Adsorption and Diffusion in Nanoporous Materials


Book Description

Offering a materials science point of view, the author covers the theory and practice of adsorption and diffusion applied to gases in microporous crystalline, mesoporous ordered, and micro/mesoporous amorphous materials. Examples used include microporous and mesoporous molecular sieves, amorphous silica, and alumina and active carbons, akaganeites, prussian blue analogues, metal organic frameworks and covalent organic frameworks. The use of single component adsorption, diffusion in the characterization of the adsorbent surface, pore volume, pore size distribution, and the study of the parameters characterizing single component transport processes in porous materials are detailed.




Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs)


Book Description

This book covers topics of equilibria and kinetics of adsorption in porous media. Fundamental equilibria and kinetics are dealt with for homogeneous as well as heterogeneous particles. Five chapters of the book deal with equilibria and eight chapters deal with kinetics. Single component as well as multicomponent systems are discussed. In kinetics analysis, we deal with the various mass transport processes and their interactions inside a porous particle. Conventional approaches as well as the new approach using Maxwell-Stefan equations are presented. Various methods to measure diffusivity, such as the Differential Adsorption Bed (DAB), the time lag, the diffusion cell, chromatography, and the batch adsorber methods are also covered by the book. It can be used by lecturers and engineers who wish to carry out research in adsorption. A number of programming codes written in MatLab language are included so that readers can use them directly to better understand the behavior of single and multicomponent adsorption systems.




Molecular Sieves


Book Description




Adsorption and Diffusion


Book Description

"Molecular Sieves - Science and Technology" covers, in a comprehensive manner, the science and technology of zeolites and all related microporous and mesoporous materials. The contributions are grouped together topically in such a way that each volume deals with a specific sub-field. Volume 7 treats fundamentals and analyses of adsorption and diffusion in zeolites including single-file diffusion. Various methods of measuring adsorption and diffusion are described and discussed.




Diffusion in Nanoporous Materials, 2 Volumes


Book Description

Atoms and molecules in all states of matter are subject to continuous irregular movement. This process, referred to as diffusion, is among the most general and basic phenomena in nature and determines the performance of many technological processes. This book provides an introduction to the fascinating world of diffusion in microporous solids. Jointly written by three well-known researchers in this field, it presents a coherent treatise, rather than a compilation of separate review articles, covering the theoretical fundamentals, molecular modeling, experimental observation and technical applications. Based on the book Diffusion in Zeolites and other Microporous Solids, originally published in 1992, it illustrates the remarkable speed with which this field has developed since that time. Specific topics include: new families of nanoporous materials, micro-imaging and single-particle tracking, direct monitoring of transient profiles by interference microscopy, single-file diffusion and new approaches to molecular modeling.




Handbook of Vacuum Technology


Book Description

This comprehensive, standard work has been updated to remain an important resource for all those needing detailed knowledge of the theory and applications of vacuum technology. The text covers the existing knowledge on all aspects of vacuum science and technology, ranging from fundamentals to components and operating systems. It features many numerical examples and illustrations to help visualize the theoretical issues, while the chapters are carefully cross-linked and coherent symbols and notations are used throughout the book. The whole is rounded off by a user-friendly appendix of conversion tables, mathematical tools, material related data, overviews of processes and techniques, equipment-related data, national and international standards, guidelines, and much more. As a result, engineers, technicians, and scientists will be able to develop and work successfully with the equipment and environment found in a vacuum.




Fundamentals of Adsorption


Book Description

Fundamentals of Adsorption contains 2 plenary lectures and 96 selected papers from the IVth International Conference, Kyoto, May, 1992. The topics cover a wide range of studies from fundamentals to applications: characterization of porous adsorbents, molecular simulation, adsorption isotherms, diffusion in adsorbents, breakthrough detection, chromatography, pressure swing operation, etc. Model studies on adsorption, surface characterization, microporosimetry, molecular simulations of equilibrium and diffusion, computer simulation of adsorption beds, and many theoretical studies are also included. Special attention is given to: bulk gas separation and purification, solvent recovery, bioproduct separation, environmental pollution control, methane storage, adsorption cooling and resources recovery.




Fractional Diffusion Equations and Anomalous Diffusion


Book Description

Presents a unified treatment of anomalous diffusion problems using fractional calculus in a wide range of applications across scientific and technological disciplines.




Adsorption


Book Description

Adsorption is the basis of various emerging technologies that will be essential for addressing the problems of technologies that will be essential for addressing the problems of energy conservation and environmental protection.This volume reviews recent progress and outlines the outlook for future development in adsorption theories, kinetics, pressure swing adsorption, SMB, and new nanoporous adsorbents. The contributions cover the fundamental knowledge and methodologies for adsorption experiments and calculations regarding equilibria, heat effects, adsorbent structural modeling, diffusion measurement, and selectivity control.The volume also includes topics concerning hydrogen storage, desulfurization of fuels, and chiral separation. The contributors are internationally renowned scholars in the field of adsorption.




New Developments in Adsorption/Separation of Small Molecules by Zeolites


Book Description

This volume compiles and discusses the fundamental and multidisciplinary knowledge on adsorption and separation processes using zeolites as adsorbents. Over the last decade, a large amount of research has been carried out for the development of zeolites as adsorbents. However, there is still a growing interest to increase the understanding of such selective adsorbents. Therefore, synthesis strategies and new approaches for developing new selective zeolite adsorbents for gas separation are presented in the first chapter. In addition, a chapter focused on adsorption characterization techniques of microporous materials is included. This will be helpful for advanced readers, since the new IUPAC recommendations for microporous characterization are not still widely employed by the zeolite community. Experimental and theoretical aspects of economically and environmentally relevant separations, which have been successfully carried out with zeolites, are discussed in detail in subsequent chapters. Finally, industrial zeolite based adsorption and separation processes as well as current perspectives for new zeolite based separations, and improvements of current technologies are presented.