Polymer Electrolyte Fuel Cells 15 (PEFC 15)
Author : H. A. Gasteiger
Publisher : The Electrochemical Society
Page : 1391 pages
File Size : 47,32 MB
Release : 2015
Category :
ISBN : 1607686821
Author : H. A. Gasteiger
Publisher : The Electrochemical Society
Page : 1391 pages
File Size : 47,32 MB
Release : 2015
Category :
ISBN : 1607686821
Author :
Publisher :
Page : 2 pages
File Size : 29,40 MB
Release : 1987
Category : Chemical engineering
ISBN :
Author : Weidong He
Publisher : Springer
Page : 87 pages
File Size : 45,48 MB
Release : 2014-09-03
Category : Science
ISBN : 3319097377
This book provides a comprehensive overview of contemporary research and emerging measurement technologies associated with gas transport in solid oxide fuel cells. Within these pages, an introduction to the concept of gas diffusion in solid oxide fuel cells is presented. This book also discusses the history and underlying fundamental mechanisms of gas diffusion in solid oxide fuel cells, general theoretical mathematical models for gas diffusion, and traditional and advanced techniques for gas diffusivity measurement.
Author : National Institute of Standards and Technology (U.S.)
Publisher :
Page : 424 pages
File Size : 45,55 MB
Release : 1990
Category : Government publications
ISBN :
Author : John Peter Vermylen
Publisher : Stanford University
Page : 143 pages
File Size : 32,70 MB
Release : 2011
Category :
ISBN :
This thesis presents five studies of a gas shale reservoir using diverse methodologies to investigate geomechanical and transport properties that are important across the full reservoir lifecycle. Using the Barnett shale as a case study, we investigated adsorption, permeability, geomechanics, microseismicity, and stress evolution in two different study areas. The main goals of this thesis can be divided into two parts: first, to investigate how flow properties evolve with changes in stress and gas species, and second, to understand how the interactions between stress, fractures, and microseismicity control the creation of a permeable reservoir volume during hydraulic fracturing. In Chapter 2, we present results from adsorption and permeability experiments conducted on Barnett shale rock samples. We found Langmuir-type adsorption of CH4 and N2 at magnitudes consistent with previous studies of the Barnett shale. Three of our samples demonstrated BET-type adsorption of CO2, in contrast to all previous studies on CO2 adsorption in gas shales, which found Langmuir-adsorption. At low pressures (600 psi), we found preferential adsorption of CO2 over CH4 ranging from 3.6x to 5.5x. While our measurements were conducted at low pressures (up to 1500 psi), when our model fits are extrapolated to reservoir pressures they reach similar adsorption magnitudes as have been found in previous studies. At these high reservoir pressures, the very large preferential adsorption of CO2 over CH4 (up to 5-10x) suggests a significant potential for CO2 storage in gas shales like the Barnett if practical problems of injectivity and matrix transport can be overcome. We successfully measured permeability versus effective stress on two intact Barnett shale samples. We measured permeability effective stress coefficients less than 1 on both samples, invalidating our hypothesis that there might be throughgoing flow paths within the soft, porous organic kerogen that would lead the permeability effective stress coefficient to be greater than 1. The results suggest that microcracks are likely the dominant flow paths at these scales. In Chapter 3, we present integrated geological, geophysical, and geomechanical data in order to characterize the rock properties in our Barnett shale study area and to model the stress state in the reservoir before hydraulic fracturing occurred. Five parallel, horizontal wells were drilled in the study area and then fractured using three different techniques. We used the well logs from a vertical pilot well and a horizontal well to constrain the stress state in the reservoir. While there was some variation along the length of the well, we were able to determine a best fit stress state of Pp = 0.48 psi/ft, Sv = 1.1 psi/ft, SHmax = 0.73 psi/ft, and Shmin = 0.68 psi/ft. Applying this stress state to the mapped natural fractures indicates that there is significant potential for induced shear slip on natural fracture planes in this region of the Barnett, particularly close to the main hydraulic fracture where the pore pressure increase during hydraulic fracturing is likely to be very high. In Chapter 4, we present new techniques to quantify the robustness of hydraulic fracturing in gas shale reservoirs. The case study we analyzed involves five parallel horizontal wells in the Barnett shale with 51 frac stages. To investigate the numbers, sizes, and types of microearthquakes initiated during each frac stage, we created Gutenberg-Richter-type magnitude distribution plots to see if the size of events follows the characteristic scaling relationship found in natural earthquakes. We found that slickwater fracturing does generate a log-linear distribution of microearthquakes, but that it creates proportionally more small events than natural earthquake sources. Finding considerable variability in the generation of microearthquakes, we used the magnitude analysis as a proxy for the "robustness" of the stimulation of a given stage. We found that the conventionally fractured well and the two alternately fractured wells ("zipperfracs") were more effective than the simultaneously fractured wells ("simulfracs") in generating microearthquakes. We also found that the later stages of fracturing a given well were more successful in generating microearthquakes than the early stages. In Chapter 5, we present estimates of stress evolution in our study reservoir through analysis of the instantaneous shut-in pressure (ISIP) at the end of each stage. The ISIP increased stage by stage for all wells, but the simulfrac wells showed the greatest increase and the zipperfrac wells the least. We modeled the stress increase in the reservoir with a simple sequence of 2-D cracks along the length of the well. When using a spacing of one crack per stage, the modeled stress increase was nearly identical to the measured stress increase in the zipperfrac wells. When using three cracks per stage, the modeled final stage stress magnitude matched the measured final stage stress magnitude from the simulfrac wells, but the rate of stress increase in the simulfrac wells was much more gradual than the model predicted. To further investigate the causes of these ISIP trends, we began numerical flow and stress analysis to more realistically model the processes in the reservoir. One of our hypotheses was that the shorter total time needed to complete all the stages of the simulfrac wells was the cause of the greater ISIP increase compared to the zipperfrac wells. The microseismic activity level measured in Chapter 4 also correlates with total length of injection, suggesting leak off into the reservoir encouraged shear failure. Numerical modeling using the coupled FEM and flow software GEOSIM was able to model some cumulative stress increase the reservoir, but the full trend was not replicated. Further work to model field observations of hydraulic fracturing will enhance our understanding of the impact that hydraulic fracturing and stress change have on fracture creation and permeability enhancement in gas shales.
Author : Julian Szekely
Publisher : Elsevier
Page : 415 pages
File Size : 16,32 MB
Release : 2012-12-02
Category : Science
ISBN : 0323151396
Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it's based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.
Author :
Publisher :
Page : 834 pages
File Size : 48,76 MB
Release : 1990
Category : Power resources
ISBN :
Author : William Davison
Publisher : Cambridge University Press
Page : 321 pages
File Size : 26,3 MB
Release : 2016-09-15
Category : Science
ISBN : 110713076X
An essential guide to the applications and usage of the diffusive gradients in thin-films (DGT) technique for students and professionals.
Author : John Crank
Publisher : Oxford University Press
Page : 428 pages
File Size : 14,50 MB
Release : 1979
Category : Mathematics
ISBN : 9780198534112
Though it incorporates much new material, this new edition preserves the general character of the book in providing a collection of solutions of the equations of diffusion and describing how these solutions may be obtained.
Author : Brian Evans
Publisher : Academic Press
Page : 549 pages
File Size : 49,57 MB
Release : 1992-08-04
Category : Business & Economics
ISBN : 008095989X
This festschrift, compiled from the symposium held in honor of W.F. Brace, is a timely overview of fault mechanics and transport properties of rock. State-of-the-art research is presented by internationally recognized experts, who highlight developments in this contemporary area of study subsequent to Bill Brace's pioneering work.Key Features* The strength of brittle rocks* The effects of stress and stress-induced damage on physical properties of rock* Permeability and fluid flow in rocks* The strength of rocks and tectonic processes