Gas-Solid Reactions


Book Description

Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it's based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.







The Reduction of Iron Ores


Book Description

For the English edition the book was revised by the authors, taking into account a number of suggestions of the readers of the German edition. Some of the most important publications in the field of iron ore reduction, which appeared since 1967, have been used to bring the manuscript as far as possible up to date. The kind assistance of Dr. K. BOHNENKAMP of the Max-Planck-Institut fUr Eisenforschung, Dusseldorf, was much appreciated in this respect. Ohapters 2.9 and 2.10, dealing with the reduction of molten oxide slags by solid carbon and with the contribution of the water-gas reaction to iron ore reduction, have been added for the English edition. Ohapter 2.9 has been completely revised with the kind assistance of Dr. H. J. GRABKE, Stuttgart. Dipl.-Ing. J. LODDE contributed to this edition by revising the bibliography. Owing to the rapid development of the blast furnace it was necessary to revise Ohapter 5 considerably. In this field many valuable suggestions have been made by Dipl.-Ing. G. LANGE and Dipl.-Ing. P. HEINRICH. Furthermore, Ohapters3 and 4 have been thoroughly revised by Dr.-Ing. E. FORSTER and Dr.-Ing. U. SCHIERLOH. Last, but not least, we have to thank our translators for their excellent work.




SPONGE IRON PRODUCTION BY DIRECT REDUCTION OF IRON OXIDE


Book Description

This book provides a fascinating study of the very important emerging field of direct reduction in which iron ore is ‘directly reduced’ in the solid-state, using either natural gas or non-coking coal, to produce a highly metallised material, referred to as sponge iron (or direct reduced iron). This intermediate product is subsequently melted in electric arc furnaces or induction furnaces (sometimes even in basic oxygen furnaces) to produce liquid steel. Such a process combination enables steel to be produced without using coking coal, which is an expensive input in the normal blast furnace—basic oxygen furnace route of steelmaking adopted in integrated steel plants. The book offers comprehensive coverage and critical assessment of various coal-based and gas-based direct reduction processes. Besides dealing with the application of the theoretical principles involved in the thermodynamics and kinetics of direct reduction, the book also contains some worked-out examples on sponge iron production. The concluding part of this seminal book summarises the present and future scenario of direct reduction, including the use of gas generated from coal in direct reduction processes. The book is primarily intended for the undergraduate and postgraduate students of metallurgical engineering. It is also a must-read for researchers, technologists and process metallurgists engaged in the rapidly developing field of direct reduction of iron oxides, which is of critical importance for India and other developing nations that are beginning to play a major role in global steelmaking.




Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals


Book Description

This book describes and explains the methods by which three related ores and recyclables are made into high purity metals and chemicals, for materials processing. It focuses on present day processes and future developments rather than historical processes. Nickel, cobalt and platinum group metals are key elements for materials processing. They occur together in one book because they (i) map together on the periodic table (ii) occur together in many ores and (iii) are natural partners for further materials processing and materials manufacturing. They all are, for example, important catalysts – with platinum group metals being especially important for reducing car and truck emissions. Stainless steels and CoNiFe airplane engine super alloys are examples of practical usage. The product emphasises a sequential, building-block approach to the subject gained through the author's previous writings (particularly Extractive Metallurgy of Copper in four editions) and extensive experience. Due to the multiple metals involved and because each metal originates in several types of ore – e.g. tropical ores and arctic ores this necessitates a multi-contributor work drawing from multiple networks and both engineering and science. - Synthesizes detailed review of the fundamental chemistry and physics of extractive metallurgy with practical lessons from industrial consultancies at the leading international plants - Discusses Nickel, Cobalt and Platinum Group Metals for the first time in one book - Reviews extraction of multiple metals from the same tropical or arctic ore - Industrial, international and multidisciplinary focus on current standards of production supports best practice use of industrial resources




Combustion


Book Description

This book provides a rigorous treatment of the coupling of chemical reactions and fluid flow. Combustion-specific topics of chemistry and fluid mechanics are considered and tools described for the simulation of combustion processes. This edition is completely restructured. Mathematical Formulae and derivations as well as the space-consuming reaction mechanisms have been replaced from the text to appendix. A new chapter discusses the impact of combustion processes on the atmosphere, the chapter on auto-ignition is extended to combustion in Otto- and Diesel-engines, and the chapters on heterogeneous combustion and on soot formation are heavily revised.




Aquatic Redox Chemistry


Book Description

This volume provides a comprehensive overview of aquatic redox chemistry through chapters contributed by many of the leading investigators in the field.







Engineering Flow and Heat Exchange


Book Description

The third edition of Engineering Flow and Heat Exchange is the most practical textbook available on the design of heat transfer and equipment. This book is an excellent introduction to real-world applications for advanced undergraduates and an indispensable reference for professionals. The book includes comprehensive chapters on the different types and classifications of fluids, how to analyze fluids, and where a particular fluid fits into a broader picture. This book includes various a wide variety of problems and solutions – some whimsical and others directly from industrial applications. Numerous practical examples of heat transfer Different from other introductory books on fluids Clearly written, simple to understand, written for students to absorb material quickly Discusses non-Newtonian as well as Newtonian fluids Covers the entire field concisely Solutions manual with worked examples and solutions provided




An Introduction to Chemical Kinetics


Book Description

This book is a progressive presentation of kinetics of the chemical reactions. It provides complete coverage of the domain of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, Chemical Engineering, Macromolecular Chemistry and Combustion. It will help them to understand the most sophisticated knowledge of their future job area. Over 15 chapters, this book present the fundamentals of chemical kinetics, its relations with reaction mechanisms and kinetic properties. Two chapters are then devoted to experimental results and how to calculate the kinetic laws in both homogeneous and heterogeneous systems. The following two chapters describe the main approximation modes to calculate these laws. Three chapters are devoted to elementary steps with the various classes, the principles used to write them and their modeling using the theory of the activated complex in gas and condensed phases. Three chapters are devoted to the particular areas of chemical reactions, chain reactions, catalysis and the stoichiometric heterogeneous reactions. Finally the non-steady-state processes of combustion and explosion are treated in the final chapter.