Problems in Metallurgical Thermodynamics and Kinetics


Book Description

Problems in Metallurgical Thermodynamics and Kinetics provides an illustration of the calculations encountered in the study of metallurgical thermodynamics and kinetics, focusing on theoretical concepts and practical applications. The chapters of this book provide comprehensive account of the theories, including basic and applied numerical examples with solutions. Unsolved numerical examples drawn from a wide range of metallurgical processes are also provided at the end of each chapter. The topics discussed include the three laws of thermodynamics; Clausius-Clapeyron equation; fugacity, activity, and equilibrium constant; thermodynamics of electrochemical cells; and kinetics. This book is beneficial to undergraduate and postgraduate students in universities, polytechnics, and technical colleges.













Thermodynamic Measurement Techniques


Book Description

This book offers various techniques for measurement of thermodynamic quantities of materials such as enthalpy, free energy, and entropy. Techniques described herein include calorimetry, chemical equilibria, vapour pressure, and electrochemical analysis. The book covers general and solution thermodynamics in Chapters 1 and 2, respectively, and highlights the significance of various thermodynamic quantities required for materials characterization and development in Chapter 3. The author goes on to discuss different thermodynamic measurement techniques in detail (Chapters 4-8) together with a set of more than fifty worked-out problems related to classical as well as solution thermodynamics and measurement techniques. (Chapter 9). Topics include but are not limited to the following: The significance of various thermodynamic data required for selection and characterization of materials. The physicochemical principles involved in various thermodynamic measurement and on the evaluation of thermodynamic data by phase diagram analyses. The unique combination of calorimetry and chemical equilibrium for simultaneous determination of partial molar enthalpy and partial molar free energy of hydrogen in metals and alloys. The special technique based on the combination of vapor pressure and electrical conductivity to study the effect of tellurium vapor pressure on the mode of conduction in polycrystalline cadmium telluride.










The Metrics of Material and Metal Ecology


Book Description

This book is a must for individuals and companies that have an interest in developing sustainable technology and systems in the complex 'Web of Metals' on a first principles, technological and economic basis, with a focus to the minerals, metals and product manufacturing industries. In this inter-, intra- and trans-disciplinary book the material/metal cycle will be central, addressing technology as the basis for achieving sustainability within the system of primary mineral and metal producing, and the consumer product material cycles, linked to nature's cycles. The following major topics (not exclusive) are discussed in a detail, which will satisfy company CEO's and students of environment, engineering, economics, and law alike: (i) industrial ecology, (ii) system engineering concepts, (iii) development of future breakthrough technology as well optimization of present technology, (iv) process fundamentals (e.g. thermodynamics, separation physics, transport processes etc.), (v) product manufacture and design (for recycling), (vi) environmental legislation and (vii) technology as a basis for achieving sustainability within our present society.The book discusses contentious issues such as the limits of recycling determined by physics, chemistry, economics and process technology, therefore providing the reader with a fundamental basis to understand and critically discuss the validity of environmental legislation. Furthermore, the 'Web of Metals' (i.e. the dynamic interconnection of metal and material cycles and product systems) will reveal that, if the application of environmental evaluation techniques such as material flow analysis, life cycle assessment etc. are not carried out on a sufficient theoretical basis, technological and economic understanding, analyses could lead to erroneous and in the end environmentally harmful conclusions.The book is illustrated with many industrial examples embracing car and electronic consumer goods manufacturing and recycling, and the production and recycling of all major metals (e.g. steel, aluminium, copper, zinc, lead, magnesium, PGM's and PM's) and to an extent plastics. A complete section of the book is devoted to the recycling of light metals. Numerous colour figures and photos, plant and reactor data as well as software and computer models (running under Matlab's SimulinkĀ® and AMPLĀ® as well as tools based on neural net technology (CSenseTM) are provided to give the reader the opportunity to investigate the various topics addressed in this book at various levels of depth and theoretical sophistication, providing a wealth of information, share-data and industrial know-how.Finally, the book philosophically discusses how to harmonize the resource, life and technological cycles depicted by the figure on the cover to make a contribution to the sustainable use of resources and products.* Material and Metal Ecology and the various modelling aspects to quantify this * System modelling of recycling systems with applications in the automotive and consumergoods sector* Metallurgical metal recycling with applications in aluminium, supplemented with various modelling examples from thermodynamics, exergy, neural nets to CFD