Advanced Green Chemistry - Part 2: From Catalysis To Chemistry Frontiers


Book Description

This book is indexed in Chemical Abstracts ServiceGreen Chemistry has evolved in response to several environmental issues in the second half of the last century, mostly due to the almost freely expanding chemical, petrochemical, and pharmaceutical industries. During the past two decades Green Chemistry grew rapidly and we can now consider this area as a mature and powerful field. Tremendous development has taken place in many important areas including renewable energy and resources, reaction environments, catalysis, synthesis, chemical biology, green polymers, and facile recycling. The combination of Green Chemistry with engineering, biology, toxicology, and physics will lead to novel interdisciplinary systems, which can now lift Green Chemistry to the next, advanced level.The editors have assembled authors among the best specialists of this growing area of research. This collection of reviews and perspectives provides an exciting vision of the more recent developments in Green Chemistry. The contents of this book illustrate the breath of the field and its role to address environmental issues. This volume will serve as a book of reference showing a panoramic view of the field and a preview of its future direction, as well as a book of inspiration for those aiming to further advance its frontiers. This volume emphasizes on the most recent developments in green catalysis, bio-sourced polymers and the study of continental organic matter for a better understanding of the carbon geochemical cycle.




Supramolecular Catalysts: Design, Fabrication, And Applications


Book Description

This book is indexed in Chemical Abstracts Service'The present book displays the continuing broad interest in the area of Supramolecular Catalysis. It provides an excellent update to previous contributions in the field and will be highly beneficial reading for all students and researchers interested in the challenges faced in this domain of Supramolecular Chemistry.'Jean-Marie LehnNobel Laureate The construction of catalysts by supramolecular forces has recently become a powerful tool and the role of noncovalent interactions can assist in designing new tools for the construction of effective and selective catalytic systems. It is unquestionably, vastly important to understand how different noncovalent interactions can be controlled or manipulated under appropriate reaction conditions. Supramolecular catalysts have had a tremendous impact on the syntheses of both chemical commodities and fine chemicals over the last 50 years, leading to the discovery of new reactions that were previously deemed impossible. This means that supramolecular chemistry plays a predominant role in accelerating or understanding chemical reactions.This book which addresses the above points is written by some of the leading contributors in this field and is intended for graduate students, researchers and academics working in supramolecular chemistry, organic chemistry, inorganic chemistry, and physical chemistry as well as researchers with an interest in the area of catalysis. The authors give examples illustrating the growth of the field, especially with special emphasis on new results published over the last decade. They also provide an explanation of fundamentals and topical research.




Electrochemistry Of Metalloporphyrins


Book Description

This book is part of a series of ongoing volumes in the Series on Chemistry, Energy and the Environment, edited by Karl Kadish and Roger Guilard. The current volume on Electrochemistry of Metalloporphyrins covers all aspects of porphyrin electrochemistry in nonaqueous media and should be of benefit and interest to beginning graduate students as well as experienced researchers in many fields of porphyrin chemistry where electrochemistry is known to play a key role in influencing properties of the compounds as well as mechanisms and biological functions. The first half of the book is aimed at non-experts in the field of electrochemistry who would like to begin studies on porphyrin electrochemistry or understand the literature on porphyrin electrochemistry and this is then followed by detailed examples of how changes in the central metal ion of a given metalloporphyrin will affect its redox properties. The scope of the work covers the period in the literature between the mid-1960s and mid-2022 and expands greatly upon several earlier reviews by the senior author which are no longer in print and were never accessible in electronic form. This is the only book of its kind in the field which covers the basic electrochemistry of metalloporphyrins as well as describes the published data as a function of the central metal ion, considering all elements in the periodic table.




Topics In Enantioselective Catalysis: Recent Achievements And Future Challenges


Book Description

This book illustrates the broad field of enantioselective catalysis by highlighting a few topics, out of myriads, with the double aim to typify selected synthetic achievements and future challenges. Eleven research groups have highlighted topics of interest in either organo- or organometallic catalysis, related to their own expertise. For mature fields, these short chapters, far from being exhaustive, show updated overviews including major recent advances and disclose a few prospects. Other chapters focus on upcoming topics in enantioselective catalysis, i.e. on classes of reactions or families of catalysts that are expected to provide appealing synthetic tools when suitably mastered. For all these areas, recent studies demonstrate highly promising perspectives.




Progress In Layered Double Hydroxides: From Synthesis To New Applications


Book Description

Layered Double Hydroxides (LDH) are two-dimensional materials with unique physiochemical properties, which enable their use in a wide range of applications such as catalysis, biomaterials, energy, filler of polymeric composites, and water remediation.This book addresses basic aspects of LDH as the implementations in the methodologies based on density functional theory (DFT) to understand the properties and applications of LDHs, the synthetic methods to prepare LDHs and LDH based core-shell structures, and the swelling and exfoliation behaviors of LDH compounds. A relevant part of the book is devoted to consolidated and emerging applications of LDHs as catalysts in photocatalysis, electrocatalysis and water oxidation processes, as biomaterials and as functional fillers in food packaging. New advances on LDH are described with a keen eye on the past research.




Green Organic Reactions


Book Description

This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.




Green Approaches in Medicinal Chemistry for Sustainable Drug Design


Book Description

Extensive experimentation and high failure rates are a well-recognized downside to the drug discovery process, with the resultant high levels of inefficiency and waste producing a negative environmental impact. Sustainable and Green Approaches in Medicinal Chemistry 2e reveals how medicinal chemistry can play a direct role in addressing this issue. After providing essential context to the growth of green chemistry in relation to drug discovery, the book goes on to identify a broad range of practical techniques and useful insights, revealing how medicinal chemistry techniques can be used to improve efficiency, mitigate failure and increase the environmental benignity of the entire drug discovery process. Drawing on the knowledge of a global team of experts, Sustainable and Green Approaches in Medicinal Chemistry, Second Edition encourages the growth of green medicinal chemistry, and supports medicinal chemists, drug discovery researchers, pharmacologists and all those in related fields across both academia and industry in integrating these approaches into their own work. This second volume of the second edition includes the development of nanoparticles and nanocomposites, as well as the application of ultrasound and microwave-induced methods; studies solventless synthesis; defines the role of steroids; studies reactions in aqueous solution; identifies enzyme-mediated reactions; investigates ionic liquids and deep eutectic solvents; explores natural products; investigates solid supports; realizes the effects of salts; focuses on combinatorial chemistry; develops one-pot methods; analyzes multi-component reactions; investigates dipole moment values; and examines computer-assisted methods. - Highlights the need for adoption of sustainable and green chemistry pathways in drug development - Reveals risk factors associated with the drug development process and the ways sustainable approaches can help address these - Identifies novel and cost effective green medicinal chemistry approaches for improved efficiency and sustainability




Advanced Catalysis for Drop-in Chemicals


Book Description

Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. Describes fossil fuels, biomass, drop-in chemicals, catalysis, nano- and atomic-scale catalysts Includes pre- and post-treatment strategies for biomass upgrading Provides green catalytic processes for drop-in chemicals synthesis Outlines stabilization of nano- and atomic-scale catalysts Prospects atom-economy catalytic routes for drop-in chemicals synthesis Challenges using drop-in chemicals in place of petrochemicals in the chemical industry




Advanced Green Chemistry - Part 1: Greener Organic Reactions And Processes


Book Description

Green Chemistry has evolved in response to several environmental issues in the second half of the last century, mostly due to the almost freely expanding chemical, petrochemical, and pharmaceutical industries. During the past two decades Green Chemistry grew rapidly and we can now consider this area as a mature and powerful field. Tremendous development has taken place in many important areas including renewable energy and resources, reaction environments, catalysis, synthesis, chemical biology, green materials, in situ monitoring and facile recycling. The combination of Green Chemistry with engineering, biology, toxicology, and physics will lead to novel interdisciplinary systems, which can now lift Green Chemistry to the next, advanced level.The editors of this book have assembled as authors among the best specialists of this growing area of research. This collection of reviews and perspectives provides an exciting vision of the more recent developments in Green Chemistry. It illustrates the breath of the field and its role to address environmental issues. This volume will serve as a book of reference showing a panoramic view of the field and a preview of its future direction as well as a book of inspiration for those aiming to further advance its frontiers.