Valence Instabilities and Related Narrow-Band Phenomena


Book Description

Those well-intending workers, especially theorists, who have viewed hungrily the mixed valence problem, but have not yet made the bold leap, might be comforted to learn that the Rochester conference left the virginal state of that problem essentially intact. That is not to say that the event was prosaic. Indeed, the conferees exhibited a level of effervescence appropriate to the freshness and challenge of the problem at hand. If the meeting failed to solve major questions, it at least established several guidelines. One is that future experimental efforts, at least on a short time scale, might be spent most profitably on those substances which exhibit consistent, and hence probably intrinsic, behavior from laboratory to laboratory. A recurring message, not always subtle, to the·theorists was that piecemeal approaches to the mixed valence problem, characteristic of much of the work to date, are of limited usefulness. For at the core of the problem one has a melange of boot-strapping interac tions which must be sorted out and dealt with properly. Para phrasing Phil Anderson (see Epilogue), the mixed valence problem is in the same category of problems which are failing to be done in field theory these days.




Valence Instabilities


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Experimental Studies of Valence Instabilities


Book Description

The research accomplished is summarized in abstracts of five Ph. D theses which were completed during the period: (1)'Experimental Studies of the Ce(1-x)Th(x) Valence Instability, ' (2) 'Experimental Studies of Two Kondo Lattice Systems: CeAl(2) and Ce(1-x)Th(x)' (3) 'Calorimetric Studies of a Cerium Alloy and a Cerium Intermetallic: Ce(1-x)Th(x) and CeAl(2), ' (4) 'Transport Studies of Cooperative Phenomena in Rare Earth Based Systems, ' and (5) 'The Valence Instability in Cerium-Based Alloy Systems.' (Author).










Valence Instabilities as a Source of Actinide System Inconsistencies


Book Description

Light actinide elements alone, and in some of their alloys, may exist as a static or dynamic mixture of two configurations. Such a state can explain both a resistivity maximum and lack of magnetic order observed in so many actinide materials, and still be compatible with the existence of f-electrons in narrow bands. Impurity elements may stabilize slightly different intermediate valence states in U, Np, and Pu, thus contributing to inconsistencies in published results. The physical property behavior of mixed-valence, rare-earth compounds is very much like that observed in development of antiphase (martensitic) structures. Martensitic transformations in U, Np, and Pu, from high-temperature b. c. c. to alpha phase, may be a way of ordering an alloy-like metal of mixed or intermediate valence. The relative stability of each phase structure may depend upon its electron-valence ratio. A Hubbard model for electron correlations in a narrow energy band has been invoked in most recent theories for explaining light actinide behavior. Such a model may also be applicable to crystal symmetry changes in martensitic transformations in actinides.