Thermodynamic Weirdness


Book Description

An account of the concepts and intellectual structure of classical thermodynamics that reveals the subject's simplicity and coherence. Students of physics, chemistry, and engineering are taught classical thermodynamics through its methods—a “problems first” approach that neglects the subject's concepts and intellectual structure. In Thermodynamic Weirdness, Don Lemons fills this gap, offering a nonmathematical account of the ideas of classical thermodynamics in all its non-Newtonian “weirdness.” By emphasizing the ideas and their relationship to one another, Lemons reveals the simplicity and coherence of classical thermodynamics. Lemons presents concepts in an order that is both chronological and logical, mapping the rise and fall of ideas in such a way that the ideas that were abandoned illuminate the ideas that took their place. Selections from primary sources, including writings by Daniel Fahrenheit, Antoine Lavoisier, James Joule, and others, appear at the end of most chapters. Lemons covers the invention of temperature; heat as a form of motion or as a material fluid; Carnot's analysis of heat engines; William Thomson (later Lord Kelvin) and his two definitions of absolute temperature; and energy as the mechanical equivalent of heat. He explains early versions of the first and second laws of thermodynamics; entropy and the law of entropy non-decrease; the differing views of Lord Kelvin and Rudolf Clausius on the fate of the universe; the zeroth and third laws of thermodynamics; and Einstein's assessment of classical thermodynamics as “the only physical theory of universal content which I am convinced will never be overthrown.”







Thermodynamic Foundations of the Earth System


Book Description

An accessible book for graduate students and researchers that describes how the laws of thermodynamics apply to Earth system processes.




Thermodynamic Models for Industrial Applications


Book Description

Using an applications perspective Thermodynamic Models for Industrial Applications provides a unified framework for the development of various thermodynamic models, ranging from the classical models to some of the most advanced ones. Among these are the Cubic Plus Association Equation of State (CPA EoS) and the Perturbed Chain Statistical Association Fluid Theory (PC-SAFT). These two advanced models are already in widespread use in industry and academia, especially within the oil and gas, chemical and polymer industries. Presenting both classical models such as the Cubic Equations of State and more advanced models such as the CPA, this book provides the critical starting point for choosing the most appropriate calculation method for accurate process simulations. Written by two of the developers of these models, Thermodynamic Models for Industrial Applications emphasizes model selection and model development and includes a useful “which model for which application” guide. It also covers industrial requirements as well as discusses the challenges of thermodynamics in the 21st Century.










Thermodynamic Optimization of Complex Energy Systems


Book Description

A comprehensive assessment of the methodologies of thermodynamic optimization, exergy analysis and thermoeconomics, and their application to the design of efficient and environmentally sound energy systems. The chapters are organized in a sequence that begins with pure thermodynamics and progresses towards the blending of thermodynamics with other disciplines, such as heat transfer and cost accounting. Three methods of analysis stand out: entropy generation minimization, exergy (or availability) analysis, and thermoeconomics. The book reviews current directions in a field that is both extremely important and intellectually alive. Additionally, new directions for research on thermodynamics and optimization are revealed.




International Thermodynamic Tables of the Fluid State, Argon, 1971


Book Description

Thermodynamics and Thermochemistry: Thermodynamic Tables Project is a result of a chemistry conference in 1963. The text contains various studies, lessons, and experimental data that are relevant to the field. The book is divided into two chapters; the first one includes lessons about the constituent tables, encompassing the physical constants and fixed points, vapor pressure equations, PVT surface equations, and derived properties. For each of these topics, the corresponding formula is explained. Chapter 2 highlights the IUPAC (International Union of Pure and Applied Chemistry) tables and explores the table's physical constants and PVT equations, together with its relevant subtopics. The last part of the book illustrates different tables that are closely associated with the constituent and IUPAC tables. The text caters to people who are interested in studying this field of chemistry, including undergraduates and postgraduates.




Time's Arrow


Book Description

Exploration of Second Law of Thermodynamics details fundamental dynamic properties behind construction of statistical mechanics. Topics include maximal entropy principles; invertible and noninvertible systems; ergodicity and unique equilibria; and asymptotic periodicity and entropy evolution. Geared toward physicists and applied mathematicians; suitable for advanced undergraduate and graduate courses. 1992 edition.