WESTBROOK The Series, "Data and Knowledge in a Changing World", exemplifies CODATA's primary purpose of collecting, from widely different fields, a wealth of information on efficient exploitation of data for progress in science and technology and making that information available to scientists and engineers. A separate and complementary CODATA Reference Series will present Directories of compiled and evaluated data and Glossaries of data-related terms. The present book "Thermodynamic Modeling and Materials Data Engineering" discusses thermodynamic, structural, systemic and heuristic approaches to the modeling of complex materials behavior in condensed phases, both fluids and solids, in order to evaluate their potential applications. Itwas inspired by the Symposium on "Materials and Structural Properties" held during the 14th International CODATA Conference in Chambery, France. The quality of the contributions to this Symposium motivated us to present" a coherent book of interest to the field. Updated contributions inspired by Symposium discussions and selections from other CODATA workshops concerning material properties data and Computer Aided Design combine to highlight the complexity of material data issues on experimental, theoretical and simulation levels Articles were selected for their pertinence in three areas. Complex data leading to interesting developments and tools such as: • new developments in state equations and their applications, • prediction and validation of physical and energy data by group correlations for pure compounds, • modeling and prediction of mixture properties.




Fission Product Processes In Reactor Accidents


Book Description

The Three Mile Island and Chernobyl nuclear incidents emphasized the need for the world-wide nuclear community to cooperate further and exchange the results of research in this field in the most open and effective manner. Recognizing the roles of heat and mass transfer in all aspects of fission-product behavior in sever reactor accidents, the Executive Committee of the International Centre for Heat and Mass Transfer organized a Seminar on Fission Product Transport Processes in Reactor Accidents. This book contains the eleven of the lectures and all the papers presented at the seminar along with four invited papers that were not presented and a summary of the closing session.




CRC Handbook of Chemistry and Physics, 96th Edition


Book Description

Proudly serving the scientific community for over a century, this 96th edition of the CRC Handbook of Chemistry and Physics is an update of a classic reference, mirroring the growth and direction of science. This venerable work continues to be the most accessed and respected scientific reference in the world. An authoritative resource consisting of tables of data and current international recommendations on nomenclature, symbols, and units, its usefulness spans not only the physical sciences but also related areas of biology, geology, and environmental science. The 96th edition of the Handbook includes 18 new or updated tables along with other updates and expansions. A new series highlighting the achievements of some of the major historical figures in chemistry and physics was initiated with the 94th edition. This series is continued with this edition, which is focused on Lord Kelvin, Michael Faraday, John Dalton, and Robert Boyle. This series, which provides biographical information, a list of major achievements, and notable quotations attributed to each of the renowned chemists and physicists, will be continued in succeeding editions. Each edition will feature two chemists and two physicists. The 96th edition now includes a complimentary eBook with purchase of the print version. This reference puts physical property data and mathematical formulas used in labs and classrooms every day within easy reach. New Tables: Section 1: Basic Constants, Units, and Conversion Factors Descriptive Terms for Solubility Section 8: Analytical Chemistry Stationary Phases for Porous Layer Open Tubular Columns Coolants for Cryotrapping Instability of HPLC Solvents Chlorine-Bromine Combination Isotope Intensities Section 16: Health and Safety Information Materials Compatible with and Resistant to 72 Percent Perchloric Acid Relative Dose Ranges from Ionizing Radiation Updated and Expanded Tables Section 6: Fluid Properties Sublimation Pressure of Solids Vapor Pressure of Fluids at Temperatures Below 300 K Section 7: Biochemistry Structure and Functions of Some Common Drugs Section 9: Molecular Structure and Spectroscopy Bond Dissociation Energies Section 11: Nuclear and Particle Physics Summary Tables of Particle Properties Table of the Isotopes Section 14: Geophysics, Astronomy, and Acoustics Major World Earthquakes Atmospheric Concentration of Carbon Dioxide, 1958-2014 Global Temperature Trend, 1880-2014 Section 15: Practical Laboratory Data Dependence of Boiling Point on Pressure Section 16: Health and Safety Information Threshold Limits for Airborne Contaminants




High Temperature Thermodynamic Studies on the Transuranium Oxides and Their Solid Solutions


Book Description

A growing demand for energy supply worldwide, coupled with the necessity to reduce emission of greenhouse gases, has led to a renewed interest in nuclear energy as an alternative to fossil fuels for electricity production in the last years. One of the ma







Material Behavior and Physical Chemistry in Liquid Metal Systems


Book Description

The international seminar "Material Behavior and Physical Chemistry in Liquid Metal Systems" was organized by the Institute of Materials and Solid State Research of the Karlsruhe Nuclear Research Center (Karlsruhe, Federal Republic of Germany). The seminar was held at the Nuclear Engineering School of the center on March 24-26, 1981. The aim of the seminar was to give metallurgists, chemists,. and physicists working in different areas of the science and technology of liquid metals an opportunity to discuss the basic work and the need for further work in this field. Since the seminar was held near one of the laboratories which for the last few years has been engaged in liquid alkali metal studies, partic ipants also had an opportunity to observe modern equipment for liquid alkali metal research. Interest in the application of liquid metals as working fluids in energy production, conversion, and storage is increasing. The technology has already demonstrated its high standards, which make possible the operation of large sodium-cooled fast reactors. Past conferences have shown, however, that there is still a lack of basic knowledge and understanding. Therefore, the aim of the present seminar was to discuss basic work in detail, and most of the papers contributed to this objective.




The SGTE Casebook


Book Description

The Scientific Group Thermodata Europe (SGTE) is a consortium involved in the development and application of thermodynamic databanks for materials such as metals. Building on SGTE research, the second edition of this standard reference presents thermodynamic calculations as the basic tools in developing and optimizing various materials and processes. The SGTE Casebook: Thermodynamics at Work, Second Edition shows how this data can optimize the production and quality of steel and other alloys. The book explores phases stable at equilibrium as well as their amounts and compositions, and provides information about the degree of instability of the phases not present at equilibrium