Thermophysical Properties of Heavy Petroleum Fluids


Book Description

This book addresses conventional and new predictive methodologies for estimating thermophysical properties of heavy petroleum fluids. For the unidentifiable fractions forming the fluids, chemical structures are calculated so that property estimation methods for mixtures of identifiable components are now available for such fractions. Chemical and multiphase equilibriums are of utmost importance; hence, the most significant ones involving heavy petroleum fluids are determined and illustrated using advanced equations of state such as sPC-SAFT and EoS/GE. The included phase equilibriums are phase envelopes of reservoir fluids, asymmetric mixtures between light solvents and bitumen including the presence of water and asphaltenes, among others. Besides, heavy petroleum fluids are analyzed from the Newtonian and non-Newtonian viewpoints, exploring their complex rheological behavior. Finally, complemented by online an Excel program for the thermodynamic characterization of unidentifiable petroleum fractions, this book is a useful resource for engineers and researchers in the petroleum industry and is also of interest to students studying chemical and petroleum engineering.




Characterization and Properties of Petroleum Fractions


Book Description

The last three chapters of this book deal with application of methods presented in previous chapters to estimate various thermodynamic, physical, and transport properties of petroleum fractions. In this chapter, various methods for prediction of physical and thermodynamic properties of pure hydrocarbons and their mixtures, petroleum fractions, crude oils, natural gases, and reservoir fluids are presented. As it was discussed in Chapters 5 and 6, properties of gases may be estimated more accurately than properties of liquids. Theoretical methods of Chapters 5 and 6 for estimation of thermophysical properties generally can be applied to both liquids and gases; however, more accurate properties can be predicted through empirical correlations particularly developed for liquids. When these correlations are developed with some theoretical basis, they are more accurate and have wider range of applications. In this chapter some of these semitheoretical correlations are presented. Methods presented in Chapters 5 and 6 can be used to estimate properties such as density, enthalpy, heat capacity, heat of vaporization, and vapor pressure. Characterization methods of Chapters 2-4 are used to determine the input parameters needed for various predictive methods. One important part of this chapter is prediction of vapor pressure that is needed for vapor-liquid equilibrium calculations of Chapter 9.




Spills of Diluted Bitumen from Pipelines


Book Description

Diluted bitumen has been transported by pipeline in the United States for more than 40 years, with the amount increasing recently as a result of improved extraction technologies and resulting increases in production and exportation of Canadian diluted bitumen. The increased importation of Canadian diluted bitumen to the United States has strained the existing pipeline capacity and contributed to the expansion of pipeline mileage over the past 5 years. Although rising North American crude oil production has resulted in greater transport of crude oil by rail or tanker, oil pipelines continue to deliver the vast majority of crude oil supplies to U.S. refineries. Spills of Diluted Bitumen from Pipelines examines the current state of knowledge and identifies the relevant properties and characteristics of the transport, fate, and effects of diluted bitumen and commonly transported crude oils when spilled in the environment. This report assesses whether the differences between properties of diluted bitumen and those of other commonly transported crude oils warrant modifications to the regulations governing spill response plans and cleanup. Given the nature of pipeline operations, response planning, and the oil industry, the recommendations outlined in this study are broadly applicable to other modes of transportation as well.




Petroleum Migration


Book Description

Petroleum Migration follows petroleum from its generation in source rocks through migration to the reservoir or the surface. The book is divided into 4 parts. Part 1 deals with both the generation of petroleum by the thermal breakdown of kerogen and the expulsion of the petroleum from the source rock. Part 2 considers secondary migration: the procesess which control petroleum behaviour during its movement through relatively permeable carrier beds from the mudrock sequences, which contain source intervals, to the reservoir in the structural culmination of the carrier bed or other trap. Part 3 contains case studies which show how understanding of generation, expulsion and secondary migration can be used to explain the distribution of oil and gas in a basin and therefore, to predict the nature of the petoleum in an undrilled prospect. Part 4 examines leakage from accumulations.




Process Equipment and Plant Design


Book Description

Process Equipment and Plant Design: Principles and Practices takes a holistic approach towards process design in the chemical engineering industry, dealing with the design of individual process equipment and its configuration as a complete functional system. Chapters cover typical heat and mass transfer systems and equipment included in a chemical engineering curriculum, such as heat exchangers, heat exchanger networks, evaporators, distillation, absorption, adsorption, reactors and more. The authors expand on additional topics such as industrial cooling systems, extraction, and topics on process utilities, piping and hydraulics, including instrumentation and safety basics that supplement the equipment design procedure and help to arrive at a complete plant design. The chapters are arranged in sections pertaining to heat and mass transfer processes, reacting systems, plant hydraulics and process vessels, plant auxiliaries, and engineered safety as well as a separate chapter showcasing examples of process design in complete plants. This comprehensive reference bridges the gap between industry and academia, while exploring best practices in design, including relevant theories in process design making this a valuable primer for fresh graduates and professionals working on design projects in the industry. - Serves as a consolidated resource for process and plant design, including process utilities and engineered safety - Bridges the gap between industry and academia by including practices in design and summarizing relevant theories - Presents design solutions as a complete functional system and not merely the design of major equipment - Provides design procedures as pseudo-code/flow-chart, along with practical considerations




Petroleum Refining Design and Applications Handbook, Volume 1


Book Description

There is a renaissance that is occurring in chemical and process engineering, and it is crucial for today's scientists, engineers, technicians, and operators to stay current. With so many changes over the last few decades in equipment and processes, petroleum refining is almost a living document, constantly needing updating. With no new refineries being built, companies are spending their capital re-tooling and adding on to existing plants. Refineries are like small cities, today, as they grow bigger and bigger and more and more complex. A huge percentage of a refinery can be changed, literally, from year to year, to account for the type of crude being refined or to integrate new equipment or processes. This book is the most up-to-date and comprehensive coverage of the most significant and recent changes to petroleum refining, presenting the state-of-the-art to the engineer, scientist, or student. Useful as a textbook, this is also an excellent, handy go-to reference for the veteran engineer, a volume no chemical or process engineering library should be without. Written by one of the world's foremost authorities, this book sets the standard for the industry and is an integral part of the petroleum refining renaissance. It is truly a must-have for any practicing engineer or student in this area.




Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs


Book Description

Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs delivers information on the role of PVT (pressure-volume-temperature) tests/data in various aspects, in particular reserve estimation, reservoir modeling, flow assurance, and enhanced oil recovery for both conventional and unconventional reservoirs. This must-have reference also prepares engineers on the importance of PVT tests, how to evaluate the data, develop an effective management plan for flow assurance, and gain perspective of flow characterization, with a particular focus on shale oil, shale gas, gas hydrates, and tight oil making. This book is a critical resource for today's reservoir engineer, helping them effectively manage and maximize a company's oil and gas reservoir assets. - Provides tactics on reservoir phase behavior and dynamics with new information on shale oil and gas hydrates - Helps readers Improve on the effect of salt concentration and application to C02-Acid Gas Disposal with content on water-hydrocarbon systems - Provides practical experience with PVT and tuning of EOS with additional online excel spreadsheet examples







Thermophysical Properties of Individual Hydrocarbons of Petroleum and Natural Gases


Book Description

Thermophysical Properties of Individual Hydrocarbons of Petroleum and Natural Gases: Properties, Methods, and Low-Carbon Technologies is a go-to data source for engineers who need derive property data on everyday components. Providing more precise data improves existing oil and gas processing systems and creates opportunities for more sustainable operations and equipment, such as hydrogen and carbon capture. Covering modern equations of state, this source discusses detailed descriptions of experimental apparatus, methods of measurement, corrections and error estimates as well as results of previous experiments. Generalized predictive methods for calculating viscosity and thermal conductivity are also covered. Rounding out with property databases and lower-carbon technology advances, the book gives today's engineers a detailed study of methods for more sustainable experimental research of thermophysical properties. - Teaches approaches for the measurement and modeling of thermophysical properties for future sustainability growth, including hydrogen and carbon capture - Provides exact property data of natural gas and their main components, including saturated properties - Gives readers new knowledge in experimental measurement procedures and guidelines for calculating thermophysical properties, along with updates on applications