Acrylic Acid Production from Natural Gas - Cost Analysis - Acrylic Acid E81A


Book Description

This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from natural gas. The study examines an integrated plant in which natural gas is first converted to acetylene and the acetylene produced is converted to Acrylic Acid. In addition, synthesis gas obtained in the acetylene manufacture is used to produce methanol as by-product. This report was developed based essentially on the following reference(s): (1) "Acrylic Acid and Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition (2) "Acetylene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Propenoic Acid, Reppe, BASF, Rohm and Haas




Acrylic Acid Production from Propane - Cost Analysis - Acrylic Acid E91A


Book Description

This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from propane The process examined is a novel process for propane oxidation. In this process, propane is fed to an oxydehydrogenation reactor in the presence of steam to form propylene. The propylene-containing gas passes through a two-stage vapor phase oxidation to generate an acrylic acid-containing gas, from which acrylic acid is recovered via absorption in water. The aqueous acrylic acid solution is purified via light solvent extraction to Ester-grade Acrylic Acid (EAA). This report was developed based essentially on the following reference(s): (1) "Acrylic Acid and Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition (2) US Patent 6492548, issued to Union Carbide in 2002 Keywords: Propene, Air Oxidation, Propenoic Acid, Nippon Shokubai, Rohm & Haas, Dow




Acrylic Acid Production from Acetylene - Cost Analysis - Acrylic Acid E61A


Book Description

This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from acetylene and carbon monoxide. The process examined involves the addition of carbon monoxide to acetylene using a nickel carbonyl catalyst. This report was developed based essentially on the following reference(s): Keywords: BASF, Reppe Reaction, CO, Ni(CO)4




Generating Electricity from the Sun


Book Description

The direct conversion of daylight into electricity by photovoltaic solar cells is one of the most promising of the renewable energy options. The importance of the technology is reflected in the growth in the field. What was largely technology for space programmes in 1976 produced 28.6 MW of terrestrial modules in 1987. The popularity of the technology can partly be explained by its versatility. Arrays of any size and voltage can be constructed from standard modules, with the conversion efficiency being practically independent from output. Photovoltaics are also well suited to on-site generation of power in remote areas. This book is intended primarily to give students, engineers and scientists entering the photovoltaics field an overview of all aspects of the subject, with pointers to further reading. However, by using simple language and avoiding jargon, an effort has been made to make the work useful and interesting to the general public.




Acrylic Acid Production from Propylene - Cost Analysis - Acrylic Acid E11A


Book Description

This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from chemical grade (CG) propylene. The process examined is a typical propylene oxidation. In this process, propylene passes through a two-stage vapor phase oxidation to generate an acrylic acid-containing gas, from which acrylic acid is recovered via absorption in water. The aqueous acrylic acid solution is purified via light solvent extraction to Ester-grade Acrylic Acid (EAA), which is used in the production of acrylic esters. This report was developed based essentially on the following reference(s): "Acrylic Acid", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Propene, Air Oxidation, Propenoic Acid, Nippon Shokubai, Rohm & Haas, Dow




Methyl Acrylate from Acrylic Acid - Cost Analysis - Methyl Acrylate E11A


Book Description

This report presents a cost analysis of Methyl Acrylate production from acrylic acid and methanol The process examined is a typical esterification process. In this process, acrylic acid and methanol are esterified in a fixed-bed reactor producing Methyl Acrylate. This report was developed based essentially on the following reference(s): Keywords: Methyl Alcohol, Lower Alkyl Acrylate, Methyl Prop-2-Enoate




Glacial Acrylic Acid from Crude Acrylic Acid - Cost Analysis - Acrylic Acid E52A


Book Description

This report presents a cost analysis of Glacial Acrylic Acid production from crude acrylic acid. The process examined consists of a typical distillation/purification process. This report was developed based essentially on the following reference(s): "Acrylic Acid and Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Propenoic Acid, Commercial Grade Acrylic Acid, Propylene Oxidation, Rohm and Haas, Dow, Flocculant Grade, GAA-FG




Acrylic Acid Production from Ethylene Oxide - Cost Analysis - Acrylic Acid E71A


Book Description

This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from ethylene oxide using a carbonylation process. The process examined is similar to Novomer process. In this process, ethylene oxide is catalytic carbonylated to beta-propiolactone intermediate, which is then converted to Acrylic Acid. The final product obtained is EAA, which is used in the production of acrylic esters. This report was developed based essentially on the following reference(s): WO Patent 2013126375, issued to Novomer in 2013 Keywords: Propenoic Acid, Polypropiolactone, Carbon Monoxide, Acrylate Esters, Cornell Research Foundation, Celanese, Ketene




Acrylic Acid Production from Glycerol - Cost Analysis - Acrylic Acid E21A


Book Description

This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from crude glycerol. The two-step process examined is similar to Arkema process. In this process, crude glycerol (at 85 wt% purity) obtained as by-product of biodiesel plants, is used as the main raw material. After purification, glycerol is dehydrated to acrolein and subsequently oxidized. The final product obtained is EAA, which is used in the production of acrylic esters. This report was developed based essentially on the following reference(s): US Patent 2010/0168471 A1, issued to Arkema in 2010 Keywords: Glicerin, Dehydration, Oxidation, Unsaturated Carboxylic Acid, Propenoic Acid




Bio-Acrylic Acid Production from Glucose - Cost Analysis - Acrylic Acid E32A


Book Description

This report presents a cost analysis of bio-based Acrylic Acid production from glucose syrup using a fermentation process In the process examined, glucose is fermented to produce 3-hydroxypropionic acid (3-HPA), which is dehydrated to produce Acrylic Acid. The process uses a 70 wt% glucose-water syrup as raw material and the final product obtained is Glacial Acrylic Acid. This report was developed based essentially on the following reference(s): (1) US Patent 9428778, issued to Cargill in 2016 (2) US Patent 7186856, issued to Cargill in 2007 Keywords: Dextrose, Fermentation, Salt-Splitting, 3-HP, Dehydration, Glacial Acrylic Acid