A Study of Metal-Semiconductor Contacts on Indium Phosphide


Book Description

This report describes the research accomplished during the last twelve months of a 20-month program of research on metal contacts to the semiconductor indium phosphide (InP). The Schottky barrier energy phi sub B and the contact resistance r(c) were measured for several metal-InP structures and the electrical properties were correlated to the metallurgical properties obtained with Auger electron spectroscopy (AES). Separate measurement of phi sub B on both n-type and p-type InP was carried out using Al as the metal Electrode. Control samples of Al/GaAs and Al/Si diodes were fabricated simultaneously in order to evaluate fabrication procedures. The Al/InP diodes were rectifying and phi sub B(n) less than phi sub B(p), in agreement with our earlier work on Pd/InP diodes. Ohmic contacts to p-type InP were also investigated. The results of a study of a multilayered metal film consisting of Au and Be alloyed to the InP surface, are given. In was found that the Au/Be/p-InP structure when properly heat treated would produce ohmic behavior with r(c) = 0.001 ohm sq cm at a net doping of about 1.0 x 10 to the 17th power per cu cm and r(c) = 0.0002 ohm sq cm at 1.4 x 10 to the 18th power per cu cm. The Au/Be contact was relatively easy to apply but tight control over the Au/Be thickness ratio and heat-treatment cycle was found to be necessary. (Author).




A Study of Metal Semiconductor Contacts on Indium Phosphide


Book Description

This report describes the research accomplished during a 14-month program of research on metal-semiconductor contacts on indium phosphide. Emphasis was placed on fabrication and characterization of ohmic contacts to p- and n-type InP using the deposition of thin metallic layers and subsequent heat treatment at elevated temperatures. Extensive use of Auger electron spectroscopy (AES) was made in order to obtain depth-composition profiles of the thin-film structures. For contact to n-type InP, three thin-film systems were investigated: Au, Ni, and a composite layer of Ni/Au/Ge. The specific contact resistance (r sub c) of the Ni/Au/Ge/In system varied in a systematic manner with heat-treatment temperature, and a minimum value of r sub c of .00003 ohm-sq cm at 325 C was found for N(D) = 3 x 10 to the 16th power/cc. Several nickel germanide phases, detected by AES and X-ray diffraction, were formed during heat treatment and were found to affect r sub c. For contact to p-type InP, a film consisting of Au/Mg was investigated. For heat treatment of the Au/Mg/InP system above 350 C, r sub c decreased with increasing signs of alloying at higher temperatures. The smoothest surface was obtained at 446 C for 50 minutes with r sub c approx. 0.0001 ohm/sq cm for N(A) = 6 x 10 to the 17th power/cc.







Studies of Schottky Contacts on Indium Phosphide


Book Description

Metal-semiconductor contacts are one of the most widely used rectifying contacts in semiconductor industry. Therefore, the fabrication of high quality Schottky contacts is essential to improve the performance of the device. InP is a material of particular interest for optoelectronic and high-speed electronic devices. In view of the important applications, the fabrication of Schottky contacts to InP is of vital importance. The contacts formed should have electrical and thermal stability with desired surface morphology. During the technological stages leading to the final device, InP substrates unavoidably undergo many thermal treatments involving rapid thermal annealing. This book includes the fabrication and characterization of Schottky contacts to InP formed with high temperature stable metals like ruthenium and molybdenum. The Schottky structures formed on InP are rapid thermal annealed and its effect on the electrical, structural properties and deep level defects are investigated. The results presnted in the book will be useful for those working in the field of semiconductor Schottky contact fabrication.













Metal Contacts on Semiconductors


Book Description

Since the last report a number of experiments have been carried out on metal-semiconductor interfaces and semiconductor heterostructures. The range of experimental techniques applied included low energy electron diffraction (LEED), X-ray photoemission spectroscopy (XPS), Raman scattering, and transport measurement, i.e. current-voltage (I-V) and capacitance-voltage (C-V) measurements. The system investigated most thoroughly within this project is Sb on InP(110). As mentioned in an earlier report this Sb/InP interface exhibits properties which makes it an ideal system to study the formation of Schottky barriers and also test the different theoretical models for this formation. The Raman and transport measurements were performed on both Sb/n-InP and Sb/p-InP. This work has been accepted for publication and preprints are included. Indium phosphides, Antimony. (MJM).




Indium Phosphide and Related Materials


Book Description

Presents an integrated survey of the most recent research, engineering development and commercial application of indium phosphide and related materials. The book is tutorial in nature, rich in application-engineering detail and emphasizes the designing and implementing of practical devices.